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Electronic versus steric effects of pyridinophane ligands on Pd( iii ) complexes

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/c7dt04366j· OSTI ID:1511823
 [1];  [1];  [2];  [1]
  1. Washington Univ., St. Louis, MO (United States)
  2. Univ. of Missouri, St. Louis, MO (United States)
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Reported herein is the study of the electronic and steric effects of pyridinophane ligands on the corresponding Pd(iii) complexes.

Research Organization:
Washington Univ., St. Louis, MO (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0006862
OSTI ID:
1511823
Journal Information:
Dalton Transactions, Vol. 47, Issue 4; ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (38)

PhosphinooxazolinesA New Class of Versatile, Modular P,N - Ligands for Asymmetric Catalysis June 2000
The Aerobic Oxidation of a Pd(II) Dimethyl Complex Leads to Selective Ethane Elimination from a Pd(III) Intermediate January 2012
cclib: A library for package-independent computational chemistry algorithms January 2008
Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design November 2002
Dinuclear Palladium(III) Complexes with a Single Unsupported Bridging Halide Ligand: Reversible Formation from Mononuclear Palladium(II) or Palladium(IV) Precursors May 2011
Unsupported d 8 –d 8 interactions in cationic Pd II and Pt II complexes: evidence for a significant metal–metal bonding character January 2012
Steric and electronic effects in the bonding of N-heterocyclic ligands to transition metals December 2005
C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity January 2013
Palladium Complexes of N-Heterocyclic Carbenes as Catalysts for Cross-Coupling Reactions—A Synthetic Chemist's Perspective April 2007
A short history of SHELX December 2007
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density January 1988
Theoretical study on the influence of different NˆN ligands on the electronic structures and optoelectronic properties of heteroleptic Iridium(III) complexes December 2013
Diamagnetic Corrections and Pascal's Constants April 2008
Comparative Reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe 3 ):  Impact of Ancillary Ligand L on Activation of Carbon−Hydrogen Bonds Including Catalytic Hydroarylation and Hydrovinylation/Oligomerization of Ethylene May 2007
Compact effective potentials and efficient shared‐exponent basis sets for the first‐ and second‐row atoms December 1984
Remarkable Tuning of the Photophysical Properties of Bifunctional Lanthanide tris(Dipicolinates) and its Consequence on the Design of Bioprobes September 2008
Substituent electronic effects in chiral ligands for asymmetric catalysis May 2006
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions February 2010
The Conformational Flexibility of the Tetradentate Ligand tBu N4 is Essential for the Stabilization of ( tBu N4)Pd III Complexes November 2014
Reaction of tosylamide monosodium salt with bis(halomethyl) compounds: an easy entry to symmetrical N-tosyl aza macrocycles July 1988
Relativistic compact effective potentials and efficient, shared-exponent basis sets for the third-, fourth-, and fifth-row atoms February 1992
Inorganic Chemistry Based on Tp Ligands —From Dioxygen Complexes to Organometallic Systems— August 2002
Structure and solution behaviour of rhodium(I) Vaska-type complexes for correlation of steric and electronic properties of tertiary phosphine ligands October 2003
Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis February 2010
Structure and electronic properties of Pd(III) complexes January 2013
Structural and reactivity comparison of analogous organometallic Pd(iii) and Pd(iv) complexes January 2012
High-Oxidation-State Palladium Catalysis: New Reactivity for Organic Synthesis October 2009
A new mixing of Hartree–Fock and local density‐functional theories January 1993
Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds August 2009
The syntheses and catalytic applications of unsymmetrical ferrocene ligands January 2004
400. The determination of the paramagnetic susceptibility of substances in solution by nuclear magnetic resonance January 1959
Stable Mononuclear Organometallic Pd(III) Complexes and Their C−C Bond Formation Reactivity June 2010
Development of organopalladium(IV) chemistry: fundamental aspects and systems for studies of mechanism in organometallic chemistry and catalysis February 1992
Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality June 2009
Oxidative Reactivity of (N2S2)PdRX Complexes (R = Me, Cl; X = Me, Cl, Br): Involvement of Palladium(III) and Palladium(IV) Intermediates March 2013
Detection of Pd(III) and Pd(IV) Intermediates during the Aerobic Oxidative C–C Bond Formation from a Pd(II) Dimethyl Complex August 2012
Deoxygenations of (silox) 3 WNO and R 3 PO by (silox) 3 M (M = V, Ta) and (silox) 3 NbL (silox = t Bu 3 SiO):  Consequences of Electronic Effects July 2001
Recent studies in asymmetric catalysis using ferrocenyl ligands August 1999

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY