skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High-Pressure Oxidation of Propane

Abstract

The oxidation properties of propane have been investigated by conducting experiments in a laminar flow reactor at a pressure of 100 bar and temperatures of 500-900 K. The onset temperature for reaction increased from 625 K under oxidizing conditions to 725 K under reducing conditions. A chemical kinetic model for high pressure propane oxidation was established, with particular emphasis on the peroxide chemistry. The rate constant for the important abstraction reaction C3H8 + HO2 was calculated theoretically. Modeling predictions were in satisfactory agreement with the present data as well as shock tube data (6-61 bar) and flame speeds (1-5 bar) from literature. (C) 2018 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

Authors:
; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
European Union - Horizon 2020 Research and Innovation Programme; USDOE Office of Science - Office of Basic Energy Sciences - Chemical Sciences, Geosciences, and Biosciences Division
OSTI Identifier:
1510027
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Conference
Resource Relation:
Conference: 37th International Symposium on Combustion, 07/29/18 - 08/03/18, Dublin, IE
Country of Publication:
United States
Language:
English

Citation Formats

Hashemi, Hamid, Christensen, Jakob M., Harding, Lawrence B., Klippenstein, Stephen J., and Glarborg, Peter. High-Pressure Oxidation of Propane. United States: N. p., 2019. Web. doi:10.1016/j.proci.2018.07.009.
Hashemi, Hamid, Christensen, Jakob M., Harding, Lawrence B., Klippenstein, Stephen J., & Glarborg, Peter. High-Pressure Oxidation of Propane. United States. doi:10.1016/j.proci.2018.07.009.
Hashemi, Hamid, Christensen, Jakob M., Harding, Lawrence B., Klippenstein, Stephen J., and Glarborg, Peter. Tue . "High-Pressure Oxidation of Propane". United States. doi:10.1016/j.proci.2018.07.009.
@article{osti_1510027,
title = {High-Pressure Oxidation of Propane},
author = {Hashemi, Hamid and Christensen, Jakob M. and Harding, Lawrence B. and Klippenstein, Stephen J. and Glarborg, Peter},
abstractNote = {The oxidation properties of propane have been investigated by conducting experiments in a laminar flow reactor at a pressure of 100 bar and temperatures of 500-900 K. The onset temperature for reaction increased from 625 K under oxidizing conditions to 725 K under reducing conditions. A chemical kinetic model for high pressure propane oxidation was established, with particular emphasis on the peroxide chemistry. The rate constant for the important abstraction reaction C3H8 + HO2 was calculated theoretically. Modeling predictions were in satisfactory agreement with the present data as well as shock tube data (6-61 bar) and flame speeds (1-5 bar) from literature. (C) 2018 The Combustion Institute. Published by Elsevier Inc. All rights reserved.},
doi = {10.1016/j.proci.2018.07.009},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}

Conference:
Other availability
Please see Document Availability for additional information on obtaining the full-text document. Library patrons may search WorldCat to identify libraries that hold this conference proceeding.

Save / Share: