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Title: Beyond fossil fuel–driven nitrogen transformations

Abstract

This review summarizes chemical reactions of nitrogen, both oxidative and reductive reactions, as an outlook for moving beyond fossil-fuel driven reactions. The article focuses on the challenges and opportunities associated with the chemistry of N2, including thermodynamics of the nitrogen cycle, and then focusing on the reduced forms of nitrogen, primarily NH3, and then the oxidized forms. This article evolved from presentations and discussion at the workshop “Frontiers, Opportunities, and Challenges in Biochemical and Chemical N2 activation” held in October 2016, in Gaithersburg, Maryland. The workshop was sponsored by the Council on Chemical Sciences, Geosciences and Biosciences of the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. The authors thank the members of the Council for their encouragement and assistance in developing this workshop. In addition, the authors are indebted to the agencies responsible for funding of their individual research efforts, without which this work would not have been possible.

Authors:
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Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1508046
Report Number(s):
PNNL-SA-130348
Journal ID: ISSN 0036-8075
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Science
Additional Journal Information:
Journal Volume: 360; Journal Issue: 6391; Journal ID: ISSN 0036-8075
Publisher:
AAAS
Country of Publication:
United States
Language:
English

Citation Formats

Chen, Jingguang G., Crooks, Richard M., Seefeldt, Lance C., Bren, Kara L., Bullock, R. Morris, Darensbourg, Marcetta Y., Holland, Patrick L., Hoffman, Brian, Janik, Michael J., Jones, Anne K., Kanatzidis, Mercouri G., King, Paul, Lancaster, Kyle M., Lymar, Sergei V., Pfromm, Peter, Schneider, William F., and Schrock, Richard R. Beyond fossil fuel–driven nitrogen transformations. United States: N. p., 2018. Web. doi:10.1126/science.aar6611.
Chen, Jingguang G., Crooks, Richard M., Seefeldt, Lance C., Bren, Kara L., Bullock, R. Morris, Darensbourg, Marcetta Y., Holland, Patrick L., Hoffman, Brian, Janik, Michael J., Jones, Anne K., Kanatzidis, Mercouri G., King, Paul, Lancaster, Kyle M., Lymar, Sergei V., Pfromm, Peter, Schneider, William F., & Schrock, Richard R. Beyond fossil fuel–driven nitrogen transformations. United States. doi:10.1126/science.aar6611.
Chen, Jingguang G., Crooks, Richard M., Seefeldt, Lance C., Bren, Kara L., Bullock, R. Morris, Darensbourg, Marcetta Y., Holland, Patrick L., Hoffman, Brian, Janik, Michael J., Jones, Anne K., Kanatzidis, Mercouri G., King, Paul, Lancaster, Kyle M., Lymar, Sergei V., Pfromm, Peter, Schneider, William F., and Schrock, Richard R. Thu . "Beyond fossil fuel–driven nitrogen transformations". United States. doi:10.1126/science.aar6611.
@article{osti_1508046,
title = {Beyond fossil fuel–driven nitrogen transformations},
author = {Chen, Jingguang G. and Crooks, Richard M. and Seefeldt, Lance C. and Bren, Kara L. and Bullock, R. Morris and Darensbourg, Marcetta Y. and Holland, Patrick L. and Hoffman, Brian and Janik, Michael J. and Jones, Anne K. and Kanatzidis, Mercouri G. and King, Paul and Lancaster, Kyle M. and Lymar, Sergei V. and Pfromm, Peter and Schneider, William F. and Schrock, Richard R.},
abstractNote = {This review summarizes chemical reactions of nitrogen, both oxidative and reductive reactions, as an outlook for moving beyond fossil-fuel driven reactions. The article focuses on the challenges and opportunities associated with the chemistry of N2, including thermodynamics of the nitrogen cycle, and then focusing on the reduced forms of nitrogen, primarily NH3, and then the oxidized forms. This article evolved from presentations and discussion at the workshop “Frontiers, Opportunities, and Challenges in Biochemical and Chemical N2 activation” held in October 2016, in Gaithersburg, Maryland. The workshop was sponsored by the Council on Chemical Sciences, Geosciences and Biosciences of the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. The authors thank the members of the Council for their encouragement and assistance in developing this workshop. In addition, the authors are indebted to the agencies responsible for funding of their individual research efforts, without which this work would not have been possible.},
doi = {10.1126/science.aar6611},
journal = {Science},
issn = {0036-8075},
number = 6391,
volume = 360,
place = {United States},
year = {2018},
month = {5}
}

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Catalytic removal of NO
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A comprehensive review on PEM water electrolysis
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