Spin Stripe Order in a Square Planar Trilayer Nickelate

Zhang, Junjie; Pajerowski, Daniel M.; Botana, Antia S.; Zheng, Hong; Harriger, Leland W.; Rodriguez-Rivera, J A.; Ruff, Jacob P. C.; Schreiber, N. J.; Wang, Bixia; Chen, Yu-Sheng; Chen, W. C.; Norman, M. R.; Rosenkranz, Stephen; Mitchell, John F.; Phelan, Daniel

doi:10.1103/physrevlett.122.247201

Title: Spin Stripe Order in a Square Planar Trilayer Nickelate

Journal Article · Tue Jun 18 00:00:00 EDT 2019 · Physical Review Letters

DOI:https://doi.org/10.1103/physrevlett.122.247201· OSTI ID:1528697

^[1];

^[2]; Botana, Antia S. ^[3]; Zheng, Hong ^[4]; Harriger, Leland W. ^[5]; Rodriguez-Rivera, J A. ^[6]; Ruff, Jacob P. C. ^[7]; Schreiber, N. J. ^[7]; Wang, Bixia ^[4]; Chen, Yu-Sheng ^[8]; Chen, W. C. ^[6]; Norman, M. R. ^[4]; Rosenkranz, Stephen ^[4]; Mitchell, John F. ^[4]; Phelan, Daniel ^[4]

Argonne National Lab. (ANL), Argonne, IL (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Arizona State Univ., Tempe, AZ (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Univ. of Maryland, College Park, MD (United States)
Cornell Univ., Ithaca, NY (United States)
Univ. of Chicago, IL (United States)

In this study, trilayer nickelates, which exhibit a high degree of orbital polarization combined with an electron count (d^8.67) corresponding to overdoped cuprates, have been identified as a promising candidate platform for achieving high-T_c superconductivity. One such material, La₄Ni₃O₈, undergoes a semiconductor-insulator transition at ∼105 K, which was recently shown to arise from the formation of charge stripes. However, an outstanding issue has been the origin of an anomaly in the magnetic susceptibility at the transition and whether it signifies the formation of spin stripes akin to single layer nickelates. Here we report single crystal neutron diffraction measurements (both polarized and unpolarized) that establish that the ground state is indeed magnetic. The ordering is modeled as antiferromagnetic spin stripes that are commensurate with the charge stripes, the magnetic ordering occurring in individual trilayers that are essentially uncorrelated along the crystallographic c axis. Lastly, a comparison of the charge and spin stripe order parameters reveals that, in contrast to single-layer nickelates such as La_2-xSr_xNiO₄ as well as related quasi-2D oxides including manganites, cobaltates, and cuprates, these orders uniquely appear simultaneously, thus demonstrating a stronger coupling between spin and charge than in these related low-dimensional correlated oxides.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1528697

Alternate ID(s):: OSTI ID: 1546408

Journal Information:: Physical Review Letters, Vol. 122, Issue 24; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 33 works

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