The viscosity of atmospherically relevant organic particles

Reid, Jonathan P.; Bertram, Allan K.; Topping, David O.; Laskin, Alexander; Martin, Scot T.; Petters, Markus D.; Pope, Francis D.; Rovelli, Grazia

doi:10.1038/s41467-018-03027-z

Title: The viscosity of atmospherically relevant organic particles

Journal Article · Tue Mar 06 00:00:00 EST 2018 · Nature Communications

DOI:https://doi.org/10.1038/s41467-018-03027-z· OSTI ID:1511471

^[1]; Bertram, Allan K. ^[2]; Topping, David O. ^[3]; Laskin, Alexander ^[4]; Martin, Scot T. ^[5];

^[6]; Pope, Francis D. ^[7]; Rovelli, Grazia ^[1]

Univ. of Bristol, Manchester (United Kingdom)
Univ. of British Columbia, Vancouver, BC (Canada)
Univ. of Manchester, Manchester (United Kingdom)
Purdue Univ., West Lafayette, IN (United States)
Harvard Univ., Cambridge, MA (United States)
North Carolina State Univ., Raleigh, NC (United States)
Univ. of Birmingham, Birmingham (United Kingdom)

The importance of organic aerosol particles in the environment has been long established, influencing cloud formation and lifetime, absorbing and scattering sunlight, affecting atmospheric composition and impacting on human health. Conventionally, ambient organic particles were considered to exist as liquids. Recent observations in field measurements and studies in the laboratory suggest that they may instead exist as highly viscous semi-solids or amorphous glassy solids under certain conditions, with important implications for atmospheric chemistry, climate and air quality. This review explores our understanding of aerosol particle phase, particularly as identified by measurements of the viscosity of organic particles, and the atmospheric implications of phase state.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of Colorado, Boulder, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0012043

OSTI ID:: 1511471

Journal Information:: Nature Communications, Vol. 9, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 207 works

Citation information provided by
Web of Science

References (129)

Synthesis of tailored composite nanoparticles in the gas phase Maisels, Arkadi; Kruis, F. Einar; Fissan, Heinz Applied Physics Letters, Vol. 77, Issue 26 https://doi.org/10.1063/1.1335843	journal	December 2000
Effect of crystallization kinetics on the properties of spray dried microparticles Baldelli, Alberto; Power, Rory M.; Miles, Rachael E. H. Aerosol Science and Technology, Vol. 50, Issue 7 https://doi.org/10.1080/02786826.2016.1177163	journal	April 2016
Competition between water uptake and ice nucleation by glassy organic aerosol particles Berkemeier, T.; Shiraiwa, M.; Pöschl, U. Atmospheric Chemistry and Physics, Vol. 14, Issue 22 https://doi.org/10.5194/acp-14-12513-2014	journal	January 2014
Imaging phase separation in model lipid membranes through the use of BODIPY based molecular rotors Dent, Michael R.; López-Duarte, Ismael; Dickson, Callum J. Physical Chemistry Chemical Physics, Vol. 17, Issue 28 https://doi.org/10.1039/C5CP01937K	journal	January 2015
Airborne soil organic particles generated by precipitation Wang, Bingbing; Harder, Tristan H.; Kelly, Stephen T. Nature Geoscience, Vol. 9, Issue 6 https://doi.org/10.1038/ngeo2705	journal	May 2016
Water activity as the determinant for homogeneous ice nucleation in aqueous solutions Koop, Thomas; Luo, Beiping; Tsias, Athanasios Nature, Vol. 406, Issue 6796 https://doi.org/10.1038/35020537	journal	August 2000
Size distribution dynamics reveal particle-phase chemistry in organic aerosol formation Shiraiwa, M.; Yee, L. D.; Schilling, K. A. Proceedings of the National Academy of Sciences, Vol. 110, Issue 29 https://doi.org/10.1073/pnas.1307501110	journal	July 2013
Kinematics and dynamics of atomic-beam scattering on liquid and self-assembled monolayer surfaces Alexander, William A.; Zhang, Jianming; Murray, Vanessa J. Faraday Discussions, Vol. 157 https://doi.org/10.1039/c2fd20034a	journal	January 2012
The effect of hydroxyl functional groups and molar mass on the viscosity of non-crystalline organic and organic–water particles Grayson, James W.; Evoy, Erin; Song, Mijung Atmospheric Chemistry and Physics, Vol. 17, Issue 13 https://doi.org/10.5194/acp-17-8509-2017	journal	January 2017
Estimating the Viscosity Range of SOA Particles Based on Their Coalescence Time Pajunoja, Aki; Malila, Jussi; Hao, Liqing Aerosol Science and Technology, Vol. 48, Issue 2 https://doi.org/10.1080/02786826.2013.870325	journal	December 2013
Validation of the poke-flow technique combined with simulations of fluid flow for determining viscosities in samples with small volumes and high viscosities Grayson, J. W.; Song, M.; Sellier, M. Atmospheric Measurement Techniques, Vol. 8, Issue 6 https://doi.org/10.5194/amt-8-2463-2015	journal	January 2015
Probing the micro-rheological properties of aerosol particles using optical tweezers Power, Rory M.; Reid, Jonathan P. Reports on Progress in Physics, Vol. 77, Issue 7 https://doi.org/10.1088/0034-4885/77/7/074601	journal	July 2014
Ultra-slow water diffusion in aqueous sucrose glasses Zobrist, Bernhard; Soonsin, Vacharaporn; Luo, Bei P. Physical Chemistry Chemical Physics, Vol. 13, Issue 8 https://doi.org/10.1039/c0cp01273d	journal	January 2011
Mapping viscosity in cells using molecular rotors Kuimova, Marina K. Physical Chemistry Chemical Physics, Vol. 14, Issue 37 https://doi.org/10.1039/c2cp41674c	journal	January 2012
Water diffusion in atmospherically relevant α-pinene secondary organic material Price, Hannah C.; Mattsson, Johan; Zhang, Yue Chemical Science, Vol. 6, Issue 8 https://doi.org/10.1039/C5SC00685F	journal	January 2015
Viscosity controls humidity dependence of N ₂ O ₅ uptake to citric acid aerosol Gržinić, G.; Bartels-Rausch, T.; Berkemeier, T. Atmospheric Chemistry and Physics, Vol. 15, Issue 23 https://doi.org/10.5194/acp-15-13615-2015	journal	January 2015
Reactivity of Liquid and Semisolid Secondary Organic Carbon with Chloride and Nitrate in Atmospheric Aerosols Wang, Bingbing; O’Brien, Rachel E.; Kelly, Stephen T. The Journal of Physical Chemistry A, Vol. 119, Issue 19 https://doi.org/10.1021/jp510336q	journal	November 2014
Fluorescence lifetime imaging of optically levitated aerosol: a technique to quantitatively map the viscosity of suspended aerosol particles Fitzgerald, C.; Hosny, N. A.; Tong, H. Physical Chemistry Chemical Physics, Vol. 18, Issue 31 https://doi.org/10.1039/C6CP03674K	journal	January 2016
The formation, properties and impact of secondary organic aerosol: current and emerging issues Hallquist, M.; Wenger, J. C.; Baltensperger, U. Atmospheric Chemistry and Physics, Vol. 9, Issue 14 https://doi.org/10.5194/acp-9-5155-2009	journal	January 2009
Changing shapes and implied viscosities of suspended submicron particles Zhang, Y.; Sanchez, M. S.; Douet, C. Atmospheric Chemistry and Physics, Vol. 15, Issue 14 https://doi.org/10.5194/acp-15-7819-2015	journal	January 2015
Analysis of Recent Measurements of the Viscosity of Glasses Fulcher, Gordon S. Journal of the American Ceramic Society, Vol. 8, Issue 6 https://doi.org/10.1111/j.1151-2916.1925.tb16731.x	journal	June 1925
Dynamic measurements and simulations of airborne picolitre-droplet coalescence in holographic optical tweezers Bzdek, Bryan R.; Collard, Liam; Sprittles, James E. The Journal of Chemical Physics, Vol. 145, Issue 5 https://doi.org/10.1063/1.4959901	journal	August 2016
