Ultrafine Pt Nanoparticle-Decorated Pyrite-Type CoS 2 Nanosheet Arrays Coated on Carbon Cloth as a Bifunctional Electrode for Overall Water Splitting
Abstract
To improve the utilization efficiency of precious metals, metal-supported materials provide a direction for fabricating highly active and stable heterogeneous catalysts. Here, carbon cloth (CC)-supported Earth-abundant CoS2 nanosheet arrays (CoS2/CC) are presented as ideal substrates for ultrafine Pt deposition (Pt-CoS2/CC) to achieve remarkable performance toward the hydrogen and oxygen evolution reactions (HER/OER) in alkaline solutions. Notably, the Pt-CoS2/CC hybrid delivers an overpotential of 24 mV at 10 mA cm–2 and a mass activity of 3.89 A Ptmg–1, which is 4.7 times higher than that of commercial Pt/C, at an overpotential of 130 mV for catalyzing the HER. An alkali-electrolyzer using Pt-CoS2/CC as a bifunctional electrode enables a water-splitting current density of 10 mA cm–2 at a low voltage of 1.55 V and can sustain for more than 20 h, which is superior to that of the state-of-the-art Pt/C+RuO2 catalyst. Further experimental and theoretical simulation studies demonstrate that strong electronic interaction between Pt and CoS2 synergistically optimize hydrogen adsorption/desorption behaviors and facilitate the in situ generation of OER active species, enhancing the overall water-splitting performance. This research highlights the regulation of interfacial and electronic synergy in pursuit of highly efficient and durable supported catalysts for hydrogen and oxygen electrocatalytic applications.
- Authors:
-
- Tianjin Univ. (China)
- Shandong Univ., Jinan (China)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- National Natural Science Foundation of China (NSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1526674
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 24; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; active sites; nanocomposite; Pt nanoparticles; pyrite CoS2; water splitting
Citation Formats
Han, Xiaopeng, Wu, Xiaoyu, Deng, Yida, Liu, Jian, Lu, Jun, Zhong, Cheng, and Hu, Wenbin. Ultrafine Pt Nanoparticle-Decorated Pyrite-Type CoS 2 Nanosheet Arrays Coated on Carbon Cloth as a Bifunctional Electrode for Overall Water Splitting. United States: N. p., 2018.
Web. doi:10.1002/aenm.201800935.
Han, Xiaopeng, Wu, Xiaoyu, Deng, Yida, Liu, Jian, Lu, Jun, Zhong, Cheng, & Hu, Wenbin. Ultrafine Pt Nanoparticle-Decorated Pyrite-Type CoS 2 Nanosheet Arrays Coated on Carbon Cloth as a Bifunctional Electrode for Overall Water Splitting. United States. https://doi.org/10.1002/aenm.201800935
Han, Xiaopeng, Wu, Xiaoyu, Deng, Yida, Liu, Jian, Lu, Jun, Zhong, Cheng, and Hu, Wenbin. 2018.
"Ultrafine Pt Nanoparticle-Decorated Pyrite-Type CoS 2 Nanosheet Arrays Coated on Carbon Cloth as a Bifunctional Electrode for Overall Water Splitting". United States. https://doi.org/10.1002/aenm.201800935. https://www.osti.gov/servlets/purl/1526674.
@article{osti_1526674,
title = {Ultrafine Pt Nanoparticle-Decorated Pyrite-Type CoS 2 Nanosheet Arrays Coated on Carbon Cloth as a Bifunctional Electrode for Overall Water Splitting},
author = {Han, Xiaopeng and Wu, Xiaoyu and Deng, Yida and Liu, Jian and Lu, Jun and Zhong, Cheng and Hu, Wenbin},
abstractNote = {To improve the utilization efficiency of precious metals, metal-supported materials provide a direction for fabricating highly active and stable heterogeneous catalysts. Here, carbon cloth (CC)-supported Earth-abundant CoS2 nanosheet arrays (CoS2/CC) are presented as ideal substrates for ultrafine Pt deposition (Pt-CoS2/CC) to achieve remarkable performance toward the hydrogen and oxygen evolution reactions (HER/OER) in alkaline solutions. Notably, the Pt-CoS2/CC hybrid delivers an overpotential of 24 mV at 10 mA cm–2 and a mass activity of 3.89 A Ptmg–1, which is 4.7 times higher than that of commercial Pt/C, at an overpotential of 130 mV for catalyzing the HER. An alkali-electrolyzer using Pt-CoS2/CC as a bifunctional electrode enables a water-splitting current density of 10 mA cm–2 at a low voltage of 1.55 V and can sustain for more than 20 h, which is superior to that of the state-of-the-art Pt/C+RuO2 catalyst. Further experimental and theoretical simulation studies demonstrate that strong electronic interaction between Pt and CoS2 synergistically optimize hydrogen adsorption/desorption behaviors and facilitate the in situ generation of OER active species, enhancing the overall water-splitting performance. This research highlights the regulation of interfacial and electronic synergy in pursuit of highly efficient and durable supported catalysts for hydrogen and oxygen electrocatalytic applications.},
doi = {10.1002/aenm.201800935},
url = {https://www.osti.gov/biblio/1526674},
journal = {Advanced Energy Materials},
issn = {1614-6832},
number = 24,
volume = 8,
place = {United States},
year = {Mon Jul 02 00:00:00 EDT 2018},
month = {Mon Jul 02 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Kinetics and Mechanistic Aspects of the Oxygen Evolution Reaction at Hydrous Iron Oxide Films in Base
journal, December 2012
- Doyle, R. L.; Lyons, M. E. G.
