Recent advances in analysis of trace elements in environmental samples by X-ray based techniques (IUPAC Technical Report)

Terzano, Roberto; Denecke, Melissa A.; Falkenberg, Gerald; Miller, Bradley; Paterson, David; Janssens, Koen

doi:10.1515/pac-2018-0605

Title: Recent advances in analysis of trace elements in environmental samples by X-ray based techniques (IUPAC Technical Report)

Journal Article · Tue May 21 00:00:00 EDT 2019 · Pure and Applied Chemistry

DOI:https://doi.org/10.1515/pac-2018-0605· OSTI ID:1529617

Terzano, Roberto ^[1]; Denecke, Melissa A. ^[2]; Falkenberg, Gerald ^[3]; Miller, Bradley ^[4]; Paterson, David ^[5]; Janssens, Koen ^[6]

Univ. of Bari (Italy)
Univ. of Manchester (United Kingdom)
Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
US Environmental Protection Agency (EPA), Lakewood, Denver, CO (United States)
Australian Nuclear Science and Technology Organisation (ANSTO), Melbourne, VIC (Australia). Australian Synchrotron
Univ. of Antwerp (Belgium)

Trace elements analysis is a foundational challenge in environmental sciences. Scientists measure trace elements in environmental media in order to assess the quality and safety of ecosystems and to quantify the burden of anthropogenic pollution. Among the available analytical techniques, X-ray based methods are particularly powerful, as they can quantify trace elements in situ. Chemical extraction is not required, as is the case for many other analytical techniques. In the last few years, the potential for X-ray techniques to be applied in the environmental sciences has dramatically increased due to developments in laboratory instruments and synchrotron radiation facilities with improved sensitivity and spatial resolution. In this report, we summarize the principles of the X-ray based analytical techniques most frequently employed to study trace elements in environmental samples. We report on the most recent developments in laboratory and synchrotron techniques, as well as advances in instrumentation, with a special attention on X-ray sources, detectors, and optics. Lastly, we inform readers on recent applications of X-ray based analysis to different environmental matrices, such as soil, sediments, waters, wastes, living organisms, geological samples, and atmospheric particulate, and we report examples of sample preparation.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: IUPAC

OSTI ID:: 1529617

Journal Information:: Pure and Applied Chemistry, Vol. 91, Issue 6; ISSN 0033-4545

Publisher:: IUPACCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 21 works

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References (134)

Soft X-Ray Spectromicroscopy Investigation of the Interaction of Aquatic Humic Acid and Clay Colloids Rothe, Jörg; Denecke, Melissa A.; Dardenne, Kathy Journal of Colloid and Interface Science, Vol. 231, Issue 1 https://doi.org/10.1006/jcis.2000.7124	journal	November 2000
Advanced source apportionment of size-resolved trace elements at multiple sites in London during winter Visser, S.; Slowik, J. G.; Furger, M. Atmospheric Chemistry and Physics, Vol. 15, Issue 19 https://doi.org/10.5194/acp-15-11291-2015	journal	January 2015
Chemical processes affecting the mobility of major, minor and trace elements during weathering of granitic rocks Middelburg, Jack J.; van der Weijden, Cornelis H.; Woittiez, Joost R. W. Chemical Geology, Vol. 68, Issue 3-4 https://doi.org/10.1016/0009-2541(88)90025-3	journal	May 1988
X-ray-induced photo-chemistry and X-ray absorption spectroscopy of biological samples George, Graham N.; Pickering, Ingrid J.; Pushie, M. Jake Journal of Synchrotron Radiation, Vol. 19, Issue 6 https://doi.org/10.1107/S090904951203943X	journal	October 2012
Characterization of atmospheric aerosols using Synchroton radiation total reflection X-ray fluorescence and Fe K-edge total reflection X-ray fluorescence-X-ray absorption near-edge structure Fittschen, U. E. A.; Meirer, F.; Streli, C. Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 63, Issue 12, p. 1489-1495 https://doi.org/10.1016/j.sab.2008.10.016	journal	December 2008
Kerb and urban increment of highly time-resolved trace elements in PM ₁₀ , PM _2.5 and PM _1.0 winter aerosol in London during ClearfLo 2012 Visser, S.; Slowik, J. G.; Furger, M. Atmospheric Chemistry and Physics, Vol. 15, Issue 5 https://doi.org/10.5194/acp-15-2367-2015	journal	January 2015
Molybdenum reduction in a sulfidic lake: Evidence from X-ray absorption fine-structure spectroscopy and implications for the Mo paleoproxy Dahl, Tais W.; Chappaz, Anthony; Fitts, Jeffrey P. Geochimica et Cosmochimica Acta, Vol. 103 https://doi.org/10.1016/j.gca.2012.10.058	journal	February 2013
Mapping of multi-elements during melting and solidification using synchrotron X-rays and pixel-based spectroscopy Liotti, E.; Lui, A.; Connolley, T. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep15988	journal	November 2015
Accelerator-based trace element analysis of foods and agriculture products Lagunas-Solar, Manuel C.; Piña U., Cecilia; Solís, Corina Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 266, Issue 10 https://doi.org/10.1016/j.nimb.2008.03.027	journal	May 2008
Identification of nickel chelators in three hyperaccumulating plants: An X-ray spectroscopic study Montargès-Pelletier, Emmanuelle; Chardot, Vanessa; Echevarria, Guillaume Phytochemistry, Vol. 69, Issue 8 https://doi.org/10.1016/j.phytochem.2008.02.009	journal	May 2008
Products of in Situ Corrosion of Depleted Uranium Ammunition in Bosnia and Herzegovina Soils Wang, Yuheng; von Gunten, Konstantin; Bartova, Barbora Environmental Science & Technology, Vol. 50, Issue 22 https://doi.org/10.1021/acs.est.6b03732	journal	October 2016
Non-labile silver species in biosolids remain stable throughout 50 years of weathering and ageing Donner, E.; Scheckel, K.; Sekine, R. Environmental Pollution, Vol. 205 https://doi.org/10.1016/j.envpol.2015.05.017	journal	October 2015
Characterization of As-polluted soils by laboratory X-ray-based techniques coupled with sequential extractions and electron microscopy: the case of Crocette gold mine in the Monte Rosa mining district (Italy) Allegretta, Ignazio; Porfido, Carlo; Martin, Maria Environmental Science and Pollution Research, Vol. 25, Issue 25 https://doi.org/10.1007/s11356-018-2526-9	journal	June 2018
Speciation and Distribution of Arsenic in the Nonhyperaccumulator Macrophyte Ceratophyllum demersum Mishra, Seema; Wellenreuther, Gerd; Mattusch, Jürgen Plant Physiology, Vol. 163, Issue 3 https://doi.org/10.1104/pp.113.224303	journal	September 2013
Three-dimensional structure determination using multiple-scattering analysis of XAFS: applications to metalloproteins and coordination chemistry Levina, Aviva; Armstrong, Robert S.; Lay, Peter A. Coordination Chemistry Reviews, Vol. 249, Issue 1-2 https://doi.org/10.1016/j.ccr.2004.10.008	journal	January 2005
Quantitative sampling and analysis of trace elements in atmospheric aerosols: impactor characterization and Synchrotron-XRF mass calibration Richard, A.; Bukowiecki, N.; Lienemann, P. Atmospheric Measurement Techniques, Vol. 3, Issue 5 https://doi.org/10.5194/amt-3-1473-2010	journal	January 2010
The hyperaccumulator Alyssum murale uses complexation with nitrogen and oxygen donor ligands for Ni transport and storage McNear, David H.; Chaney, Rufus L.; Sparks, Donald L. Phytochemistry, Vol. 71, Issue 2-3 https://doi.org/10.1016/j.phytochem.2009.10.023	journal	February 2010
Three-Dimensional Trace Element Analysis by Confocal X-ray Microfluorescence Imaging Vincze, Laszlo; Vekemans, Bart; Brenker, Frank E. Analytical Chemistry, Vol. 76, Issue 22 https://doi.org/10.1021/ac049274l	journal	November 2004
Speciation of copper and zinc in size-fractionated atmospheric particulate matter using total reflection mode X-ray absorption near-edge structure spectrometry Osán, János; Meirer, Florian; Groma, Veronika Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 65, Issue 12 https://doi.org/10.1016/j.sab.2010.11.002	journal	December 2010
Analysis of sublethal arsenic toxicity to Ceratophyllum demersum : subcellular distribution of arsenic and inhibition of chlorophyll biosynthesis Mishra, Seema; Alfeld, Matthias; Sobotka, Roman Journal of Experimental Botany, Vol. 67, Issue 15 https://doi.org/10.1093/jxb/erw238	journal	June 2016
Localizing the Biochemical Transformations of Arsenate in a Hyperaccumulating Fern Pickering, Ingrid J.; Gumaelius, Luke; Harris, Hugh H. Environmental Science & Technology, Vol. 40, Issue 16 https://doi.org/10.1021/es052559a	journal	August 2006
Refractive x-ray lenses Lengeler, Bruno; Schroer, Christian G.; Kuhlmann, Marion Journal of Physics D: Applied Physics, Vol. 38, Issue 10A https://doi.org/10.1088/0022-3727/38/10A/042	journal	May 2005
Trace Metals in Ambient Air: Hourly Size-Segregated Mass Concentrations Determined by Synchrotron-XRF Bukowiecki, Nicolas; Hill, Matthias; Gehrig, Robert Environmental Science & Technology, Vol. 39, Issue 15 https://doi.org/10.1021/es048089m	journal	August 2005
Application of Synchrotron Radiation-based Methods for Environmental Biogeochemistry: Introduction to the Special Section Hettiarachchi, Ganga M.; Donner, Erica; Doelsch, Emmanuel Journal of Environmental Quality, Vol. 46, Issue 6 https://doi.org/10.2134/jeq2017.09.0349	journal	November 2017
