Long-Range Antiferromagnetic Order in a Rocksalt High Entropy Oxide

Zhang, Junjie; Yan, Jiaqiang; Calder, Stuart A.; Zheng, Qiang; McGuire, Michael A.; Abernathy, Douglas L.; Ren, Yang; Lapidus, Saul H.; Page, Katharine L.; Zheng, Hong; Freeland, John W.; Budai, John D.; Hermann, Raphael P.

doi:10.1021/acs.chemmater.9b00624

Title: Long-Range Antiferromagnetic Order in a Rocksalt High Entropy Oxide

Journal Article · Fri Apr 26 00:00:00 EDT 2019 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.9b00624· OSTI ID:1513391

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^[2]; Lapidus, Saul H. ^[2];

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

We report for the first time the magnetic structure of the high entropy oxide (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O using neutron powder diffraction. This material exhibits a sluggish magnetic transition but possesses a long-range ordered antiferromagnetic ground state, as revealed by direct current and alternating current magnetic susceptibility, neutron diffraction, and spectroscopy. The magnetic propagation wavevector is k = (1/2, 1/2, 1/2) based on the cubic structure Fm3m, and the magnetic structure consists of ferromagnetic sheets in the (111) planes with spins antiparallel between two neighboring planes. Neutron spectroscopy reveals strong magnetic excitations at 100 K that survive up to room temperature. This work demonstrates that entropy-stabilized oxides represent a unique platform to study long-range magnetic order with an extreme chemical disorder.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

OSTI ID:: 1513391

Alternate ID(s):: OSTI ID: 1529267

Journal Information:: Chemistry of Materials, Vol. 31, Issue 10; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 72 works

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