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Title: Structural analysis of the initial lithiation of NiO thin film electrodes

Abstract

Our results reveal that conversion reactions and structural changes in NiO thin film electrodes begin near the theoretical lithiation potential.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [1];  [3]; ORCiD logo [4];  [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [5]
  1. Department of Materials Science and Engineering, Northwestern University, Evanston, USA
  2. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, USA
  3. NUANCE Center, Northwestern University, Evanston, USA, Department of Mechanical Engineering
  4. X-ray Science Division, Argonne National Laboratory, Lemont, USA
  5. Department of Materials Science and Engineering, Northwestern University, Evanston, USA, Department of Physics and Astronomy, Northwestern University
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1507165
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print) Journal Volume: 21 Journal Issue: 17; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Evmenenko, Guennadi, Fister, Timothy T., Castro, Fernando C., Chen, Xinqi, Lee, Byeongdu, Buchholz, D. Bruce, Dravid, Vinayak P., Fenter, Paul, and Bedzyk, Michael J. Structural analysis of the initial lithiation of NiO thin film electrodes. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CP01527B.
Evmenenko, Guennadi, Fister, Timothy T., Castro, Fernando C., Chen, Xinqi, Lee, Byeongdu, Buchholz, D. Bruce, Dravid, Vinayak P., Fenter, Paul, & Bedzyk, Michael J. Structural analysis of the initial lithiation of NiO thin film electrodes. United Kingdom. doi:10.1039/C9CP01527B.
Evmenenko, Guennadi, Fister, Timothy T., Castro, Fernando C., Chen, Xinqi, Lee, Byeongdu, Buchholz, D. Bruce, Dravid, Vinayak P., Fenter, Paul, and Bedzyk, Michael J. Wed . "Structural analysis of the initial lithiation of NiO thin film electrodes". United Kingdom. doi:10.1039/C9CP01527B.
@article{osti_1507165,
title = {Structural analysis of the initial lithiation of NiO thin film electrodes},
author = {Evmenenko, Guennadi and Fister, Timothy T. and Castro, Fernando C. and Chen, Xinqi and Lee, Byeongdu and Buchholz, D. Bruce and Dravid, Vinayak P. and Fenter, Paul and Bedzyk, Michael J.},
abstractNote = {Our results reveal that conversion reactions and structural changes in NiO thin film electrodes begin near the theoretical lithiation potential.},
doi = {10.1039/C9CP01527B},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
issn = {1463-9076},
number = 17,
volume = 21,
place = {United Kingdom},
year = {2019},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1039/C9CP01527B

Citation Metrics:
Cited by: 1 work
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Works referenced in this record:

High-Capacity Anode Materials for Lithium-Ion Batteries: Choice of Elements and Structures for Active Particles
journal, October 2013

  • Nitta, Naoki; Yushin, Gleb
  • Particle & Particle Systems Characterization, Vol. 31, Issue 3
  • DOI: 10.1002/ppsc.201300231

Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics
journal, January 2017

  • Evmenenko, Guennadi; Fister, Timothy T.; Buchholz, D. Bruce
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 30
  • DOI: 10.1039/C7CP02448G

Particle Size Effects on the Electrochemical Performance of Copper Oxides toward Lithium
journal, January 2001

  • Grugeon, S.; Laruelle, S.; Herrera-Urbina, R.
  • Journal of The Electrochemical Society, Vol. 148, Issue 4
  • DOI: 10.1149/1.1353566

Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries
journal, March 2013

  • Reddy, M. V.; Subba Rao, G. V.; Chowdari, B. V. R.
  • Chemical Reviews, Vol. 113, Issue 7
  • DOI: 10.1021/cr3001884

Co-refinement of multiple-contrast neutron/X-ray reflectivity data using MOTOFIT
journal, March 2006


New design on Li-ion battery anode of ternary complex metal/metal oxide@CNT: A case study of hierarchical NiCo-NiCo2O4@CNTs
journal, December 2018


Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems
journal, September 2013

  • Zhan, Chun; Lu, Jun; Jeremy Kropf, A.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3437

A study on capacity fading of lithium-ion battery with manganese spinel positive electrode during cycling
journal, April 2006


Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights
journal, October 2015

  • Gauthier, Magali; Carney, Thomas J.; Grimaud, Alexis
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
  • DOI: 10.1021/acs.jpclett.5b01727

Effect of SEI on Capacity Losses of Spinel Lithium Manganese Oxide/Graphite Batteries Stored at 60°C
journal, January 2010

  • Cho, In Haeng; Kim, Sung-Soo; Shin, Soon Cheol
  • Electrochemical and Solid-State Letters, Vol. 13, Issue 11
  • DOI: 10.1149/1.3481711

Molecular Probes Reveal Chemical Selectivity of the Solid–Electrolyte Interphase
journal, August 2018