- Journal of The Electrochemical Society, Vol. 160, Issue 2
Electronic and Morphological Dual Modulation of Cobalt Carbonate Hydroxides by Mn Doping toward Highly Efficient and Stable Bifunctional Electrocatalysts for Overall Water Splitting
journal, June 2017
- Tang, Tang; Jiang, Wen-Jie; Niu, Shuai
- Journal of the American Chemical Society, Vol. 139, Issue 24
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
journal, October 2006
- Greeley, Jeff; Jaramillo, Thomas F.; Bonde, Jacob
- Nature Materials, Vol. 5, Issue 11, p. 909-913
Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006
- Lewis, N. S.; Nocera, D. G.
- Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
Hierarchical NiCo 2 S 4 Nanowire Arrays Supported on Ni Foam: An Efficient and Durable Bifunctional Electrocatalyst for Oxygen and Hydrogen Evolution Reactions
journal, April 2016
- Sivanantham, Arumugam; Ganesan, Pandian; Shanmugam, Sangaraju
- Advanced Functional Materials, Vol. 26, Issue 26
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
journal, October 2014
- Kärkäs, Markus D.; Verho, Oscar; Johnston, Eric V.
- Chemical Reviews, Vol. 114, Issue 24
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
journal, January 2015
- Nie, Yao; Li, Li; Wei, Zidong
- Chemical Society Reviews, Vol. 44, Issue 8
Ultrafine Pt Nanoparticle-Decorated Co(OH) 2 Nanosheet Arrays with Enhanced Catalytic Activity toward Hydrogen Evolution
journal, September 2017
- Xing, Zhicai; Han, Ce; Wang, Dewen
- ACS Catalysis, Vol. 7, Issue 10
Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts
journal, January 2012
- Cheng, Fangyi; Chen, Jun
- Chemical Society Reviews, Vol. 41, Issue 6, p. 2172-2192
Atomically Thin Mesoporous Co 3 O 4 Layers Strongly Coupled with N-rGO Nanosheets as High-Performance Bifunctional Catalysts for 1D Knittable Zinc-Air Batteries
journal, December 2017
- Li, Yingbo; Zhong, Cheng; Liu, Jie
- Advanced Materials, Vol. 30, Issue 4
One-Step Synthesis of CoS-Doped β-Co(OH) 2 @Amorphous MoS 2+ x Hybrid Catalyst Grown on Nickel Foam for High-Performance Electrochemical Overall Water Splitting
journal, August 2016
- Yoon, Taeseung; Kim, Kwang S.
- Advanced Functional Materials, Vol. 26, Issue 41
High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS 2 ) Micro- and Nanostructures
journal, June 2014
- Faber, Matthew S.; Dziedzic, Rafal; Lukowski, Mark A.
- Journal of the American Chemical Society, Vol. 136, Issue 28
Design of Efficient Bifunctional Oxygen Reduction/Evolution Electrocatalyst: Recent Advances and Perspectives
journal, July 2017
- Huang, Zhen-Feng; Wang, Jiong; Peng, Yuecheng
- Advanced Energy Materials, Vol. 7, Issue 23
Chemical Transformation from FePt to Fe 1 - x PtM x (M = Ru, Ni, Sn) Nanocrystals by a Cation Redox Reaction: X-ray Absorption Spectroscopic Studies
journal, February 2007
- Wang, Di-Yan; Chen, Ching-Hsiang; Yen, Hung-Chi
- Journal of the American Chemical Society, Vol. 129, Issue 6
Nanoscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis
journal, August 2014
- Gong, Ming; Zhou, Wu; Tsai, Mon-Che
- Nature Communications, Vol. 5, Issue 1
Ultrafine Metal Nanoparticles/N-Doped Porous Carbon Hybrids Coated on Carbon Fibers as Flexible and Binder-Free Water Splitting Catalysts
journal, April 2017
- Zhang, Yongqi; Xia, Xinhui; Cao, Xun
- Advanced Energy Materials, Vol. 7, Issue 15
Electrochemical approach to prepare integrated air electrodes for highly stretchable zinc-air battery array with tunable output voltage and current for wearable electronics
journal, September 2017
- Qu, Shengxiang; Song, Zhishuang; Liu, Jie
- Nano Energy, Vol. 39
Hydrogenated Uniform Pt Clusters Supported on Porous CaMnO 3 as a Bifunctional Electrocatalyst for Enhanced Oxygen Reduction and Evolution
journal, December 2013
- Han, Xiaopeng; Cheng, Fangyi; Zhang, Tianran
- Advanced Materials, Vol. 26, Issue 13
A class of non-precious metal composite catalysts for fuel cells
journal, September 2006
- Bashyam, Rajesh; Zelenay, Piotr
- Nature, Vol. 443, Issue 7107
An Investigation of Structure−Catalytic Activity Relationship for Pt−Co/C Bimetallic Nanoparticles toward the Oxygen Reduction Reaction
journal, October 2007
- Hwang, Bing Joe; Kumar, Sakkarapalayam Murugesan Senthil; Chen, Ching-Hsiang
- The Journal of Physical Chemistry C, Vol. 111, Issue 42
From Water Oxidation to Reduction: Homologous Ni-Co Based Nanowires as Complementary Water Splitting Electrocatalysts
journal, February 2015
- Peng, Zheng; Jia, Dingsi; Al-Enizi, Abdullah M.