Mechanisms of murine cerebral malaria: Multimodal imaging of altered cerebral metabolism and protein oxidation at hemorrhage sites Hackett, Mark J.; Aitken, Jade B.; El-Assaad, Fatima Science Advances, Vol. 1, Issue 11 https://doi.org/10.1126/sciadv.1500911	journal	December 2015
Actinide speciation using X-ray absorption fine structure spectroscopy Denecke, M. Coordination Chemistry Reviews, Vol. 250, Issue 7-8 https://doi.org/10.1016/j.ccr.2005.09.004	journal	April 2006
Zinc hyperaccumulation and cellular distribution in Arabidopsis halleri Zhao, F. J.; Lombi, E.; Breedon, T. Plant, Cell & Environment, Vol. 23, Issue 5 https://doi.org/10.1046/j.1365-3040.2000.00569.x	journal	May 2000
Geochemical, mineralogical and microbiological characteristics of sediment from a naturally reduced zone in a uranium-contaminated aquifer Campbell, K. M.; Kukkadapu, R. K.; Qafoku, N. P. Applied Geochemistry, Vol. 27, Issue 8 https://doi.org/10.1016/j.apgeochem.2012.04.013	journal	August 2012
Combined Computed Nanotomography and Nanoscopic X-ray Fluorescence Imaging of Cobalt Nanoparticles in Caenorhabditis elegans Cagno, Simone; Brede, Dag Anders; Nuyts, Gert Analytical Chemistry, Vol. 89, Issue 21 https://doi.org/10.1021/acs.analchem.7b02554	journal	October 2017
Application of Synchrotron X‐Ray Microbeam Spectroscopy to the Determination of Metal Distribution and Speciation in Biological Tissues Punshon, T.; Jackson, B. P.; Lanzirotti, A. Spectroscopy Letters, Vol. 38, Issue 3 https://doi.org/10.1081/SL-200058715	journal	May 2005
Nickel biopathways in tropical nickel hyperaccumulating trees from Sabah (Malaysia) van der Ent, Antony; Callahan, Damien L.; Noller, Barry N. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep41861	journal	February 2017
Nutritional characterization and shelf-life of packaged microgreens Paradiso, Vito Michele; Castellino, Maria; Renna, Massimiliano Food & Function, Vol. 9, Issue 11 https://doi.org/10.1039/C8FO01182F	journal	January 2018
Mouse Assay for Determination of Arsenic Bioavailability in Contaminated Soils Bradham, Karen D.; Diamond, Gary L.; Scheckel, Kirk G. Journal of Toxicology and Environmental Health, Part A, Vol. 76, Issue 13 https://doi.org/10.1080/15287394.2013.821395	journal	July 2013
The Bionanoprobe: hard X-ray fluorescence nanoprobe with cryogenic capabilities Chen, S.; Deng, J.; Yuan, Y. Journal of Synchrotron Radiation, Vol. 21, Issue 1 https://doi.org/10.1107/S1600577513029676	journal	December 2013
X-ray Absorption and Micro X-ray Fluorescence Spectroscopy Investigation of Copper and Zinc Speciation in Biosolids Donner, Erica; Howard, Daryl L.; Jonge, Martin D. de Environmental Science & Technology, Vol. 45, Issue 17 https://doi.org/10.1021/es201710z	journal	September 2011
Determination of phosphorus and other elements in atmospheric aerosols using synchrotron total-reflection X-ray fluorescence: Phosphorus in aerosols Fittschen, Ursula E. A.; Streli, Christina; Meirer, Florian X-Ray Spectrometry, Vol. 42, Issue 5 https://doi.org/10.1002/xrs.2457	journal	April 2013
Quantitative, chemically specific imaging of selenium transformation in plants Pickering, I. J.; Prince, R. C.; Salt, D. E. Proceedings of the National Academy of Sciences, Vol. 97, Issue 20 https://doi.org/10.1073/pnas.200244597	journal	September 2000
Reduced As components in highly oxidized environments: Evidence from full spectral XANES imaging using the Maia massively parallel detector Etschmann, B. E.; Ryan, C. G.; Brugger, J. American Mineralogist, Vol. 95, Issue 5-6 https://doi.org/10.2138/am.2010.3469	journal	May 2010
Quantitative imaging of gold nanoparticle distribution in a tumor-bearing mouse using benchtop x-ray fluorescence computed tomography Manohar, Nivedh; Reynoso, Francisco J.; Diagaradjane, Parmeswaran Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep22079	journal	February 2016
Redox preconditioning deep cratonic lithosphere for kimberlite genesis – evidence from the central Slave Craton Yaxley, G. M.; Berry, A. J.; Rosenthal, A. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-00049-3	journal	February 2017
Macro and Micro Full Field X-Ray Fluorescence with an X-Ray Pinhole Camera Presenting High Energy and High Spatial Resolution Romano, Francesco Paolo; Caliri, Claudia; Cosentino, Luigi Analytical Chemistry, Vol. 86, Issue 21 https://doi.org/10.1021/ac503263h	journal	October 2014
Using rare earth elements to trace wind-driven dispersion of sediments from a point source Van Pelt, R. Scott; Barnes, Melanie C. W.; Strack, John E. Aeolian Research, Vol. 32 https://doi.org/10.1016/j.aeolia.2018.01.004	journal	June 2018