Differences between stress and strain control in the non-linear behavior of complex fluids Läuger, Jörg; Stettin, Heiko Rheologica Acta, Vol. 49, Issue 9 https://doi.org/10.1007/s00397-010-0450-0	journal	April 2010
Technical Note: New methodology for measuring viscosities in small volumes characteristic of environmental chamber particle samples Renbaum-Wolff, L.; Grayson, J. W.; Bertram, A. K. Atmospheric Chemistry and Physics, Vol. 13, Issue 2 https://doi.org/10.5194/acp-13-791-2013	journal	January 2013
Do atmospheric aerosols form glasses? Zobrist, B.; Marcolli, C.; Pedernera, D. A. Atmospheric Chemistry and Physics, Vol. 8, Issue 17 https://doi.org/10.5194/acp-8-5221-2008	journal	January 2008
Size dependence of phase transitions in aerosol nanoparticles Cheng, Yafang; Su, Hang; Koop, Thomas Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6923	journal	January 2015
Raman Spectroscopy of Isotopic Water Diffusion in Ultraviscous, Glassy, and Gel States in Aerosol by Use of Optical Tweezers Davies, James F.; Wilson, Kevin R. Analytical Chemistry, Vol. 88, Issue 4 https://doi.org/10.1021/acs.analchem.5b04315	journal	January 2016
An amorphous solid state of biogenic secondary organic aerosol particles Virtanen, Annele; Joutsensaari, Jorma; Koop, Thomas Nature, Vol. 467, Issue 7317 https://doi.org/10.1038/nature09455	journal	October 2010
Gas–particle partitioning of atmospheric aerosols: interplay of physical state, non-ideal mixing and morphology Shiraiwa, Manabu; Zuend, Andreas; Bertram, Allan K. Physical Chemistry Chemical Physics, Vol. 15, Issue 27 https://doi.org/10.1039/c3cp51595h	journal	January 2013
Recent advances in understanding secondary organic aerosol: Implications for global climate forcing: Advances in Secondary Organic Aerosol Shrivastava, Manish; Cappa, Christopher D.; Fan, Jiwen Reviews of Geophysics, Vol. 55, Issue 2 https://doi.org/10.1002/2016RG000540	journal	June 2017
Impactor Apparatus for the Study of Particle Rebound: Relative Humidity and Capillary Forces Bateman, Adam P.; Belassein, Helene; Martin, Scot T. Aerosol Science and Technology, Vol. 48, Issue 1 https://doi.org/10.1080/02786826.2013.853866	journal	October 2013
Complex three-dimensional self-assembly in proxies for atmospheric aerosols Pfrang, C.; Rastogi, K.; Cabrera-Martinez, E. R. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01918-1	journal	November 2017
Exploring the complexity of aerosol particle properties and processes using single particle techniques Krieger, Ulrich K.; Marcolli, Claudia; Reid, Jonathan P. Chemical Society Reviews, Vol. 41, Issue 19 https://doi.org/10.1039/c2cs35082c	journal	January 2012
Heterogeneous Ice Nucleation on Simulated Sea-Spray Aerosol Using Raman Microscopy Schill, Gregory P.; Tolbert, Margaret A. The Journal of Physical Chemistry C, Vol. 118, Issue 50 https://doi.org/10.1021/jp505379j	journal	August 2014
Molecular Diversity of Sea Spray Aerosol Particles: Impact of Ocean Biology on Particle Composition and Hygroscopicity Cochran, Richard E.; Laskina, Olga; Trueblood, Jonathan V. Chem, Vol. 2, Issue 5 https://doi.org/10.1016/j.chempr.2017.03.007	journal	May 2017
Measurements and Predictions of Binary Component Aerosol Particle Viscosity Song, Young Chul; Haddrell, Allen E.; Bzdek, Bryan R. The Journal of Physical Chemistry A, Vol. 120, Issue 41 https://doi.org/10.1021/acs.jpca.6b07835	journal	October 2016
Atmospheric Ice Nuclei from Decomposing Vegetation Schnell, R. C.; Vali, G. Nature, Vol. 236, Issue 5343 https://doi.org/10.1038/236163a0	journal	March 1972
Accurate representations of the physicochemical properties of atmospheric aerosols: when are laboratory measurements of value? Marsh, Aleksandra; Rovelli, Grazia; Song, Young-Chul Faraday Discussions, Vol. 200 https://doi.org/10.1039/C7FD00008A	journal	January 2017
Rainforest Aerosols as Biogenic Nuclei of Clouds and Precipitation in the Amazon Poschl, U.; Martin, S. T.; Sinha, B. Science, Vol. 329, Issue 5998 https://doi.org/10.1126/science.1191056	journal	September 2010
Viscosity of -pinene secondary organic material and implications for particle growth and reactivity Renbaum-Wolff, L.; Grayson, J. W.; Bateman, A. P. Proceedings of the National Academy of Sciences, Vol. 110, Issue 20 https://doi.org/10.1073/pnas.1219548110	journal	April 2013
Equilibration timescale of atmospheric secondary organic aerosol partitioning Shiraiwa, Manabu; Seinfeld, John H. Geophysical Research Letters, Vol. 39, Issue 24 https://doi.org/10.1029/2012GL054008	journal	December 2012
The rate of equilibration of viscous aerosol particles O'Meara, Simon; Topping, David O.; McFiggans, Gordon Atmospheric Chemistry and Physics, Vol. 16, Issue 8 https://doi.org/10.5194/acp-16-5299-2016	journal	January 2016
Anthropogenic influences on the physical state of submicron particulate matter over a tropical forest Bateman, Adam P.; Gong, Zhaoheng; Harder, Tristan H. Atmospheric Chemistry and Physics, Vol. 17, Issue 3 https://doi.org/10.5194/acp-17-1759-2017	journal	January 2017
Direct imaging of changes in aerosol particle viscosity upon hydration and chemical aging Hosny, N. A.; Fitzgerald, C.; Vyšniauskas, A. Chemical Science, Vol. 7, Issue 2 https://doi.org/10.1039/C5SC02959G	journal	January 2016
