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Title: Final Report For PDRD SR16009: Durable Water Splitting Using Thermochemical Cycles Of Nanostructured Metal Oxides

Technical Report ·
DOI:https://doi.org/10.2172/1512420· OSTI ID:1512420
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  1. Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

The Tritium Facility process for stripping tritium from the glovebox atmosphere currently relies on the use of hot magnesium beds (mag beds) to “crack” tritiated water, releasing hydrogen isotopes as a gas. This is a safe and effective process for recovering hydrogen isotopes from water for further processing. However, due to the thermodynamic properties of magnesium, mag beds are single use - once the magnesium metal is converted to magnesium oxide the bed must be replaced. Replacing mag beds is a labor-intensive and operationally complex task. In order to streamline operations and reduce costs, it is desirable to develop a reusable system that recovers hydrogen isotopes from water, while safely sequestering oxygen in a stable form. The following document reviews the results from the Plant Directed Research, Development, and Demonstration (PDRD) project “Durable Water Splitting using Thermochemical Cycles of Nanostructured Metal Oxides” (SR16009), which had the specific goal of developing a process for stripping tritium from the glovebox atmosphere that eliminates magnesium beds.

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States)
Sponsoring Organization:
USDOE Office of Environmental Management (EM)
DOE Contract Number:
AC09-08SR22470
OSTI ID:
1512420
Report Number(s):
SRNL-TR-2018-00265
Country of Publication:
United States
Language:
English