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Title: CuCo 2O 4 ORR/OER Bi-functional catalyst: Influence of synthetic approach on performance

Abstract

A series of CuCo 2O 4 catalysts were synthesized by pore forming, sol-gel, spray pyrolysis and sacrificial support methods. Catalysts were characterized by XRD, SEM, XPS and BET techniques. The electrochemical activity for the oxygen reduction and oxygen evolution reactions (ORR and OER) was evaluated in alkaline media by RRDE. Density Functional Theory was used to identify two different types of active sites responsible for ORR/OER activity of CuCo 2O 4 and it was found that CuCo 2O 4 can activate the O-O bond by binding molecular oxygen in bridging positions between Co or Co and Cu atoms. It was found that the sacrificial support method (SSM) catalyst has the highest performance in both ORR and OER and has the highest content of phase-pure CuCo 2O 4. It was shown that the presence of CuO significantly decreases the activity in oxygen reduction and oxygen evolution reactions. As a result, the half-wave potential (E 1/2) of CuCo 2O 4-SSM was found as 0.8 V, making this material a state-of-the-art, unsupported oxide catalyst.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Univ. of New Mexico, Albuquerque, NM (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
OSTI Identifier:
1523228
Alternate Identifier(s):
OSTI ID: 1222086
Report Number(s):
LA-UR-14-26548
Journal ID: ISSN 0013-4651
Grant/Contract Number:  
89233218CNA000001; AC05-76RL01830; AC52-06NA25396
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 162; Journal Issue: 4; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; Inorganic and Physical Chemistry; Material Science; Environmental Molecular Sciences Laboratory

Citation Formats

Serov, Alexey, Andersen, Nalin I., Roy, Aaron J., Matanovic, Ivana, Artyushkova, Kateryna, and Atanassov, Plamen. CuCo2O4 ORR/OER Bi-functional catalyst: Influence of synthetic approach on performance. United States: N. p., 2015. Web. doi:10.1149/2.0921504jes.
Serov, Alexey, Andersen, Nalin I., Roy, Aaron J., Matanovic, Ivana, Artyushkova, Kateryna, & Atanassov, Plamen. CuCo2O4 ORR/OER Bi-functional catalyst: Influence of synthetic approach on performance. United States. doi:10.1149/2.0921504jes.
Serov, Alexey, Andersen, Nalin I., Roy, Aaron J., Matanovic, Ivana, Artyushkova, Kateryna, and Atanassov, Plamen. Sat . "CuCo2O4 ORR/OER Bi-functional catalyst: Influence of synthetic approach on performance". United States. doi:10.1149/2.0921504jes. https://www.osti.gov/servlets/purl/1523228.
@article{osti_1523228,
title = {CuCo2O4 ORR/OER Bi-functional catalyst: Influence of synthetic approach on performance},
author = {Serov, Alexey and Andersen, Nalin I. and Roy, Aaron J. and Matanovic, Ivana and Artyushkova, Kateryna and Atanassov, Plamen},
abstractNote = {A series of CuCo2O4 catalysts were synthesized by pore forming, sol-gel, spray pyrolysis and sacrificial support methods. Catalysts were characterized by XRD, SEM, XPS and BET techniques. The electrochemical activity for the oxygen reduction and oxygen evolution reactions (ORR and OER) was evaluated in alkaline media by RRDE. Density Functional Theory was used to identify two different types of active sites responsible for ORR/OER activity of CuCo2O4 and it was found that CuCo2O4 can activate the O-O bond by binding molecular oxygen in bridging positions between Co or Co and Cu atoms. It was found that the sacrificial support method (SSM) catalyst has the highest performance in both ORR and OER and has the highest content of phase-pure CuCo2O4. It was shown that the presence of CuO significantly decreases the activity in oxygen reduction and oxygen evolution reactions. As a result, the half-wave potential (E1/2) of CuCo2O4-SSM was found as 0.8 V, making this material a state-of-the-art, unsupported oxide catalyst.},
doi = {10.1149/2.0921504jes},
journal = {Journal of the Electrochemical Society},
issn = {0013-4651},
number = 4,
volume = 162,
place = {United States},
year = {2015},
month = {2}
}

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Cited by: 31 works
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Works referenced in this record:

A mechanistic study of 4-aminoantipyrine and iron derived non-platinum group metal catalyst on the oxygen reduction reaction
journal, February 2013


CoMn2O4 Spinel Nanoparticles Grown on Graphene as Bifunctional Catalyst for Lithium-Air Batteries
journal, January 2011

  • Wang, Long; Zhao, Xin; Lu, Yuhao
  • Journal of The Electrochemical Society, Vol. 158, Issue 12
  • DOI: 10.1149/2.068112jes

A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation
journal, October 2010

  • Gorlin, Yelena; Jaramillo, Thomas F.
  • Journal of the American Chemical Society, Vol. 132, Issue 39, p. 13612-13614
  • DOI: 10.1021/ja104587v

Highly active PdCu catalysts for electrooxidation of 2-propanol
journal, August 2012


Theoretical Study of Electrochemical Processes on Pt–Ni Alloys
journal, May 2011

  • Matanović, Ivana; Garzon, Fernando H.; Henson, Neil J.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 21
  • DOI: 10.1021/jp111930w

Elucidating Oxygen Reduction Active Sites in Pyrolyzed Metal–Nitrogen Coordinated Non-Precious-Metal Electrocatalyst Systems
journal, April 2014

  • Tylus, Urszula; Jia, Qingying; Strickland, Kara
  • The Journal of Physical Chemistry C, Vol. 118, Issue 17
  • DOI: 10.1021/jp500781v

Novel Pd–In catalysts for alcohols electrooxidation in alkaline media
journal, September 2013


Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials
journal, July 2012

  • Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter
  • ACS Catalysis, Vol. 2, Issue 8
  • DOI: 10.1021/cs3003098

La0.6Ca0.4CoO3: a stable and powerful catalyst for bifunctional air electrodes
journal, August 1994


pH dependence of catalytic activity for ORR of the non-PGM catalyst derived from heat-treated Fe–phenanthroline
journal, January 2013


X-ray absorption and diffraction studies of La0.6Ca0.4CoO3 perovskite, a catalyst for bifunctional oxygen electrodes
journal, July 2002


Metal oxides/CNT nano-composite catalysts for oxygen reduction/oxygen evolution in alkaline media
journal, February 2015


Impact of Glass Corrosion on the Electrocatalysis on Pt Electrodes in Alkaline Electrolyte
journal, January 2008

  • Mayrhofer, K. J. J.; Wiberg, G. K. H.; Arenz, M.
  • Journal of The Electrochemical Society, Vol. 155, Issue 1
  • DOI: 10.1149/1.2800752

Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction
journal, August 2011

  • Liang, Yongye; Li, Yanguang; Wang, Hailiang
  • Nature Materials, Vol. 10, Issue 10, p. 780-786
  • DOI: 10.1038/nmat3087

Regularities of formation and catalytic properties of supported cobaltites in the oxidation of CO and hydrocarbons and in the reduction of nitrogen oxides
journal, September 2000

  • Pirogova, G. N.; Panich, N. M.; Korosteleva, R. I.
  • Russian Chemical Bulletin, Vol. 49, Issue 9
  • DOI: 10.1007/BF02495156

Fe-N-C Oxygen Reduction Fuel Cell Catalyst Derived from Carbendazim: Synthesis, Structure, and Reactivity
journal, March 2014

  • Serov, Alexey; Artyushkova, Kateryna; Atanassov, Plamen
  • Advanced Energy Materials, Vol. 4, Issue 10
  • DOI: 10.1002/aenm.201301735

Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011

  • Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1427

Non-platinum oxygen reduction electrocatalysts based on pyrolyzed transition metal macrocycles
journal, November 2008


Mechanistic Insight into Oxide-Promoted Palladium Catalysts for the Electro-Oxidation of Ethanol
journal, July 2014


Anode Catalysts for Direct Hydrazine Fuel Cells: From Laboratory Test to an Electric Vehicle
journal, August 2014

  • Serov, Alexey; Padilla, Monica; Roy, Aaron J.
  • Angewandte Chemie International Edition, Vol. 53, Issue 39
  • DOI: 10.1002/anie.201404734

Bi-Functional Oxygen Electrode Using Large Surface Area La[sub 1−x]Ca[sub x]CoO[sub 3] for Rechargeable Metal-Air Battery
journal, January 1990

  • Shimizu, Youichi
  • Journal of The Electrochemical Society, Vol. 137, Issue 11
  • DOI: 10.1149/1.2086234

A non-precious metal bifunctional oxygen electrode for alkaline anion exchange membrane cells
journal, May 2012


Bifunctional oxygen/air electrodes
journal, April 2006


Borohydride-tolerant oxygen electroreduction catalyst for mixed-reactant Swiss-roll direct borohydride fuel cells
journal, January 2013

  • Serov, Alexey; Aziznia, Amin; Benhangi, Pooya H.
  • Journal of Materials Chemistry A, Vol. 1, Issue 45
  • DOI: 10.1039/c3ta13457a

Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
journal, September 2009

  • Greeley, J.; Stephens, I. E. L.; Bondarenko, A. S.
  • Nature Chemistry, Vol. 1, Issue 7, p. 552-556
  • DOI: 10.1038/nchem.367

La0.6Ca0.4CoO3, La0.1Ca0.9MnO3 and LaNiO3 as bifunctional oxygen electrodes
journal, March 2002


    Works referencing / citing this record:

    A review of transition metal‐based bifunctional oxygen electrocatalysts
    journal, April 2019

    • Ibrahim, Kassa B.; Tsai, Meng‐Che; Chala, Soressa A.
    • Journal of the Chinese Chemical Society, Vol. 66, Issue 8
    • DOI: 10.1002/jccs.201900001

    Oxygen Reduction Reaction Activity of Mesostructured Cobalt‐Based Metal Oxides Studied with the Cavity‐Microelectrode Technique
    journal, July 2019


    Enhancement of Electrocatalytic Oxidation of Glycerol by Plasmonics
    journal, July 2018

    • Rasmussen, Michelle; Serov, Alexey; Artyushkova, Kateryna
    • ChemElectroChem, Vol. 6, Issue 1
    • DOI: 10.1002/celc.201800611

    Oxygen Reduction Reaction Activity of Mesostructured Cobalt‐Based Metal Oxides Studied with the Cavity‐Microelectrode Technique
    journal, July 2019


    A review of transition metal‐based bifunctional oxygen electrocatalysts
    journal, April 2019

    • Ibrahim, Kassa B.; Tsai, Meng‐Che; Chala, Soressa A.
    • Journal of the Chinese Chemical Society, Vol. 66, Issue 8
    • DOI: 10.1002/jccs.201900001

    Enhancing the catalytic performance of cobalt oxide by doping on ceria in the high temperature water–gas shift reaction
    journal, January 2015

    • Jha, Ajay; Jeong, Dae-Woon; Lee, Yeol-Lim
    • RSC Advances, Vol. 5, Issue 125
    • DOI: 10.1039/c5ra22704f