Monte Carlo simulation of X-ray fluorescence spectra: Part 4. Photon scattering at high X-ray energies Vincze, L.; Janssens, K.; Vekemans, B. Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 54, Issue 12 https://doi.org/10.1016/S0584-8547(99)00094-4	journal	November 1999
Mineralogical characterization of mine waste Jamieson, Heather E.; Walker, Stephen R.; Parsons, Michael B. Applied Geochemistry, Vol. 57 https://doi.org/10.1016/j.apgeochem.2014.12.014	journal	June 2015
Beachrock formation via microbial dissolution and re-precipitation of carbonate minerals McCutcheon, Jenine; Nothdurft, Luke D.; Webb, Gregory E. Marine Geology, Vol. 382 https://doi.org/10.1016/j.margeo.2016.10.010	journal	December 2016
Applications of Environmental Scanning Electron Microscopy (ESEM) in botanical research Sorbo, Sergio; Basile, Adriana; Castaldo Cobianchi, Rosa Plant Biosystems - An International Journal Dealing with all Aspects of Plant Biology, Vol. 142, Issue 2 https://doi.org/10.1080/11263500802150829	journal	July 2008
Iron (Fe) speciation in xylem sap by XANES at a high brilliant synchrotron X-ray source: opportunities and limitations Terzano, Roberto; Mimmo, Tanja; Vekemans, Bart Analytical and Bioanalytical Chemistry, Vol. 405, Issue 16 https://doi.org/10.1007/s00216-013-6959-1	journal	April 2013
Practical review on the use of synchrotron based micro- and nano- X-ray fluorescence mapping and X-ray absorption spectroscopy to investigate the interactions between plants and engineered nanomaterials Castillo-Michel, Hiram A.; Larue, Camille; Pradas del Real, Ana E. Plant Physiology and Biochemistry, Vol. 110 https://doi.org/10.1016/j.plaphy.2016.07.018	journal	January 2017
Small-angle scattering computed tomography (SAS-CT) using a Talbot-Lau interferometer and a rotating anode x-ray tube: theory and experiments Chen, Guang-Hong; Bevins, Nicholas; Zambelli, Joseph Optics Express, Vol. 18, Issue 12 https://doi.org/10.1364/OE.18.012960	journal	January 2010
In Vivo Investigation of the Distribution and the Local Speciation of Selenium in Allium c epa L . by Means of Microscopic X-ray Absorption Near-Edge Structure Spectroscopy and Confocal Microscopic X-ray Fluorescence Analysis Bulska, Ewa; Wysocka, Irena A.; Wierzbicka, Małgorzata H. Analytical Chemistry, Vol. 78, Issue 22 https://doi.org/10.1021/ac060380s	journal	November 2006
The Race to X-ray Microbeam and Nanobeam Science Ice, G. E.; Budai, J. D.; Pang, J. W. L. Science, Vol. 334, Issue 6060 https://doi.org/10.1126/science.1202366	journal	December 2011
On the distribution and speciation of arsenic in the soil-plant-system of a rice field in West-Bengal, India: A μ-synchrotron techniques based case study Kramar, U.; Norra, S.; Berner, Z. Applied Geochemistry, Vol. 77 https://doi.org/10.1016/j.apgeochem.2015.11.006	journal	February 2017
Nitrogen and sulfur compounds in coastal Antarctic fine aerosol particles—an insight using non-destructive X-ray microanalytical methods Osan, J.; Torok, S.; Beckhoff, B. Atmospheric Environment, Vol. 40, Issue 25 https://doi.org/10.1016/j.atmosenv.2006.04.033	journal	August 2006
Synchrotron X-Ray Fluorescence Nanoprobe Reveals Target Sites for Organo-Osmium Complex in Human Ovarian Cancer Cells Sanchez-Cano, Carlos; Romero-Canelón, Isolda; Yang, Yang Chemistry - A European Journal, Vol. 23, Issue 11 https://doi.org/10.1002/chem.201605911	journal	January 2017
Fast X-ray microfluorescence imaging with submicrometer-resolution integrating a Maia detector at beamline P06 at PETRA III Boesenberg, Ulrike; Ryan, Christopher G.; Kirkham, Robin Journal of Synchrotron Radiation, Vol. 23, Issue 6 https://doi.org/10.1107/S1600577516015289	journal	October 2016
Quantitative Trace Element Analysis of Individual Fly Ash Particles by Means of X-ray Microfluorescence Vincze, L.; Somogyi, A.; Osán, J. Analytical Chemistry, Vol. 74, Issue 5 https://doi.org/10.1021/ac010789b	journal	March 2002
Localization and speciation of arsenic in Glomus intraradices by synchrotron radiation spectroscopic analysis González-Chávez, Ma. del Carmen A.; Miller, Bradley; Maldonado-Mendoza, Ignacio Eduardo Fungal Biology, Vol. 118, Issue 5-6 https://doi.org/10.1016/j.funbio.2014.03.002	journal	May 2014
Hard X-ray fluorescence tomography—an emerging tool for structural visualization de Jonge, Martin D.; Vogt, Stefan Current Opinion in Structural Biology, Vol. 20, Issue 5 https://doi.org/10.1016/j.sbi.2010.09.002	journal	October 2010
Imaging the penetration and distribution of zinc and zinc species after topical application of zinc pyrithione to human skin Holmes, Amy M.; Kempson, Ivan; Turnbull, Tyron Toxicology and Applied Pharmacology, Vol. 343 https://doi.org/10.1016/j.taap.2018.02.012	journal	March 2018
