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Title: Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission

Abstract

Here, the family of molecular level low–dimensional organic metal halide hybrids has expanded significantly over the last few years. Here a new type of 1D metal halide structure is reported, in which metal halide octahedra form a corrugated double–chain structure via nonplanar edge–sharing. This material with a chemical formula of C 5H 16N 2Pb 2Br 6 exhibits a broadband yellow emission under ultraviolet light excitation with a photoluminescence quantum efficiency of around 10%. The light–yellow emission is considered to be attributed to self–trapping excitons. Theoretical calculations show that the unique alignment of the octahedra leads to small band dispersion and large exciton binding energy. Together with previously reported 1D metal halide wires and tubes, this new bulk assembly of 1D metal halides suggests the potential to develop a library of bulk assemblies of metal halides with controlled structures and compositions.

Authors:
 [1];  [2];  [1];  [1]; ORCiD logo [3];  [4];  [1];  [1];  [1];  [2];  [5]; ORCiD logo [3]; ORCiD logo [1]
  1. Florida State Univ., Tallahassee, FL (United States)
  2. FAMU‐FSU College of Engineering, Tallahassee, FL (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. East China Normal Univ., Shanghai (China)
  5. FAMU‐FSU College of Engineering, Tallahassee, FL (United States); Florida State Univ., Tallahassee, FL (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1507863
Alternate Identifier(s):
OSTI ID: 1490909
Grant/Contract Number:  
AC05-00OR22725; DMR-1709116; 17RT0906; DMR-606952; DMR- 1644779; 61574059; 61722402
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Advanced Optical Materials
Additional Journal Information:
Journal Volume: 7; Journal Issue: 6; Journal ID: ISSN 2195-1071
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 1D structures; exciton self‐trapping; organic metal halide hybrids; photoluminescence; quantum confinement effect

Citation Formats

Lin, Haoran, Zhou, Chenkun, Neu, Jennifer, Zhou, Yan, Han, Dan, Chen, Shiyou, Worku, Michael, Chaaban, Maya, Lee, Sujin, Berkwits, Ella, Siegrist, Theo, Du, Mao ‐Hua, and Ma, Biwu. Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission. United States: N. p., 2019. Web. doi:10.1002/adom.201801474.
Lin, Haoran, Zhou, Chenkun, Neu, Jennifer, Zhou, Yan, Han, Dan, Chen, Shiyou, Worku, Michael, Chaaban, Maya, Lee, Sujin, Berkwits, Ella, Siegrist, Theo, Du, Mao ‐Hua, & Ma, Biwu. Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission. United States. doi:10.1002/adom.201801474.
Lin, Haoran, Zhou, Chenkun, Neu, Jennifer, Zhou, Yan, Han, Dan, Chen, Shiyou, Worku, Michael, Chaaban, Maya, Lee, Sujin, Berkwits, Ella, Siegrist, Theo, Du, Mao ‐Hua, and Ma, Biwu. Tue . "Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission". United States. doi:10.1002/adom.201801474. https://www.osti.gov/servlets/purl/1507863.
@article{osti_1507863,
title = {Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission},
author = {Lin, Haoran and Zhou, Chenkun and Neu, Jennifer and Zhou, Yan and Han, Dan and Chen, Shiyou and Worku, Michael and Chaaban, Maya and Lee, Sujin and Berkwits, Ella and Siegrist, Theo and Du, Mao ‐Hua and Ma, Biwu},
abstractNote = {Here, the family of molecular level low–dimensional organic metal halide hybrids has expanded significantly over the last few years. Here a new type of 1D metal halide structure is reported, in which metal halide octahedra form a corrugated double–chain structure via nonplanar edge–sharing. This material with a chemical formula of C5H16N2Pb2Br6 exhibits a broadband yellow emission under ultraviolet light excitation with a photoluminescence quantum efficiency of around 10%. The light–yellow emission is considered to be attributed to self–trapping excitons. Theoretical calculations show that the unique alignment of the octahedra leads to small band dispersion and large exciton binding energy. Together with previously reported 1D metal halide wires and tubes, this new bulk assembly of 1D metal halides suggests the potential to develop a library of bulk assemblies of metal halides with controlled structures and compositions.},
doi = {10.1002/adom.201801474},
journal = {Advanced Optical Materials},
issn = {2195-1071},
number = 6,
volume = 7,
place = {United States},
year = {2019},
month = {1}
}

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Cited by: 6 works
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