Effect of varying experimental conditions on the viscosity of α -pinene derived secondary organic material Grayson, James W.; Zhang, Yue; Mutzel, Anke Atmospheric Chemistry and Physics, Vol. 16, Issue 10 https://doi.org/10.5194/acp-16-6027-2016	journal	January 2016
Bounce behavior of freshly nucleated biogenic secondary organic aerosol particles Virtanen, A.; Kannosto, J.; Kuuluvainen, H. Atmospheric Chemistry and Physics, Vol. 11, Issue 16 https://doi.org/10.5194/acp-11-8759-2011	journal	January 2011
A new group contribution method for predicting viscosity of organic liquids Sastri, S. R. S.; Rao, K. K. The Chemical Engineering Journal, Vol. 50, Issue 1 https://doi.org/10.1016/0300-9467(92)80002-R	journal	October 1992
Coalescence-based assessment of aerosol phase state using dimers prepared through a dual-differential mobility analyzer technique Rothfuss, Nicholas E.; Petters, Markus D. Aerosol Science and Technology, Vol. 50, Issue 12 https://doi.org/10.1080/02786826.2016.1221050	journal	August 2016
Atmospheric tar balls: Particles from biomass and biofuel burning: ATMOSPHERIC TAR BALLS Pósfai, Mihály; Gelencsér, András; Simonics, Renáta Journal of Geophysical Research: Atmospheres, Vol. 109, Issue D6 https://doi.org/10.1029/2003JD004169	journal	March 2004
Refinement and Parametrization of COSMO-RS Klamt, Andreas; Jonas, Volker; Bürger, Thorsten The Journal of Physical Chemistry A, Vol. 102, Issue 26 https://doi.org/10.1021/jp980017s	journal	June 1998
Changes in Secondary Organic Aerosol Composition and Mass due to Photolysis: Relative Humidity Dependence Wong, Jenny P. S.; Zhou, Shouming; Abbatt, Jonathan P. D. The Journal of Physical Chemistry A, Vol. 119, Issue 19 https://doi.org/10.1021/jp506898c	journal	September 2014
Heterogeneous nucleation of ice particles on glassy aerosols under cirrus conditions Murray, Benjamin J.; Wilson, Theodore W.; Dobbie, Steven Nature Geoscience, Vol. 3, Issue 4 https://doi.org/10.1038/ngeo817	journal	March 2010
Experimental determination of chemical diffusion within secondary organic aerosol particles Abramson, Evan; Imre, Dan; Beránek, Josef Physical Chemistry Chemical Physics, Vol. 15, Issue 8 https://doi.org/10.1039/c2cp44013j	journal	January 2013
Glass formation and unusual hygroscopic growth of iodic acid solution droplets with relevance for iodine mediated particle formation in the marine boundary layer Murray, B. J.; Haddrell, A. E.; Peppe, S. Atmospheric Chemistry and Physics, Vol. 12, Issue 18 https://doi.org/10.5194/acp-12-8575-2012	journal	January 2012
Modeling kinetic partitioning of secondary organic aerosol and size distribution dynamics: representing effects of volatility, phase state, and particle-phase reaction Zaveri, R. A.; Easter, R. C.; Shilling, J. E. Atmospheric Chemistry and Physics, Vol. 14, Issue 10 https://doi.org/10.5194/acp-14-5153-2014	journal	January 2014
Characterization of the temperature and humidity-dependent phase diagram of amorphous nanoscale organic aerosols Rothfuss, Nicholas E.; Petters, Markus D. Physical Chemistry Chemical Physics, Vol. 19, Issue 9 https://doi.org/10.1039/C6CP08593H	journal	January 2017
Glassy aerosols with a range of compositions nucleate ice heterogeneously at cirrus temperatures Wilson, T. W.; Murray, B. J.; Wagner, R. Atmospheric Chemistry and Physics, Vol. 12, Issue 18 https://doi.org/10.5194/acp-12-8611-2012	journal	January 2012
Precise, contactless measurements of the surface tension of picolitre aerosol droplets Bzdek, Bryan R.; Power, Rory M.; Simpson, Stephen H. Chemical Science, Vol. 7, Issue 1 https://doi.org/10.1039/C5SC03184B	journal	January 2016
Mixing of secondary organic aerosols versus relative humidity Ye, Qing; Robinson, Ellis Shipley; Ding, Xiang Proceedings of the National Academy of Sciences, Vol. 113, Issue 45 https://doi.org/10.1073/pnas.1604536113	journal	October 2016
Group-contribution viscosity predictions of liquid mixtures using UNIFAC-VLE parameters Cao, Weihong; Knudsen, Kim; Fredenslund, Aage Industrial & Engineering Chemistry Research, Vol. 32, Issue 9 https://doi.org/10.1021/ie00021a034	journal	September 1993
Comparing the mechanism of water condensation and evaporation in glassy aerosol Bones, D. L.; Reid, J. P.; Lienhard, D. M. Proceedings of the National Academy of Sciences, Vol. 109, Issue 29 https://doi.org/10.1073/pnas.1200691109	journal	July 2012
Exploring matrix effects on photochemistry of organic aerosols Lignell, H.; Hinks, M. L.; Nizkorodov, S. A. Proceedings of the National Academy of Sciences, Vol. 111, Issue 38 https://doi.org/10.1073/pnas.1322106111	journal	September 2014
A marine biogenic source of atmospheric ice-nucleating particles Wilson, Theodore W.; Ladino, Luis A.; Alpert, Peter A. Nature, Vol. 525, Issue 7568 https://doi.org/10.1038/nature14986	journal	September 2015
Observation of viscosity transition in α -pinene secondary organic aerosol Järvinen, Emma; Ignatius, Karoliina; Nichman, Leonid Atmospheric Chemistry and Physics, Vol. 16, Issue 7 https://doi.org/10.5194/acp-16-4423-2016	journal	January 2016
Humidity-dependent phase state of SOA particles from biogenic and anthropogenic precursors Saukko, E.; Lambe, A. T.; Massoli, P. Atmospheric Chemistry and Physics, Vol. 12, Issue 16 https://doi.org/10.5194/acp-12-7517-2012	journal	January 2012
Electrodynamic balance measurements of thermodynamic, kinetic, and optical aerosol properties inaccessible to bulk methods Steimer, S. S.; Krieger, U. K.; Te, Y. -F. Atmospheric Measurement Techniques, Vol. 8, Issue 6 https://doi.org/10.5194/amt-8-2397-2015	journal	January 2015
Phase state of ambient aerosol linked with water uptake and chemical aging in the southeastern US Pajunoja, Aki; Hu, Weiwei; Leong, Yu J. Atmospheric Chemistry and Physics, Vol. 16, Issue 17 https://doi.org/10.5194/acp-16-11163-2016	journal	January 2016
Gas uptake and chemical aging of semisolid organic aerosol particles Shiraiwa, M.; Ammann, M.; Koop, T. Proceedings of the National Academy of Sciences, Vol. 108, Issue 27 https://doi.org/10.1073/pnas.1103045108	journal	June 2011
Fluorescent lifetime imaging of atmospheric aerosols: a direct probe of aerosol viscosity Hosny, Neveen A.; Fitzgerald, Clare; Tong, Changlun Faraday Discussions, Vol. 165 https://doi.org/10.1039/c3fd00041a	journal	January 2013
Saturation Vapor Pressures and Transition Enthalpies of Low-Volatility Organic Molecules of Atmospheric Relevance: From Dicarboxylic Acids to Complex Mixtures Bilde, Merete; Barsanti, Kelley; Booth, Murray Chemical Reviews, Vol. 115, Issue 10 https://doi.org/10.1021/cr5005502	journal	February 2015
Influence of Functional Groups on the Viscosity of Organic Aerosol Rothfuss, Nicholas E.; Petters, Markus D. Environmental Science & Technology, Vol. 51, Issue 1 https://doi.org/10.1021/acs.est.6b04478	journal	December 2016
Multiphase Chemistry at the Atmosphere–Biosphere Interface Influencing Climate and Public Health in the Anthropocene Pöschl, Ulrich; Shiraiwa, Manabu Chemical Reviews, Vol. 115, Issue 10 https://doi.org/10.1021/cr500487s	journal	February 2015
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere Koop, Thomas; Bookhold, Johannes; Shiraiwa, Manabu Physical Chemistry Chemical Physics, Vol. 13, Issue 43 https://doi.org/10.1039/c1cp22617g	journal	January 2011
Optical, physical, and chemical properties of tar balls observed during the Yosemite Aerosol Characterization Study Hand, J. L.; Malm, W. C.; Laskin, A. Journal of Geophysical Research, Vol. 110, Issue D21 https://doi.org/10.1029/2004JD005728	journal	January 2005
Sub-micrometre particulate matter is primarily in liquid form over Amazon rainforest Bateman, Adam P.; Gong, Zhaoheng; Liu, Pengfei Nature Geoscience, Vol. 9, Issue 1 https://doi.org/10.1038/ngeo2599	journal	December 2015
Effects of confinement on material behaviour at the nanometre size scale Alcoutlabi, Mataz; McKenna, Gregory B. Journal of Physics: Condensed Matter, Vol. 17, Issue 15 https://doi.org/10.1088/0953-8984/17/15/R01	journal	April 2005
Relative humidity-dependent viscosities of isoprene-derived secondary organic material and atmospheric implications for isoprene-dominant forests Song, M.; Liu, P. F.; Hanna, S. J. Atmospheric Chemistry and Physics, Vol. 15, Issue 9 https://doi.org/10.5194/acp-15-5145-2015	journal	January 2015
Physical properties of ambient and laboratory-generated secondary organic aerosol: PHYSICAL PROPERTIES OF ORGANIC AEROSOL O'Brien, Rachel E.; Neu, Alexander; Epstein, Scott A. Geophysical Research Letters, Vol. 41, Issue 12 https://doi.org/10.1002/2014GL060219	journal	June 2014
Diffusion coefficients of organic molecules in sucrose–water solutions and comparison with Stokes–Einstein predictions Chenyakin, Yuri; Ullmann, Dagny A.; Evoy, Erin Atmospheric Chemistry and Physics, Vol. 17, Issue 3 https://doi.org/10.5194/acp-17-2423-2017	journal	January 2017
Global distribution of particle phase state in atmospheric secondary organic aerosols Shiraiwa, Manabu; Li, Ying; Tsimpidi, Alexandra P. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15002	journal	April 2017
Predicting global atmospheric ice nuclei distributions and their impacts on climate DeMott, P. J.; Prenni, A. J.; Liu, X. Proceedings of the National Academy of Sciences, Vol. 107, Issue 25 https://doi.org/10.1073/pnas.0910818107	journal	June 2010
Hygroscopic Influence on the Semisolid-to-Liquid Transition of Secondary Organic Materials Bateman, Adam P.; Bertram, Allan K.; Martin, Scot T. The Journal of Physical Chemistry A, Vol. 119, Issue 19 https://doi.org/10.1021/jp508521c	journal	November 2014
Marine microgels as a source of cloud condensation nuclei in the high Arctic Orellana, M. V.; Matrai, P. A.; Leck, C. Proceedings of the National Academy of Sciences, Vol. 108, Issue 33 https://doi.org/10.1073/pnas.1102457108	journal	August 2011
α-Pinene Autoxidation Products May Not Have Extremely Low Saturation Vapor Pressures Despite High O:C Ratios Kurtén, Theo; Tiusanen, Kirsi; Roldin, Pontus The Journal of Physical Chemistry A, Vol. 120, Issue 16 https://doi.org/10.1021/acs.jpca.6b02196	journal	April 2016
Diffusivity measurements of volatile organics in levitated viscous aerosol particles Bastelberger, Sandra; Krieger, Ulrich K.; Luo, Beiping Atmospheric Chemistry and Physics, Vol. 17, Issue 13 https://doi.org/10.5194/acp-17-8453-2017	journal	January 2017