In-situ mobilization and transformation of iron oxides-adsorbed arsenate in natural groundwater Zhang, Di; Guo, Huaming; Xiu, Wei Journal of Hazardous Materials, Vol. 321 https://doi.org/10.1016/j.jhazmat.2016.09.021	journal	January 2017
Alkaline hydrothermal stabilization of Cr(VI) in soil using glass and aluminum from recycled municipal solid wastes Gattullo, Concetta Eliana; D’Alessandro, Caterina; Allegretta, Ignazio Journal of Hazardous Materials, Vol. 344 https://doi.org/10.1016/j.jhazmat.2017.10.035	journal	February 2018
Speciation of metal(loid)s in environmental samples by X-ray absorption spectroscopy: A critical review Gräfe, Markus; Donner, Erica; Collins, Richard N. Analytica Chimica Acta, Vol. 822 https://doi.org/10.1016/j.aca.2014.02.044	journal	April 2014
Experimental investigation of As, Sb and Cs behavior during olivine serpentinization in hydrothermal alkaline systems Lafay, Romain; Montes-Hernandez, German; Janots, Emilie Geochimica et Cosmochimica Acta, Vol. 179 https://doi.org/10.1016/j.gca.2016.02.014	journal	April 2016
Advances in element speciation analysis of biomedical samples using synchrotron-based techniques Porcaro, Francesco; Roudeau, Stéphane; Carmona, Asuncion TrAC Trends in Analytical Chemistry, Vol. 104 https://doi.org/10.1016/j.trac.2017.09.016	journal	July 2018
Phase retrieval and differential phase-contrast imaging with low-brilliance X-ray sources Pfeiffer, Franz; Weitkamp, Timm; Bunk, Oliver Nature Physics, Vol. 2, Issue 4, p. 258-261 https://doi.org/10.1038/nphys265	journal	March 2006
Synchrotron radiation total reflection X-ray fluorescence (SR-TXRF) and X-ray absorption near edge structure (XANES) of fractionated air particulates collected from Jeddah, Saudi Arabia Shaltout, Abdallah A.; Harfouche, Messaoud; Ahmed, Sameh I. Microchemical Journal, Vol. 137 https://doi.org/10.1016/j.microc.2017.10.001	journal	March 2018
X-ray elemental mapping techniques for elucidating the ecophysiology of hyperaccumulator plants van der Ent, Antony; Przybyłowicz, Wojciech J.; de Jonge, Martin D. New Phytologist, Vol. 218, Issue 2 https://doi.org/10.1111/nph.14810	journal	October 2017
Survey analysis and chemical characterization of solid inhomogeneous samples using a general homogenization procedure including acid digestion, drying, grinding and briquetting together with X-ray fluorescence Sahlin, Eskil; Magnusson, Bertil Talanta, Vol. 97 https://doi.org/10.1016/j.talanta.2012.03.063	journal	August 2012
Molybdenum in natural waters: A review of occurrence, distributions and controls Smedley, Pauline L.; Kinniburgh, David G. Applied Geochemistry, Vol. 84 https://doi.org/10.1016/j.apgeochem.2017.05.008	journal	September 2017
Laterally resolved speciation of arsenic in roots of wheat and rice using fluorescence-XANES imaging Kopittke, Peter M.; de Jonge, Martin D.; Wang, Peng New Phytologist, Vol. 201, Issue 4 https://doi.org/10.1111/nph.12595	journal	November 2013
Processes conducive to the release and transport of arsenic into aquifers of Bangladesh Polizzotto, M. L.; Harvey, C. F.; Sutton, S. R. Proceedings of the National Academy of Sciences, Vol. 102, Issue 52 https://doi.org/10.1073/pnas.0509539103	journal	December 2005
Field evaluation of a near–real time elemental monitor and identification of element sources observed at an air monitoring supersite in Korea Park, Seung–Shik; Cho, Sung–Yong; Jo, Mi–Ra Atmospheric Pollution Research, Vol. 5, Issue 1 https://doi.org/10.5094/APR.2014.015	journal	January 2014
Quantitative assessment of worldwide contamination of air, water and soils by trace metals Nriagu, Jerome O.; Pacyna, Jozef M. Nature, Vol. 333, Issue 6169 https://doi.org/10.1038/333134a0	journal	May 1988
Spatially resolved micro-X-ray fluorescence and micro-X-ray absorption fine structure study of a fractured granite bore core following a radiotracer experiment Denecke, Melissa A.; Brendebach, Boris; De Nolf, Wout Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 64, Issue 8 https://doi.org/10.1016/j.sab.2009.05.025	journal	August 2009
Actinide speciation using synchrotron-based methods Denecke, Melissa A. Journal of Radioanalytical and Nuclear Chemistry, Vol. 303, Issue 2 https://doi.org/10.1007/s10967-014-3493-3	journal	August 2014
φXANES: In vivo imaging of metal-protein coordination environments James, Simon A.; Hare, Dominic J.; Jenkins, Nicole L. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep20350	journal	February 2016
