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Measuring the x-ray irradiated degradation of PMMA through FTIR and 2D-COS analysis

Technical Report ·
DOI:https://doi.org/10.2172/1526926· OSTI ID:1526926
 [1]
  1. Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

To combat issues arising from polymer aging studies which include wasting valuable time and resources, Two-Dimensional Correlation Spectroscopy (2D-COS) has been observed to identify accelerated aging conditions in materials in a very short timeframe. This study is attempting to validate 2D-COS as a viable technique for aging studies by measuring the degradation of PMMA via x-ray radiation. PMMA has been previously observed to degrade via main chain scission under x-ray radiation, and similar results have possibly been seen in this study. More work needs to be done to collect reliable data, including finalizing a standard operating procedure and normalizing raw data so that noise is not recognized as spectral change by the extremely sensitive 2D-COS software.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
DOE Contract Number:
89233218CNA000001
OSTI ID:
1526926
Report Number(s):
LA-UR-19-25455
Country of Publication:
United States
Language:
English

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