- Advanced Energy Materials, Vol. 5, Issue 9
Morphology-Controllable Synthesis of Zn–Co-Mixed Sulfide Nanostructures on Carbon Fiber Paper Toward Efficient Rechargeable Zinc–Air Batteries and Water Electrolysis
journal, March 2017
- Wu, Xiaoyu; Han, Xiaopeng; Ma, Xiaoya
- ACS Applied Materials & Interfaces, Vol. 9, Issue 14
Porous Multishelled Ni 2 P Hollow Microspheres as an Active Electrocatalyst for Hydrogen and Oxygen Evolution
journal, October 2017
- Sun, Hongming; Xu, Xiaobin; Yan, Zhenhua
- Chemistry of Materials, Vol. 29, Issue 19
Extremely Stable Platinum Nanoparticles Encapsulated in a Zirconia Nanocage by Area-Selective Atomic Layer Deposition for the Oxygen Reduction Reaction
journal, November 2014
- Cheng, Niancai; Banis, Mohammad Norouzi; Liu, Jian
- Advanced Materials, Vol. 27, Issue 2
Reduced Mesoporous Co 3 O 4 Nanowires as Efficient Water Oxidation Electrocatalysts and Supercapacitor Electrodes
journal, July 2014
- Wang, Yongcheng; Zhou, Tong; Jiang, Kun
- Advanced Energy Materials, Vol. 4, Issue 16
Coupling Sub-Nanometric Copper Clusters with Quasi-Amorphous Cobalt Sulfide Yields Efficient and Robust Electrocatalysts for Water Splitting Reaction
journal, January 2017
- Liu, Yipu; Li, Qiuju; Si, Rui
- Advanced Materials, Vol. 29, Issue 13
Octahedral PtNi nanoparticles with controlled surface structure and composition for oxygen reduction reaction
journal, April 2017
- Lu, Yizhong; Thia, Larissa; Fisher, Adrian
- Science China Materials, Vol. 60, Issue 11
Highly Active and Stable Hybrid Catalyst of Cobalt-Doped FeS 2 Nanosheets–Carbon Nanotubes for Hydrogen Evolution Reaction
journal, January 2015
- Wang, Di-Yan; Gong, Ming; Chou, Hung-Lung
- Journal of the American Chemical Society, Vol. 137, Issue 4
Unusual synergistic effects upon incorporation of Fe and/or Ni into mesoporous Co 3 O 4 for enhanced oxygen evolution
journal, January 2014
- Xiao, Changlong; Lu, Xunyu; Zhao, Chuan
- Chemical Communications, Vol. 50, Issue 70
Photo-Promoted Platinum Nanoparticles Decorated MoS 2 @Graphene Woven Fabric Catalyst for Efficient Hydrogen Generation
journal, April 2016
- Li, Xiao; Zhang, Li; Zang, Xiaobei
- ACS Applied Materials & Interfaces, Vol. 8, Issue 17
Noble metal-free hydrogen evolution catalysts for water splitting
journal, January 2015
- Zou, Xiaoxin; Zhang, Yu
- Chemical Society Reviews, Vol. 44, Issue 15
Are Metal Chalcogenides, Nitrides, and Phosphides Oxygen Evolution Catalysts or Bifunctional Catalysts?
journal, August 2017
- Jin, Song
- ACS Energy Letters, Vol. 2, Issue 8
Low pH Electrolytic Water Splitting Using Earth-Abundant Metastable Catalysts That Self-Assemble in Situ
journal, February 2014
- Bloor, Leanne G.; Molina, Pedro I.; Symes, Mark D.
- Journal of the American Chemical Society, Vol. 136, Issue 8
Ultrathin Co 3 O 4 Layers with Large Contact Area on Carbon Fibers as High-Performance Electrode for Flexible Zinc-Air Battery Integrated with Flexible Display
journal, May 2017
- Chen, Xu; Liu, Bin; Zhong, Cheng
- Advanced Energy Materials, Vol. 7, Issue 18
Enhancing Water Oxidation Catalysis on a Synergistic Phosphorylated NiFe Hydroxide by Adjusting Catalyst Wettability
journal, March 2017
- Li, Yibing; Zhao, Chuan
- ACS Catalysis, Vol. 7, Issue 4
Tuning Reaction Rates by Lateral Strain in a Palladium Monolayer
journal, March 2005
- Kibler, Ludwig A.; El-Aziz, Ahmed M.; Hoyer, R�diger
- Angewandte Chemie International Edition, Vol. 44, Issue 14
Nanoparticles in Energy Technology: Examples from Electrochemistry and Catalysis
journal, March 2005
- Raimondi, Fabio; Scherer, Günther G.; Kötz, Rüdiger
- Angewandte Chemie International Edition, Vol. 44, Issue 15
Ultrafine Pt nanoparticles decorated MoS 2 nanosheets with significantly improved hydrogen evolution activity
journal, July 2017
- Ren, Weina; Zhang, Haifeng; Cheng, Chuanwei
- Electrochimica Acta, Vol. 241
NiCo 2 S 4 nanocrystals anchored on nitrogen-doped carbon nanotubes as a highly efficient bifunctional electrocatalyst for rechargeable zinc-air batteries
journal, January 2017
- Han, Xiaopeng; Wu, Xiaoyu; Zhong, Cheng
- Nano Energy, Vol. 31
Enhanced Activity of Gold-Supported Cobalt Oxide for the Electrochemical Evolution of Oxygen
journal, April 2011
- Yeo, Boon Siang; Bell, Alexis T.
- Journal of the American Chemical Society, Vol. 133, Issue 14
In Situ Coupling of Strung Co 4 N and Intertwined N–C Fibers toward Free-Standing Bifunctional Cathode for Robust, Efficient, and Flexible Zn–Air Batteries
journal, August 2016
- Meng, Fanlu; Zhong, Haixia; Bao, Di
- Journal of the American Chemical Society, Vol. 138, Issue 32
Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts
journal, March 2017
- Lin, Lili; Zhou, Wu; Gao, Rui
- Nature, Vol. 544, Issue 7648
Phase and composition controlled synthesis of cobalt sulfide hollow nanospheres for electrocatalytic water splitting
journal, January 2018
- Ma, Xiaoya; Zhang, Wei; Deng, Yida
- Nanoscale, Vol. 10, Issue 10
Oxygen Vacancies Dominated NiS 2 /CoS 2 Interface Porous Nanowires for Portable Zn-Air Batteries Driven Water Splitting Devices
journal, November 2017
- Yin, Jie; Li, Yuxuan; Lv, Fan
- Advanced Materials, Vol. 29, Issue 47
From 3D ZIF Nanocrystals to Co-N x /C Nanorod Array Electrocatalysts for ORR, OER, and Zn-Air Batteries
journal, November 2017
- Amiinu, Ibrahim Saana; Liu, Xiaobo; Pu, Zonghua
- Advanced Functional Materials, Vol. 28, Issue 5
Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces
journal, January 2013
- Sheng, Wenchao; Myint, MyatNoeZin; Chen, Jingguang G.
- Energy & Environmental Science, Vol. 6, Issue 5
CoOOH Nanosheets with High Mass Activity for Water Oxidation
journal, June 2015
- Huang, Junheng; Chen, Junting; Yao, Tao
- Angewandte Chemie International Edition, Vol. 54, Issue 30
Oxygen Electrochemistry as a Cornerstone for Sustainable Energy Conversion
journal, December 2013
- Katsounaros, Ioannis; Cherevko, Serhiy; Zeradjanin, Aleksandar R.
- Angewandte Chemie International Edition, Vol. 53, Issue 1
Shape-controlled synthesis of Pt-Ir nanocubes with preferential (100) orientation and their unusual enhanced electrocatalytic activities
journal, December 2014
- Zhong, Cheng; Liu, Jie; Ni, Zhengyang
- Science China Materials, Vol. 57, Issue 1
Elucidating the alkaline oxygen evolution reaction mechanism on platinum
journal, January 2017
- Favaro, M.; Valero-Vidal, C.; Eichhorn, J.
- Journal of Materials Chemistry A, Vol. 5, Issue 23
Highly Efficient and Durable Pd Hydride Nanocubes Embedded in 2D Amorphous NiB Nanosheets for Oxygen Reduction Reaction
journal, July 2017
- Lu, Yizhong; Wang, Jiong; Peng, Yuecheng
- Advanced Energy Materials, Vol. 7, Issue 21
Atomically Dispersed Copper-Platinum Dual Sites Alloyed with Palladium Nanorings Catalyze the Hydrogen Evolution Reaction
journal, November 2017
- Chao, Tingting; Luo, Xuan; Chen, Wenxing
- Angewandte Chemie International Edition, Vol. 56, Issue 50
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
journal, January 2015
- Jiao, Yan; Zheng, Yao; Jaroniec, Mietek
- Chemical Society Reviews, Vol. 44, Issue 8
Metal–Organic Framework Derived Hybrid Co 3 O 4 -Carbon Porous Nanowire Arrays as Reversible Oxygen Evolution Electrodes
journal, September 2014
- Ma, Tian Yi; Dai, Sheng; Jaroniec, Mietek
- Journal of the American Chemical Society, Vol. 136, Issue 39
Tunable Pt–MoS x Hybrid Catalysts for Hydrogen Evolution
journal, February 2018
- Chia, Xinyi; Sutrisnoh, Nur Ayu Afira; Pumera, Martin
- ACS Applied Materials & Interfaces, Vol. 10, Issue 10
Nanostructured Ti 0.7 Mo 0.3 O 2 Support Enhances Electron Transfer to Pt: High-Performance Catalyst for Oxygen Reduction Reaction
journal, August 2011
- Ho, Van Thi Thanh; Pan, Chun-Jern; Rick, John
- Journal of the American Chemical Society, Vol. 133, Issue 30
A Microribbon Hybrid Structure of CoOx-MoC Encapsulated in N-Doped Carbon Nanowire Derived from MOF as Efficient Oxygen Evolution Electrocatalysts
journal, November 2017
- Huang, Tan; Chen, Yu; Lee, Jong-Min
- Small, Vol. 13, Issue 48
Efficient and Stable Bifunctional Electrocatalysts Ni/Ni x M y (M = P, S) for Overall Water Splitting
journal, March 2016
- Chen, Gao-Feng; Ma, Tian Yi; Liu, Zhao-Qing
- Advanced Functional Materials, Vol. 26, Issue 19
Earth-Abundant Metal Pyrites (FeS 2 , CoS 2 , NiS 2 , and Their Alloys) for Highly Efficient Hydrogen Evolution and Polysulfide Reduction Electrocatalysis
journal, September 2014
- Faber, Matthew S.; Lukowski, Mark A.; Ding, Qi
- The Journal of Physical Chemistry C, Vol. 118, Issue 37
Recent Developments in the Synthesis of Supported Catalysts
journal, June 2015
- Munnik, Peter; de Jongh, Petra E.; de Jong, Krijn P.