Synchrotron-based X-Ray Approaches for Examining Toxic Trace Metal(loid)s in Soil-Plant Systems Kopittke, Peter M.; Wang, Peng; Lombi, Enzo Journal of Environmental Quality, Vol. 46, Issue 6 https://doi.org/10.2134/jeq2016.09.0361	journal	November 2017
In situ analysis of metal(loid)s in plants: State of the art and artefacts Lombi, Enzo; Scheckel, Kirk G.; Kempson, Ivan M. Environmental and Experimental Botany, Vol. 72, Issue 1 https://doi.org/10.1016/j.envexpbot.2010.04.005	journal	August 2011
Fast X-Ray Fluorescence Microtomography of Hydrated Biological Samples Lombi, Enzo; de Jonge, Martin D.; Donner, Erica PLoS ONE, Vol. 6, Issue 6 https://doi.org/10.1371/journal.pone.0020626	journal	June 2011
Determination of As concentration in earthworm coelomic fluid extracts by total-reflection X-ray fluorescence spectrometry Allegretta, Ignazio; Porfido, Carlo; Panzarino, Onofrio Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 130 https://doi.org/10.1016/j.sab.2017.02.003	journal	April 2017
Source apportionment of size and time resolved trace elements and organic aerosols from an urban courtyard site in Switzerland Richard, A.; Gianini, M. F. D.; Mohr, C. Atmospheric Chemistry and Physics, Vol. 11, Issue 17 https://doi.org/10.5194/acp-11-8945-2011	journal	January 2011
Impurities in multicrystalline silicon wafers for solar cells detected by synchrotron micro-beam X-ray fluorescence analysis Buzanich, Günter; Radtke, Martin; Reinholz, Uwe Journal of Analytical Atomic Spectrometry, Vol. 27, Issue 11 https://doi.org/10.1039/c2ja30188a	journal	January 2012
Visualising coordination chemistry: fluorescence X-ray absorption near edge structure tomography James, S. A.; Burke, R.; Howard, D. L. Chemical Communications, Vol. 52, Issue 79 https://doi.org/10.1039/C6CC06747F	journal	January 2016
Using synchrotron X-ray fluorescence microprobes in the study of metal homeostasis in plants Punshon, Tracy; Guerinot, Mary Lou; Lanzirotti, Antonio Annals of Botany, Vol. 103, Issue 5 https://doi.org/10.1093/aob/mcn264	journal	January 2009
Elemental composition of ambient aerosols measured with high temporal resolution using an online XRF spectrometer Furger, Markus; Minguillón, María Cruz; Yadav, Varun Atmospheric Measurement Techniques, Vol. 10, Issue 6 https://doi.org/10.5194/amt-10-2061-2017	journal	January 2017
An assessment of global and regional emissions of trace metals to the atmosphere from anthropogenic sources worldwide Pacyna, J. M.; Pacyna, E. G. Environmental Reviews, Vol. 9, Issue 4 https://doi.org/10.1139/a01-012	journal	December 2001
Cellular compartmentation of cadmium and zinc in relation to other elements in the hyperaccumulator Arabidopsis halleri Küpper, Hendrik; Lombi, Enzo; Zhao, Fang-Jie Planta, Vol. 212, Issue 1 https://doi.org/10.1007/s004250000366	journal	December 2000
Synchrotron-based techniques for plant and soil science: opportunities, challenges and future perspectives Lombi, Enzo; Susini, Jean Plant and Soil, Vol. 320, Issue 1-2 https://doi.org/10.1007/s11104-008-9876-x	journal	January 2009
The Broad Scope of Health Effects from Chronic Arsenic Exposure: Update on a Worldwide Public Health Problem Naujokas, Marisa F.; Anderson, Beth; Ahsan, Habibul Environmental Health Perspectives, Vol. 121, Issue 3 https://doi.org/10.1289/ehp.1205875	journal	March 2013
Cellular compartmentation of nickel in the hyperaccumulators Alyssum lesbiacum, Alyssum bertolonii and Thlaspi goesingense Küpper, Hendrik; Lombi, Enzo; Zhao, Fang‐Jie Journal of Experimental Botany, Vol. 52, Issue 365 https://doi.org/10.1093/jexbot/52.365.2291	journal	December 2001
Focusing of X-ray free-electron laser pulses with reflective optics Yumoto, Hirokatsu; Mimura, Hidekazu; Koyama, Takahisa Nature Photonics, Vol. 7, Issue 1 https://doi.org/10.1038/nphoton.2012.306	journal	December 2012
Accumulation of heavy metals and trace elements in fluvial sediments received effluents from traditional and semiconductor industries Hsu, Liang-Ching; Huang, Ching-Yi; Chuang, Yen-Hsun Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep34250	journal	September 2016
Pathways of coupled arsenic and iron cycling in high arsenic groundwater of the Hetao basin, Inner Mongolia, China: An iron isotope approach Guo, Huaming; Liu, Chen; Lu, Hai Geochimica et Cosmochimica Acta, Vol. 112 https://doi.org/10.1016/j.gca.2013.02.031	journal	July 2013
Applications of synchrotron μ-XRF to study the distribution of biologically important elements in different environmental matrices: A review Majumdar, Sanghamitra; Peralta-Videa, Jose R.; Castillo-Michel, Hiram Analytica Chimica Acta, Vol. 755 https://doi.org/10.1016/j.aca.2012.09.050	journal	November 2012