Erratum : Relation between Vapor Pressure and Viscosity of Liquids Mitra, Shashanka Shekhar The Journal of Chemical Physics, Vol. 22, Issue 8 https://doi.org/10.1063/1.1740438	journal	August 1954
Viscous organic aerosol particles in the upper troposphere: diffusivity-controlled water uptake and ice nucleation? Lienhard, D. M.; Huisman, A. J.; Krieger, U. K. Atmospheric Chemistry and Physics, Vol. 15, Issue 23 https://doi.org/10.5194/acp-15-13599-2015	journal	January 2015
Supercooled liquids and the glass transition Debenedetti, Pablo G.; Stillinger, Frank H. Nature, Vol. 410, Issue 6825 https://doi.org/10.1038/35065704	journal	March 2001
Heterogeneous ice nucleation of viscous secondary organic aerosol produced from ozonolysis of α -pinene Ignatius, Karoliina; Kristensen, Thomas B.; Järvinen, Emma Atmospheric Chemistry and Physics, Vol. 16, Issue 10 https://doi.org/10.5194/acp-16-6495-2016	journal	January 2016
Heterogeneous ice nucleation of α -pinene SOA particles before and after ice cloud processing : Ice Nucleation of Wagner, Robert; Höhler, Kristina; Huang, Wei Journal of Geophysical Research: Atmospheres, Vol. 122, Issue 9 https://doi.org/10.1002/2016JD026401	journal	May 2017
Size-resolved characterization of the polysaccharidic and proteinaceous components of sea spray aerosol Aller, Josephine Y.; Radway, JoAnn C.; Kilthau, Wendy P. Atmospheric Environment, Vol. 154 https://doi.org/10.1016/j.atmosenv.2017.01.053	journal	April 2017
Connecting Bulk Viscosity Measurements to Kinetic Limitations on Attaining Equilibrium for a Model Aerosol Composition Booth, A. Murray; Murphy, Ben; Riipinen, Ilona Environmental Science & Technology, Vol. 48, Issue 16 https://doi.org/10.1021/es501705c	journal	August 2014
A method to resolve the phase state of aerosol particles Saukko, E.; Kuuluvainen, H.; Virtanen, A. Atmospheric Measurement Techniques, Vol. 5, Issue 1 https://doi.org/10.5194/amt-5-259-2012	journal	January 2012
Lability of secondary organic particulate matter Liu, Pengfei; Li, Yong Jie; Wang, Yan Proceedings of the National Academy of Sciences, Vol. 113, Issue 45 https://doi.org/10.1073/pnas.1603138113	journal	October 2016
State transformations and ice nucleation in amorphous (semi-)solid organic aerosol Baustian, K. J.; Wise, M. E.; Jensen, E. J. Atmospheric Chemistry and Physics, Vol. 13, Issue 11 https://doi.org/10.5194/acp-13-5615-2013	journal	January 2013
Integrating phase and composition of secondary organic aerosol from the ozonolysis of -pinene Kidd, C.; Perraud, V.; Wingen, L. M. Proceedings of the National Academy of Sciences, Vol. 111, Issue 21 https://doi.org/10.1073/pnas.1322558111	journal	May 2014
Amorphous and crystalline aerosol particles interacting with water vapor: conceptual framework and experimental evidence for restructuring, phase transitions and kinetic limitations Mikhailov, E.; Vlasenko, S.; Martin, S. T. Atmospheric Chemistry and Physics, Vol. 9, Issue 24 https://doi.org/10.5194/acp-9-9491-2009	journal	January 2009
Atmospheric tar balls: aged primary droplets from biomass burning? Tóth, A.; Hoffer, A.; Nyirő-Kósa, I. Atmospheric Chemistry and Physics, Vol. 14, Issue 13 https://doi.org/10.5194/acp-14-6669-2014	journal	January 2014
Mixing times of organic molecules within secondary organic aerosol particles: a global planetary boundary layer perspective Maclean, Adrian M.; Butenhoff, Christopher L.; Grayson, James W. Atmospheric Chemistry and Physics, Vol. 17, Issue 21 https://doi.org/10.5194/acp-17-13037-2017	journal	January 2017
The transition from liquid to solid-like behaviour in ultrahigh viscosity aerosol particles Power, R. M.; Simpson, S. H.; Reid, J. P. Chemical Science, Vol. 4, Issue 6 https://doi.org/10.1039/c3sc50682g	journal	January 2013
Glassy aerosols with a range of compositions nucleate ice heterogeneously at cirrus temperatures Wilson, T. W.; Murray, B. J.; Wagner, R. Atmospheric Chemistry and Physics Discussions, Vol. 12, Issue 4 https://doi.org/10.5194/acpd-12-8979-2012	journal	January 2012
Validation of the poke-flow technique combined with simulations of fluid flow for determining viscosities in samples with small volumes and high viscosities Grayson, J. W.; Song, M.; Sellier, M. Atmospheric Measurement Techniques Discussions, Vol. 8, Issue 1 https://doi.org/10.5194/amtd-8-877-2015	journal	January 2015
Coalescence-based assessment of aerosol phase state using dimers prepared through a dual-differential mobility analyzer technique Rothfuss, Nicholas E.; Petters, Markus D. Taylor & Francis https://doi.org/10.6084/m9.figshare.3544724.v1	text	January 2016
Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays Smolentsev, Grigory; Milne, Christopher J.; Guda, Alexander Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15998-z	journal	May 2020
Analysis of Recent Measurements of the Viscosity of Glasses Fulcher, Gordon S. Journal of the American Ceramic Society, Vol. 75, Issue 5 https://doi.org/10.1111/j.1151-2916.1992.tb05536.x	journal	May 1992
Fluorescence lifetime imaging of optically levitated aerosol: a technique to quantitatively map the viscosity of suspended aerosol particles Fitzgerald, C.; Hosny, Na; Tong, H. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.6001	text	January 2016