- Chemical Reviews, Vol. 115, Issue 14
Enhanced Electrocatalysis of Oxygen Reduction on Pt/TaO x /GC
journal, December 2011
- Awaludin, Zaenal; Suzuki, Masatoshi; Masud, Jahangir
- The Journal of Physical Chemistry C, Vol. 115, Issue 51
Microwave-Assisted Reactant-Protecting Strategy toward Efficient MoS 2 Electrocatalysts in Hydrogen Evolution Reaction
journal, October 2015
- Liu, Ning; Guo, Yulin; Yang, Xiaoyun
- ACS Applied Materials & Interfaces, Vol. 7, Issue 42
Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction
journal, August 2011
- Liang, Yongye; Li, Yanguang; Wang, Hailiang
- Nature Materials, Vol. 10, Issue 10, p. 780-786
Interacting Carbon Nitride and Titanium Carbide Nanosheets for High-Performance Oxygen Evolution
journal, December 2015
- Ma, Tian Yi; Cao, Jian Liang; Jaroniec, Mietek
- Angewandte Chemie International Edition, Vol. 55, Issue 3
Integrating NiCo Alloys with Their Oxides as Efficient Bifunctional Cathode Catalysts for Rechargeable Zinc-Air Batteries
journal, June 2015
- Liu, Xien; Park, Minjoon; Kim, Min Gyu
- Angewandte Chemie International Edition, Vol. 54, Issue 33
Engineering Catalytic Active Sites on Cobalt Oxide Surface for Enhanced Oxygen Electrocatalysis
journal, December 2017
- Han, Xiaopeng; He, Guowei; He, Yu
- Advanced Energy Materials, Vol. 8, Issue 10
Photocatalytic Reduction of CO 2 on TiO 2 and Other Semiconductors
journal, June 2013
- Habisreutinger, Severin N.; Schmidt-Mende, Lukas; Stolarczyk, Jacek K.
- Angewandte Chemie International Edition, Vol. 52, Issue 29
The Role of Anions in Metal Chalcogenide Oxygen Evolution Catalysis: Electrodeposited Thin Films of Nickel Sulfide as “Pre-catalysts”
journal, June 2016
- Mabayoje, Oluwaniyi; Shoola, Ahmed; Wygant, Bryan R.
- ACS Energy Letters, Vol. 1, Issue 1
Strongly Coupled Pd Nanotetrahedron/Tungsten Oxide Nanosheet Hybrids with Enhanced Catalytic Activity and Stability as Oxygen Reduction Electrocatalysts
journal, August 2014
- Lu, Yizhong; Jiang, Yuanyuan; Gao, Xiaohui
- Journal of the American Chemical Society, Vol. 136, Issue 33
Ordered mesoporous Co3O4 spinels as stable, bifunctional, noble metal-free oxygen electrocatalysts
journal, January 2013
- Sa, Young Jin; Kwon, Kyungjung; Cheon, Jae Yeong
- Journal of Materials Chemistry A, Vol. 1, Issue 34
Interface Engineering of MoS 2 /Ni 3 S 2 Heterostructures for Highly Enhanced Electrochemical Overall-Water-Splitting Activity
journal, April 2016
- Zhang, Jian; Wang, Tao; Pohl, Darius
- Angewandte Chemie International Edition, Vol. 55, Issue 23
High-Index Faceted Ni 3 S 2 Nanosheet Arrays as Highly Active and Ultrastable Electrocatalysts for Water Splitting
journal, September 2015
- Feng, Liang-Liang; Yu, Guangtao; Wu, Yuanyuan
- Journal of the American Chemical Society, Vol. 137, Issue 44
Kinetics of the oxygen evolution reaction on NiSn electrodes in alkaline solutions
journal, October 2015
- Jović, B. M.; Lačnjevac, U. Č.; Jović, V. D.
- Journal of Electroanalytical Chemistry, Vol. 754
A Perovskite Nanorod as Bifunctional Electrocatalyst for Overall Water Splitting
journal, December 2016
- Zhu, Yinlong; Zhou, Wei; Zhong, Yijun
- Advanced Energy Materials, Vol. 7, Issue 8
Precise tuning in platinum-nickel/nickel sulfide interface nanowires for synergistic hydrogen evolution catalysis
journal, February 2017
- Wang, Pengtang; Zhang, Xu; Zhang, Jin
- Nature Communications, Vol. 8, Issue 1
Strong Interactions in Supported-Metal Catalysts
journal, March 1981
- Tauster, S. J.; Fung, S. C.; Baker, R. T. K.
- Science, Vol. 211, Issue 4487, p. 1121-1125
First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
journal, January 2013
- Kong, Desheng; Cha, Judy J.; Wang, Haotian
- Energy & Environmental Science, Vol. 6, Issue 12
Superb Alkaline Hydrogen Evolution and Simultaneous Electricity Generation by Pt-Decorated Ni 3 N Nanosheets
journal, September 2016
- Wang, Yuhang; Chen, Long; Yu, Xiaomin
- Advanced Energy Materials, Vol. 7, Issue 2
Architecture of Bimetallic Pt x Co 1− x Electrocatalysts for Oxygen Reduction Reaction As Investigated by X-ray Absorption Spectroscopy
journal, June 2009
- Lai, Feng-Ju; Sarma, Loka Subramanyam; Chou, Hung-Lung
- The Journal of Physical Chemistry C, Vol. 113, Issue 29
Hydrophilic cobalt sulfide nanosheets as a bifunctional catalyst for oxygen and hydrogen evolution in electrolysis of alkaline aqueous solution
journal, January 2018
- Zhu, Mingchao; Zhang, Zhongyi; Zhang, Hu
- Journal of Colloid and Interface Science, Vol. 509
Integrated Three-Dimensional Carbon Paper/Carbon Tubes/Cobalt-Sulfide Sheets as an Efficient Electrode for Overall Water Splitting
journal, January 2016
- Wang, Jun; Zhong, Hai-xia; Wang, Zhong-li
- ACS Nano, Vol. 10, Issue 2
MoS 2 –Ni 3 S 2 Heteronanorods as Efficient and Stable Bifunctional Electrocatalysts for Overall Water Splitting
journal, February 2017
- Yang, Yaqing; Zhang, Kai; Lin, Huanlei
- ACS Catalysis, Vol. 7, Issue 4
Low Overpotential in Vacancy-Rich Ultrathin CoSe 2 Nanosheets for Water Oxidation
journal, October 2014
- Liu, Youwen; Cheng, Hao; Lyu, Mengjie
- Journal of the American Chemical Society, Vol. 136, Issue 44
Ultrathin MoS2 nanosheets growing within an in-situ-formed template as efficient electrocatalysts for hydrogen evolution
journal, February 2015
- Liu, Ning; Yang, Lichun; Wang, Sinong
- Journal of Power Sources, Vol. 275
Tuning Unique Peapod-Like Co(S x Se 1- x ) 2 Nanoparticles for Efficient Overall Water Splitting
journal, May 2017
- Fang, Ling; Li, Wenxiang; Guan, Yongxin
- Advanced Functional Materials, Vol. 27, Issue 24
Atomically and Electronically Coupled Pt and CoO Hybrid Nanocatalysts for Enhanced Electrocatalytic Performance
journal, December 2016
- Meng, Chao; Ling, Tao; Ma, Tian-Yi
- Advanced Materials, Vol. 29, Issue 9
Integrating NiCo Alloys with Their Oxides as Efficient Bifunctional Cathode Catalysts for Rechargeable Zinc-Air Batteries
journal, June 2015
- Liu, Xien; Park, Minjoon; Kim, Min Gyu
- Angewandte Chemie, Vol. 127, Issue 33
Atomically Dispersed Copper-Platinum Dual Sites Alloyed with Palladium Nanorings Catalyze the Hydrogen Evolution Reaction
journal, November 2017
- Chao, Tingting; Luo, Xuan; Chen, Wenxing
- Angewandte Chemie, Vol. 129, Issue 50
Nanoparticles in Energy Technology: Examples from Electrochemistry and Catalysis
journal, July 2005
- Raimondi, Fabio; Scherer, Guenther G.; Koetz, Ruediger
- ChemInform, Vol. 36, Issue 28
CoOOH Nanosheets with High Mass Activity for Water Oxidation
journal, June 2015
- Huang, Junheng; Chen, Junting; Yao, Tao
- Angewandte Chemie, Vol. 127, Issue 30
Interacting Carbon Nitride and Titanium Carbide Nanosheets for High-Performance Oxygen Evolution
journal, December 2015
- Ma, Tian Yi; Cao, Jian Liang; Jaroniec, Mietek
- Angewandte Chemie, Vol. 128, Issue 3
Interface Engineering of MoS 2 /Ni 3 S 2 Heterostructures for Highly Enhanced Electrochemical Overall-Water-Splitting Activity
journal, April 2016
- Zhang, Jian; Wang, Tao; Pohl, Darius
- Angewandte Chemie, Vol. 128, Issue 23
Works referencing / citing this record:
Rational Design of Nanoarray Architectures for Electrocatalytic Water Splitting
journal, January 2019
- Hou, Jungang; Wu, Yunzhen; Zhang, Bo
- Advanced Functional Materials, Vol. 29, Issue 20
Identifying the Activation of Bimetallic Sites in NiCo 2 S 4 @g‐C 3 N 4 ‐CNT Hybrid Electrocatalysts for Synergistic Oxygen Reduction and Evolution
journal, February 2019
- Han, Xiaopeng; Zhang, Wei; Ma, Xiaoya
- Advanced Materials, Vol. 31, Issue 18
Reducing the Barrier Energy of Self‐Reconstruction for Anchored Cobalt Nanoparticles as Highly Active Oxygen Evolution Electrocatalyst
journal, June 2019
- Kim, Myeongjin; Lee, Byeongyong; Ju, Hyun
- Advanced Materials
Ultrafine α‐Phase Molybdenum Carbide Decorated with Platinum Nanoparticles for Efficient Hydrogen Production in Acidic and Alkaline Media
journal, February 2019
- Song, Hee Jo; Sung, Myeong‐Chang; Yoon, Hyunseok
- Advanced Science, Vol. 6, Issue 8
Mesoporous Decoration of Freestanding Palladium Nanotube Arrays Boosts the Electrocatalysis Capabilities toward Formic Acid and Formate Oxidation
journal, May 2019
- Ding, Jia; Liu, Zhi; Liu, Xiaorui
- Advanced Energy Materials, Vol. 9, Issue 25
Ni/Fe Codoped In 2 S 3 Nanosheet Arrays Boost Photo‐Electrochemical Performance of Planar Si Photocathodes
journal, August 2019
- Meng, Linxing; He, Jinlu; Tian, Wei
- Advanced Energy Materials, Vol. 9, Issue 38
Perowskitoxid‐Elektroden zur leistungsstarken photoelektrochemischen Wasserspaltung
journal, August 2019
- Wang, Wei; Xu, Meigui; Xu, Xiaomin
- Angewandte Chemie, Vol. 132, Issue 1
Tunable Periodically Ordered Mesoporosity in Palladium Membranes Enables Exceptional Enhancement of Intrinsic Electrocatalytic Activity for Formic Acid Oxidation
journal, January 2020
- Ding, Jia; Liu, Zhi; Liu, Xiaorui
- Angewandte Chemie, Vol. 132, Issue 13
Perovskite Oxide Based Electrodes for High‐Performance Photoelectrochemical Water Splitting
journal, August 2019
- Wang, Wei; Xu, Meigui; Xu, Xiaomin
- Angewandte Chemie International Edition, Vol. 59, Issue 1
Tuning Interfacial Structures for Better Catalysis of Water Electrolysis
journal, May 2019
- Xiang, Rui; Peng, Lishan; Wei, Zidong
- Chemistry – A European Journal, Vol. 25, Issue 42
Controlled Synthesis of Ni‐Doped MoS 2 Hybrid Electrode for Synergistically Enhanced Water‐Splitting Process
journal, December 2019
- Wang, Ying; Sun, Wenming; Ling, Xiaofei
- Chemistry – A European Journal
Direct Growth of CNTs@CoS x Se 2(1− x ) on Carbon Cloth for Overall Water Splitting
journal, July 2019
- Zhang, Yuanyuan; Qiu, Yunfeng; Ji, Xinyang
- ChemSusChem, Vol. 12, Issue 16
In Situ Fabrication of Heterostructure on Nickel Foam with Tuned Composition for Enhancing Water‐Splitting Performance
journal, October 2018
- Zheng, Xuerong; Zhang, Yiqi; Liu, Hui
- Small, Vol. 14, Issue 50
Nickel@Nitrogen-Doped Carbon@MoS 2 Nanosheets: An Efficient Electrocatalyst for Hydrogen Evolution Reaction
journal, January 2019
- Shah, Sayyar Ali; Shen, Xiaoping; Xie, Minghua
- Small, Vol. 15, Issue 9
Surface and Interface Engineering: Molybdenum Carbide–Based Nanomaterials for Electrochemical Energy Conversion
journal, September 2019
- Ge, Riyue; Huo, Juanjuan; Sun, Mingjie
- Small
NiS‐Decorated ZnO/ZnS Nanorod Heterostructures for Enhanced Photocatalytic Hydrogen Production: Insight into the Role of NiS
journal, April 2020
- Zhang, Qingsong; Xiao, Yang; Li, Yiming
- Solar RRL, Vol. 4, Issue 4
A ruthenium(IV) disulfide based non-enzymatic sensor for selective and sensitive amperometric determination of dopamine
journal, June 2019
- Deepika, J.; Sha, Rinky; Badhulika, Sushmee
- Microchimica Acta, Vol. 186, Issue 7
Engineering borate modified NiFe layer double hydroxide nanoarrays as “hydroxyl ions hungry” electrocatalysts for enhanced oxygen evolution
journal, January 2019
- Sun, Zemin; Wang, Yutong; Lin, Liu
- Chemical Communications, Vol. 55, Issue 9
Enhanced electrocatalytic activity of water oxidation in an alkaline medium via Fe doping in CoS 2 nanosheets
journal, January 2019
- Kong, Weisu; Luan, Xiaoqian; Du, Huitong
- Chemical Communications, Vol. 55, Issue 17
Controllable synthesis of nickel sulfide nanocatalysts and their phase-dependent performance for overall water splitting
journal, January 2019
- Zheng, Xuerong; Han, Xiaopeng; Zhang, Yiqi
- Nanoscale, Vol. 11, Issue 12
Bifunctional iron disulfide nanoellipsoids for high energy density supercapacitor and electrocatalytic oxygen evolution applications
journal, January 2019
- Sun, Zhiqin; Yang, Xue; Lin, Huiming
- Inorganic Chemistry Frontiers, Vol. 6, Issue 3
Nanoscale hetero-interfaces between metals and metal compounds for electrocatalytic applications
journal, January 2019
- Kwon, Taehyun; Jun, Minki; Joo, Jinwhan
- Journal of Materials Chemistry A, Vol. 7, Issue 10
Ultrafine cobalt nitride nanoparticles supported on carbon nanotubes as efficient electrocatalyst for rechargeable zinc–air batteries
journal, January 2019
- Xu, Ruizhi; Luo, Fang; Li, Min
- Chemical Communications, Vol. 55, Issue 89
The chemically reduced CuO–Co 3 O 4 composite as a highly efficient electrocatalyst for oxygen evolution reaction in alkaline media
journal, January 2019
- Aftab, Umair; Tahira, Aneela; Mazzaro, Raffaello
- Catalysis Science & Technology, Vol. 9, Issue 22
Optimization of the facet structure of cobalt oxide catalysts for enhanced hydrogen evolution reaction
journal, January 2020
- Wu, Minghong; Ke, Shuqiang; Chen, Wenqian
- Catalysis Science & Technology, Vol. 10, Issue 4
Fully reversible lithium storage of tin oxide enabled by self-doping and partial amorphization
journal, January 2019
- Pang, Yuepeng; Wang, Jing; Yang, Junhe
- Nanoscale, Vol. 11, Issue 27
Electrodepositing Pd on NiFe layered double hydroxide for improved water electrolysis
journal, January 2019
- Guo, Jinxue; Sun, Jikang; Sun, Yanfang
- Materials Chemistry Frontiers, Vol. 3, Issue 5
A new metal–organic open framework enabling facile synthesis of carbon encapsulated transition metal phosphide/sulfide nanoparticle electrocatalysts
journal, January 2019
- Weng, Baicheng; Wang, Xiaoming; Grice, Corey R.
- Journal of Materials Chemistry A, Vol. 7, Issue 12
Nanosheets assembled into nickel sulfide nanospheres with enriched Ni 3+ active sites for efficient water-splitting and zinc–air batteries
journal, January 2019
- Shi, Xiangkai; Ling, Xiaofei; Li, Lanlan
- Journal of Materials Chemistry A, Vol. 7, Issue 41
Recent advances and challenges in divalent and multivalent metal electrodes for metal–air batteries
journal, January 2019
- Sun, Yangting; Liu, Xiaorui; Jiang, Yiming
- Journal of Materials Chemistry A, Vol. 7, Issue 31
Fe nanodot-decorated MoS 2 nanosheets on carbon cloth: an efficient and flexible electrode for ambient ammonia synthesis
journal, January 2019
- Zhao, Xinhui; Zhang, Xu; Xue, Zhimin
- Journal of Materials Chemistry A, Vol. 7, Issue 48
Nature of Carbon Materials Used as Nondoped Electrodes for Oxygen Reduction Reaction and Supercapacitor Applications
journal, January 2019
- Zhang, Hui-Juan; Geng, Jing; Yao, Sunwu
- Journal of The Electrochemical Society, Vol. 166, Issue 2
Structure Design and Composition Engineering of Carbon‐Based Nanomaterials for Lithium Energy Storage
journal, March 2020
- Geng, Hongya; Peng, Yan; Qu, Liangti
- Advanced Energy Materials, Vol. 10, Issue 10
Engineering Multimetallic Aerogels for pH‐Universal HER and ORR Electrocatalysis
journal, March 2020
- Du, Ran; Jin, Wei; Hübner, René
- Advanced Energy Materials, Vol. 10, Issue 12
Anchoring ultrafine PtNi nanoparticles on N-doped graphene for highly efficient hydrogen evolution reaction
journal, January 2019
- Bao, Jiehua; Wang, Jiaqi; Zhou, Yuming
- Catalysis Science & Technology, Vol. 9, Issue 18
Advances in the development of power supplies for the Internet of Everything
journal, June 2019
- Fan, Xiayue; Liu, Xiaorui; Hu, Wenbin
- InfoMat
Tunable Periodically Ordered Mesoporosity in Palladium Membranes Enables Exceptional Enhancement of Intrinsic Electrocatalytic Activity for Formic Acid Oxidation
journal, March 2020
- Ding, Jia; Liu, Zhi; Liu, Xiaorui
- Angewandte Chemie International Edition, Vol. 59, Issue 13
Finite-Element Analysis on Percolation Performance of Foam Zinc
journal, September 2018
- Li, Yu; Liu, Jie; Deng, Yida
- ACS Omega, Vol. 3, Issue 9