Functional characterisation of metal(loid) processes in planta through the integration of synchrotron techniques and plant molecular biology Donner, Erica; Punshon, Tracy; Guerinot, Mary Lou Analytical and Bioanalytical Chemistry, Vol. 402, Issue 10 https://doi.org/10.1007/s00216-011-5624-9	journal	December 2011
Characterization of a polycapillary lens for use in micro-XANES experiments Proost, K.; Vincze, L.; Janssens, K. X-Ray Spectrometry, Vol. 32, Issue 3 https://doi.org/10.1002/xrs.635	journal	January 2003
Quantitative mapping of the oxidative effects of mantle metasomatism Berry, Andrew J.; Yaxley, Gregory M.; Hanger, Brendan J. Geology, Vol. 41, Issue 6 https://doi.org/10.1130/G34119.1	journal	June 2013
Natural gold particles in Eucalyptus leaves and their relevance to exploration for buried gold deposits Lintern, Melvyn; Anand, Ravi; Ryan, Chris Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3614	journal	October 2013
Review of semiconductor drift detectors Gatti, Emilio; Rehak, Pavel Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 541, Issue 1-2 https://doi.org/10.1016/j.nima.2005.01.037	journal	April 2005
Imaging element distribution and speciation in plant cells Zhao, Fang-Jie; Moore, Katie L.; Lombi, Enzo Trends in Plant Science, Vol. 19, Issue 3 https://doi.org/10.1016/j.tplants.2013.12.001	journal	March 2014
Quantified, multi-scale X-ray fluorescence element mapping using the Maia detector array: application to mineral deposit studies Fisher, Louise A.; Fougerouse, Denis; Cleverley, James S. Mineralium Deposita, Vol. 50, Issue 6 https://doi.org/10.1007/s00126-014-0562-z	journal	November 2014
Does Fe accumulation in durum wheat seeds benefit from improved whole-plant sulfur nutrition? Astolfi, Stefania; Pii, Youry; Terzano, Roberto Journal of Cereal Science, Vol. 83 https://doi.org/10.1016/j.jcs.2018.07.010	journal	September 2018
Optimizing detector geometry for trace element mapping by X-ray fluorescence Sun, Yue; Gleber, Sophie-Charlotte; Jacobsen, Chris Ultramicroscopy, Vol. 152 https://doi.org/10.1016/j.ultramic.2014.12.014	journal	May 2015
Cellular Compartmentation of Zinc in Leaves of the Hyperaccumulator Thlaspi caerulescens Küpper, Hendrik; Jie Zhao, Fang; McGrath, Steve P. Plant Physiology, Vol. 119, Issue 1 https://doi.org/10.1104/pp.119.1.305	journal	January 1999
Direct in vivo imaging of essential bioinorganics in Caenorhabditis elegans James, Simon A.; de Jonge, Martin D.; Howard, Daryl L. Metallomics, Vol. 5, Issue 6 https://doi.org/10.1039/c3mt00010a	journal	January 2013
Cellular Fractionation and Nanoscopic X-Ray Fluorescence Imaging Analyses Reveal Changes of Zinc Distribution in Leaf Cells of Iron-Deficient Plants Vigani, Gianpiero; Bohic, Sylvain; Faoro, Franco Frontiers in Plant Science, Vol. 9 https://doi.org/10.3389/fpls.2018.01112	journal	August 2018
Elemental Characterization of Commercial Mate Tea Leaves ( Ilex paraguariensis A. St.-Hil.) before and after Hot Water Infusion Using Ion Beam Techniques Giulian, Raquel; Iochims dos Santos, Carla Eliete; de Moraes Shubeita, Samir Journal of Agricultural and Food Chemistry, Vol. 55, Issue 3 https://doi.org/10.1021/jf062456r	journal	February 2007
Application of the fundamental parameter method to the in vivo x-ray fluorescence analysis of Pt Szalóki, I.; Lewis, D. G.; Bennett, C. A. Physics in Medicine and Biology, Vol. 44, Issue 5 https://doi.org/10.1088/0031-9155/44/5/012	journal	January 1999
Speciation change and redistribution of arsenic in soil under anaerobic microbial activities Xu, Liying; Wu, Xi; Wang, Shaofeng Journal of Hazardous Materials, Vol. 301 https://doi.org/10.1016/j.jhazmat.2015.09.030	journal	January 2016
In vivo formation of natural HgSe nanoparticles in the liver and brain of pilot whales Gajdosechova, Zuzana; Lawan, Mohammed M.; Urgast, Dagmar S. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep34361	journal	September 2016
Arsenic distribution and speciation in the fronds of the hyperaccumulator Pteris vittata Lombi, Enzo; Zhao, Fang-Jie; Fuhrmann, Mark New Phytologist, Vol. 156, Issue 2 https://doi.org/10.1046/j.1469-8137.2002.00512.x	journal	November 2002
X-ray Spectrometry Tsuji, Kouichi; Nakano, Kazuhiko; Takahashi, Yoshio Analytical Chemistry, Vol. 84, Issue 2 https://doi.org/10.1021/ac202871b	journal	December 2011
The Topobiology of Chemical Elements in Seabird Feathers R. Howell, Nicholas; Lavers, Jennifer L.; Uematsu, Sayaka Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-01878-y	journal	May 2017
Sub-5 nm hard x-ray point focusing by a combined Kirkpatrick-Baez mirror and multilayer zone plate Döring, F.; Robisch, A. L.; Eberl, C. Optics Express, Vol. 21, Issue 16 https://doi.org/10.1364/OE.21.019311	journal	January 2013