Electrodynamic balance measurements of thermodynamic, kinetic, and optical aerosol properties inaccessible to bulk methods Steimer, Sarah S.; Krieger, Ulrich K.; Te, Yiea-Funk ETH Zurich https://doi.org/10.3929/ethz-b-000101937	text	January 2015
Viscous organic aerosol particles in the upper troposphere: diffusivity-controlled water uptake and ice nucleation? Lienhard, Daniel M.; Huisman, Andrew J.; Krieger, Ulrich K. ETH Zurich https://doi.org/10.3929/ethz-b-000108076	text	January 2015
Coalescence-based assessment of aerosol phase state using dimers prepared through a dual-differential mobility analyzer technique Rothfuss, Nicholas E.; Petters, Markus D. Taylor & Francis https://doi.org/10.6084/m9.figshare.3544724	text	January 2016
The formation, properties and impact of secondary organic aerosol: current and emerging issues Y., Rudich,; M., Jang,; A. S. H., Prevot, Copernicus Publications https://doi.org/10.17615/k22s-ek71	text	January 2009
Do atmospheric aerosols form glasses? Zobrist, B.; Marcolli, C.; Pedernera, D. A. Atmospheric Chemistry and Physics Discussions, Vol. 8, Issue 3 https://doi.org/10.5194/acpd-8-9263-2008	journal	January 2008
Effect of crystallization kinetics on the properties of spray dried microparticles Baldelli, Alberto; Power, Rory M.; Miles, Rachael E. H. Taylor & Francis https://doi.org/10.6084/m9.figshare.3179947.v1	text	January 2016
Dynamic viscosity mapping of the oxidation of squalene aerosol particles. Athanasiadis, Athanasios; Fitzgerald, Clare; Davidson, Nicholas M. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.6854	text	January 2016
Diffusivity measurements of volatile organics in levitated viscous aerosol particles Bastelberger, Sandra; Krieger, Ulrich K.; Luo, Beiping ETH Zurich https://doi.org/10.3929/ethz-b-000190334	text	January 2017
Impactor Apparatus for the Study of Particle Rebound: Relative Humidity and Capillary Forces Bateman, Adam P.; Belassein, Helene; Martin, Scot T. Taylor & Francis https://doi.org/10.6084/m9.figshare.969666	text	January 2014
Heterogeneous ice nucleation of viscous secondary organic aerosol produced from ozonolysis of α-pinene Ignatius, K.; Kristensen, T. B.; Järvinen, E. Karlsruhe https://doi.org/10.5445/ir/1000056441	text	January 2016
Effect of crystallization kinetics on the properties of spray dried microparticles Baldelli, Alberto; Power, Rory M.; Miles, Rachael E. H. Taylor & Francis https://doi.org/10.6084/m9.figshare.3179947	text	January 2016
Effect of varying experimental conditions on the viscosity of α-pinene derived secondary organic material Grayson, James W.; Zhang, Yue; Mutzel, Anke München : European Geopyhsical Union https://doi.org/10.34657/907	null	January 2016
Factors controlling the evaporation of secondary organic aerosol from α‐pinene ozonolysis Yli‐Juuti, Taina; Pajunoja, Aki; Tikkanen, Olli‐Pekka Geophysical Research Letters, Vol. 44, Issue 5 https://doi.org/10.1002/2016gl072364	journal	March 2017
Atmospheric tar balls from biomass burning in Mexico Adachi, Kouji; Buseck, Peter R. Journal of Geophysical Research, Vol. 116, Issue D5 https://doi.org/10.1029/2010jd015102	journal	January 2011
Shikimic acid ozonolysis kinetics of the transition from liquid aqueous solution to highly viscous glass Steimer, Sarah S.; Berkemeier, Thomas; Gilgen, Anina Physical Chemistry Chemical Physics, Vol. 17, Issue 46 https://doi.org/10.1039/c5cp04544d	journal	January 2015
Ozone uptake on glassy, semi-solid and liquid organic matter and the role of reactive oxygen intermediates in atmospheric aerosol chemistry Berkemeier, Thomas; Steimer, Sarah S.; Krieger, Ulrich K. Physical Chemistry Chemical Physics, Vol. 18, Issue 18 https://doi.org/10.1039/c6cp00634e	journal	January 2016
Sucrose diffusion in aqueous solution Price, Hannah C.; Mattsson, Johan; Murray, Benjamin J. Physical Chemistry Chemical Physics, Vol. 18, Issue 28 https://doi.org/10.1039/c6cp03238a	journal	January 2016
Dynamic viscosity mapping of the oxidation of squalene aerosol particles Athanasiadis, Athanasios; Fitzgerald, Clare; Davidson, Nicholas M. Physical Chemistry Chemical Physics, Vol. 18, Issue 44 https://doi.org/10.1039/c6cp05674a	journal	January 2016
Condensed-phase biogenic–anthropogenic interactions with implications for cold cloud formation Charnawskas, Joseph C.; Alpert, Peter A.; Lambe, Andrew T. Faraday Discussions, Vol. 200 https://doi.org/10.1039/c7fd00010c	journal	January 2017
COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient Klamt, A.; Schüürmann, G. J. Chem. Soc., Perkin Trans. 2, Issue 5 https://doi.org/10.1039/p29930000799	journal	January 1993
Quantifying glass transition behavior in ultrathin free-standing polymer films Mattsson, J.; Forrest, J. A.; Börjesson, L. Physical Review E, Vol. 62, Issue 4 https://doi.org/10.1103/physreve.62.5187	journal	October 2000
Impactor Apparatus for the Study of Particle Rebound: Relative Humidity and Capillary Forces Bateman, Adam P.; Belassein, Helene; Martin, Scot T. Taylor & Francis https://doi.org/10.6084/m9.figshare.969666.v1	text	January 2014
Viscosity controls humidity dependence of N2O5 uptake to citric acid aerosol Grzinic, G.; Berkemeier, T.; Bartels-Rausch, T. European Geosciences Union https://doi.org/10.7892/boris.74957	text	January 2015

Cited By (27)

Physical Properties of Aerosol Internally Mixed With Soot Particles in a Biogenically Dominated Environment in California Sharma, Noopur; China, Swarup; Bhandari, Janarjan Geophysical Research Letters, Vol. 45, Issue 20 https://doi.org/10.1029/2018gl079404	journal	October 2018
Temperature- and Humidity-Dependent Phase States of Secondary Organic Aerosols Petters, Sarah S.; Kreidenweis, Sonia M.; Grieshop, Andrew P. Geophysical Research Letters, Vol. 46, Issue 2 https://doi.org/10.1029/2018gl080563	journal	January 2019
Aerosol Mixing State: Measurements, Modeling, and Impacts Riemer, N.; Ault, A. P.; West, M. Reviews of Geophysics, Vol. 57, Issue 2 https://doi.org/10.1029/2018rg000615	journal	May 2019
Extending surface enhanced Raman spectroscopy (SERS) of atmospheric aerosol particles to the accumulation mode (150–800 nm) Tirella, Peter N.; Craig, Rebecca L.; Tubbs, Darrell B. Environmental Science: Processes & Impacts, Vol. 20, Issue 11 https://doi.org/10.1039/c8em00276b	journal	January 2018
Microphysics of the aqueous bulk counters the water activity driven rate acceleration of bromide oxidation by ozone from 289–245 K Edebeli, Jacinta; Ammann, Markus; Bartels-Rausch, Thorsten Environmental Science: Processes & Impacts, Vol. 21, Issue 1 https://doi.org/10.1039/c8em00417j	journal	January 2019
From atoms to aerosols: probing clusters and nanoparticles with synchrotron based mass spectrometry and X-ray spectroscopy Ahmed, Musahid; Kostko, Oleg Physical Chemistry Chemical Physics, Vol. 22, Issue 5 https://doi.org/10.1039/c9cp05802h	journal	January 2020
Spherical tarball particles form through rapid chemical and physical changes of organic matter in biomass-burning smoke Adachi, Kouji; Sedlacek, Arthur J.; Kleinman, Lawrence Proceedings of the National Academy of Sciences, Vol. 116, Issue 39 https://doi.org/10.1073/pnas.1900129116	journal	September 2019
Optical deformation of single aerosol particles Rafferty, Aidan; Gorkowski, Kyle; Zuend, Andreas Proceedings of the National Academy of Sciences, Vol. 116, Issue 40 https://doi.org/10.1073/pnas.1907687116	journal	September 2019
Effect of Bulk Composition on the Heterogeneous Oxidation of Semi-Solid Atmospheric Aerosols Fan, Hanyu; Goulay, Fabien Atmosphere, Vol. 10, Issue 12 https://doi.org/10.3390/atmos10120791	journal	December 2019
The underappreciated role of nonvolatile cations in aerosol ammonium-sulfate molar ratios Guo, Hongyu; Nenes, Athanasios; Weber, Rodney J. Atmospheric Chemistry and Physics, Vol. 18, Issue 23 https://doi.org/10.5194/acp-18-17307-2018	journal	January 2018
Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition DeRieux, Wing-Sy Wong; Li, Ying; Lin, Peng Atmospheric Chemistry and Physics, Vol. 18, Issue 9 https://doi.org/10.5194/acp-18-6331-2018	journal	January 2018
Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations Evoy, Erin; Maclean, Adrian M.; Rovelli, Grazia Atmospheric Chemistry and Physics, Vol. 19, Issue 15 https://doi.org/10.5194/acp-19-10073-2019	journal	January 2019
Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors Song, Mijung; Maclean, Adrian M.; Huang, Yuanzhou Atmospheric Chemistry and Physics, Vol. 19, Issue 19 https://doi.org/10.5194/acp-19-12515-2019	journal	January 2019
A review of experimental techniques for aerosol hygroscopicity studies Tang, Mingjin; Chan, Chak K.; Li, Yong Jie Atmospheric Chemistry and Physics, Vol. 19, Issue 19 https://doi.org/10.5194/acp-19-12631-2019	journal	January 2019
Detection of tar brown carbon with a single particle soot photometer (SP2) Corbin, Joel C.; Gysel-Beer, Martin Atmospheric Chemistry and Physics, Vol. 19, Issue 24 https://doi.org/10.5194/acp-19-15673-2019	journal	January 2019
Optimization of process models for determining volatility distribution and viscosity of organic aerosols from isothermal particle evaporation data Tikkanen, Olli-Pekka; Hämäläinen, Väinö; Rovelli, Grazia Atmospheric Chemistry and Physics, Vol. 19, Issue 14 https://doi.org/10.5194/acp-19-9333-2019	journal	January 2019
Modelling the effect of condensed-phase diffusion on the homogeneous nucleation of ice in ultra-viscous particles Fowler, Kathryn; Connolly, Paul; Topping, David Atmospheric Chemistry and Physics, Vol. 20, Issue 2 https://doi.org/10.5194/acp-20-683-2020	journal	January 2020
Viscosity of erythritol and erythritol–water particles as a function of water activity: new results and an intercomparison of techniques for measuring the viscosity of particles Chu, Yangxi; Evoy, Erin; Kamal, Saeid Atmospheric Measurement Techniques, Vol. 11, Issue 8 https://doi.org/10.5194/amt-11-4809-2018	journal	January 2018
Multiphase chemistry in the troposphere: It all starts … and ends … with gases Finlayson‐Pitts, Barbara J. International Journal of Chemical Kinetics, Vol. 51, Issue 10 https://doi.org/10.1002/kin.21305	journal	June 2019
Significant broadband extinction abilities of bioaerosols Hu, Yihua; Zhao, Xinying; Gu, Youlin Science China Materials, Vol. 62, Issue 7 https://doi.org/10.1007/s40843-018-9411-9	journal	March 2019
Evidence for a kinetically controlled burying mechanism for growth of high viscosity secondary organic aerosol Vander Wall, Allison C.; Perraud, Véronique; Wingen, Lisa M. Environmental Science: Processes & Impacts, Vol. 22, Issue 1 https://doi.org/10.1039/c9em00379g	journal	January 2020
The effect of hydrophobic glassy organic material on the cloud condensation nuclei activity of particles with different morphologies Tandon, Ankit; Rothfuss, Nicholas E.; Petters, Markus D. Atmospheric Chemistry and Physics, Vol. 19, Issue 5 https://doi.org/10.5194/acp-19-3325-2019	journal	January 2019
A new aerosol flow reactor to study secondary organic aerosol Pereira, Kelly L.; Rovelli, Grazia; Song, Young C. Atmospheric Measurement Techniques, Vol. 12, Issue 8 https://doi.org/10.5194/amt-12-4519-2019	journal	January 2019
Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation Ullmann, Dagny A.; Hinks, Mallory L.; Maclean, Adrian M. Atmospheric Chemistry and Physics, Vol. 19, Issue 3 https://doi.org/10.5194/acp-19-1491-2019	journal	January 2019
Impact of Aerosol-Cloud Cycling on Aqueous Secondary Organic Aerosol Formation Tsui, William G.; Woo, Joseph L.; McNeill, V. Faye Atmosphere, Vol. 10, Issue 11 https://doi.org/10.3390/atmos10110666	journal	October 2019
Modeling the effect of non-ideality, dynamic mass transfer and viscosity on SOA formation in a 3-D air quality model Kim, Youngseob; Sartelet, Karine; Couvidat, Florian Atmospheric Chemistry and Physics, Vol. 19, Issue 2 https://doi.org/10.5194/acp-19-1241-2019	journal	January 2019
Microphysics of the aqueous bulk counters the water activity driven rate acceleration of bromide oxidation by ozone from 289-245 K Jacinta, Edebeli,; Markus, Ammann,; Thorsten, Bartels-Rausch, ETH Zurich https://doi.org/10.3929/ethz-b-000322290	text	January 2019

Similar Records

Development and Rigorous Validation of Modules for Predicting Organic Aerosol CCN Activity from Molecular Properties

Technical Report · Fri Aug 31 00:00:00 EDT 2018 · OSTI ID:1511471

Ziemann, Paul J.; Petters, Markus D.; Kreidenweis, Sonia M.

Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material

Journal Article · Wed Sep 16 00:00:00 EDT 2020 · Scientific Reports · OSTI ID:1511471

Petters, Markus; Kasparoglu, Sabin

Mass accommodation and gas–particle partitioning in secondary organic aerosols: dependence on diffusivity, volatility, particle-phase reactions, and penetration depth

Journal Article · Thu Feb 04 00:00:00 EST 2021 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1511471

Shiraiwa, Manabu; Pöschl, Ulrich

Related Subjects

54 ENVIRONMENTAL SCIENCES

Title: The viscosity of atmospherically relevant organic particles

Citation Formats

References (129)

Cited By (27)

Similar Records

Related Subjects