A new pnCCD-based color X-ray camera for fast spatial and energy-resolved measurements Ordavo, I.; Ihle, S.; Arkadiev, V. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 654, Issue 1 https://doi.org/10.1016/j.nima.2011.05.080	journal	October 2011
Speciation mapping of environmental samples using XANES imaging Etschmann, Barbara E.; Donner, Erica; Brugger, Joël Environmental Chemistry, Vol. 11, Issue 3 https://doi.org/10.1071/EN13189	journal	January 2014
Synchrotron-based X-ray absorption near-edge spectroscopy imaging for laterally resolved speciation of selenium in fresh roots and leaves of wheat and rice Wang, Peng; Menzies, Neal W.; Lombi, Enzo Journal of Experimental Botany, Vol. 66, Issue 15 https://doi.org/10.1093/jxb/erv254	journal	May 2015
Relative Bioavailability and Bioaccessibility and Speciation of Arsenic in Contaminated Soils Bradham, Karen D.; Scheckel, Kirk G.; Nelson, Clay M. Environmental Health Perspectives, Vol. 119, Issue 11 https://doi.org/10.1289/ehp.1003352	journal	November 2011
Elements of Modern X-ray Physics Als-Nielsen, Jens; McMorrow, Des https://doi.org/10.1002/9781119998365	book	March 2011
Recent trends in quantitative aspects of microscopic X-ray fluorescence analysis Janssens, Koen; De Nolf, Wout; Van Der Snickt, Geert TrAC Trends in Analytical Chemistry, Vol. 29, Issue 6 https://doi.org/10.1016/j.trac.2010.03.003	journal	June 2010
X-Ray Charge Densities and Chemical Bonding Coppens, Philip https://doi.org/10.1093/oso/9780195098235.001.0001	book	June 1997
Quasi-monoenergetic and tunable X-rays from a laser-driven Compton light source Powers, N. D.; Ghebregziabher, I.; Golovin, G. Nature Photonics, Vol. 8, Issue 1 https://doi.org/10.1038/nphoton.2013.314	journal	November 2013
Confocal μ-XRF depth analysis of paint layers Šmit, Ž.; Janssens, K.; Proost, K. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 219-220 https://doi.org/10.1016/j.nimb.2004.01.024	journal	June 2004
Development of confocal X-ray fluorescence (XRF) microscopy at the Cornell high energy synchrotron source Woll, A. R.; Mass, J.; Bisulca, C. Applied Physics A, Vol. 83, Issue 2 https://doi.org/10.1007/s00339-006-3513-4	journal	March 2006
Trends in X-ray Fluorescence Microscopy Vogt, Stefan; Lanzirotti, Antonio Synchrotron Radiation News, Vol. 26, Issue 2 https://doi.org/10.1080/08940886.2013.771072	journal	March 2013
Maia X-ray Microprobe Detector Array System Siddons, D. P.; Kirkham, R.; Ryan, C. G. Journal of Physics: Conference Series, Vol. 499 https://doi.org/10.1088/1742-6596/499/1/012001	journal	April 2014
Maia X-ray fluorescence imaging: Capturing detail in complex natural samples Ryan, C. G.; Siddons, D. P.; Kirkham, R. Journal of Physics: Conference Series, Vol. 499 https://doi.org/10.1088/1742-6596/499/1/012002	journal	April 2014
Chromium Barceloux, Donald G.; Barceloux, Donald Journal of Toxicology: Clinical Toxicology, Vol. 37, Issue 2 https://doi.org/10.1081/CLT-100102418	journal	January 1999
Focused X-Ray Histological Analyses to Reveal Asbestos Fibers and Bodies in Lungs and Pleura of Asbestos-Exposed Subjects Pascolo, Lorella; Gianoncelli, Alessandra; Rizzardi, Clara Microscopy and Microanalysis, Vol. 22, Issue 5 https://doi.org/10.1017/S1431927616011685	journal	September 2016
Intracellular localization of titanium dioxide-biomolecule nanocomposites Paunesku, T.; Stojicevic, N.; Vogt, S. Journal de Physique IV (Proceedings), Vol. 104 https://doi.org/10.1051/jp4:200300089	journal	March 2003
Total reflection X-ray fluorescence analysis of fly ash from Bulgarian coal-fired power plants Detcheva, Albena K.; Mitsiev, Svilen E.; Vassileva, Paunka S. Chemical Papers, Vol. 69, Issue 5 https://doi.org/10.1515/chempap-2015-0071	journal	January 2015
Field-portable-XRF reveals the ubiquity of antimony in plastic consumer products Turner, Andrew; Filella, Montserrat Science of The Total Environment, Vol. 584-585 https://doi.org/10.1016/j.scitotenv.2017.01.149	journal	April 2017
Elemental and Single Particle Aerosol Characterisation at a Background Station in Kazakhstan Hoornaert, Stefaan; Godoi, Ricardo Henrique Moreton; Van Grieken, René Journal of Atmospheric Chemistry, Vol. 48, Issue 3 https://doi.org/10.1023/B:JOCH.0000044432.74476.b0	journal	July 2004
Fast X-ray microfluorescence imaging with submicrometer-resolution integrating a Maia detector at beamline P06 at PETRA III Boesenberg, Ulrike; Ryan, Christopher G.; Kirkham, Robin Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2016-04604	text	January 2016

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