  • Harris, Oliver C.; Tang, Maureen H.
  • The Journal of Physical Chemistry C, Vol. 122, Issue 36
  • DOI: 10.1021/acs.jpcc.8b06564

Enhancing the performances of Li-ion batteries by carbon-coating: present and future
journal, January 2012


Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009


Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004


Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014


Design and performance of the 33-BM beamline at the Advanced Photon Source
journal, September 2011

  • Karapetrova, Evguenia; Ice, Gene; Tischler, Jonathan
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 649, Issue 1
  • DOI: 10.1016/j.nima.2010.12.159

Highly ordered mesoporous NiO anode material for lithium ion batteries with an excellent electrochemical performance
journal, January 2011

  • Liu, Hao; Wang, Guoxiu; Liu, Jian
  • Journal of Materials Chemistry, Vol. 21, Issue 9
  • DOI: 10.1039/c0jm03132a

Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review
journal, January 2018

  • Zhan, Chun; Wu, Tianpin; Lu, Jun
  • Energy & Environmental Science, Vol. 11, Issue 2
  • DOI: 10.1039/C7EE03122J

Revealing the Conversion Mechanism of Transition Metal Oxide Electrodes during Lithiation from First-Principles
journal, October 2017


New interpretations of XPS spectra of nickel metal and oxides
journal, May 2006

  • Grosvenor, Andrew P.; Biesinger, Mark C.; Smart, Roger St. C.
  • Surface Science, Vol. 600, Issue 9
  • DOI: 10.1016/j.susc.2006.01.041

Ultimate Limits to Intercalation Reactions for Lithium Batteries
journal, October 2014

  • Whittingham, M. Stanley
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr5003003

Electrochemical study of NiO nanosheets: toward the understanding of capacity fading
journal, February 2017

  • Kaspar, Jan; Bazarjani, Mahdi Seifollahi; Schitco, Cristina
  • Journal of Materials Science, Vol. 52, Issue 11
  • DOI: 10.1007/s10853-017-0885-0

p-Type semiconducting nickel oxide as an efficiency-enhancing anode interfacial layer in polymer bulk-heterojunction solar cells
journal, February 2008

  • Irwin, M. D.; Buchholz, D. B.; Hains, A. W.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 8, p. 2783-2787
  • DOI: 10.1073/pnas.0711990105

Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Batteries
journal, January 2014

  • Joshi, Tapesh; Eom, KwangSup; Yushin, Gleb
  • Journal of The Electrochemical Society, Vol. 161, Issue 12
  • DOI: 10.1149/2.0861412jes

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

  • Poizot, P.; Laruelle, S.; Grugeon, S.
  • Nature, Vol. 407, Issue 6803, p. 496-499
  • DOI: 10.1038/35035045

Advanced grazing-incidence techniques for modern soft-matter materials analysis
journal, January 2015


Sputter reduction of oxides by ion bombardment during Auger depth profile analysis
journal, August 1990

  • Mitchell, D. F.; Sproule, G. I.; Graham, M. J.
  • Surface and Interface Analysis, Vol. 15, Issue 8
  • DOI: 10.1002/sia.740150808

Scattering functions of polyhedra
journal, March 2015


Examining Solid Electrolyte Interphase Formation on Crystalline Silicon Electrodes: Influence of Electrochemical Preparation and Ambient Exposure Conditions
journal, September 2012

  • Schroder, Kjell W.; Celio, Hugo; Webb, Lauren J.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 37
  • DOI: 10.1021/jp307372m

The defect structure of nickel oxide surfaces as revealed by photoelectron spectroscopy
journal, January 1984

  • Roberts, M. Wyn; Smart, Roger St C.
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 80, Issue 11
  • DOI: 10.1039/f19848002957

Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
journal, August 2010

  • Cabana, Jordi; Monconduit, Laure; Larcher, Dominique
  • Advanced Materials, Vol. 22, Issue 35
  • DOI: 10.1002/adma.201000717

Mesoporous NiO nanosheet networks as high performance anodes for Li ion batteries
journal, January 2013

  • Wang, Xinghui; Qiao, Li; Sun, Xiaolei
  • Journal of Materials Chemistry A, Vol. 1, Issue 13
  • DOI: 10.1039/c3ta01640d

Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells
journal, December 2016

  • Gilbert, James A.; Shkrob, Ilya A.; Abraham, Daniel P.
  • Journal of The Electrochemical Society, Vol. 164, Issue 2
  • DOI: 10.1149/2.1111702jes

Superior Li-ion storage performance of graphene decorated NiO nanowalls on Ni as anode for lithium ion batteries
journal, January 2019


Ultrathin nickel oxide nanosheets for enhanced sodium and lithium storage
journal, January 2015


Multifunctional Ni/NiO hybrid nanomembranes as anode materials for high-rate Li-ion batteries
journal, October 2014


A critical review-promises and barriers of conversion electrodes for Li-ion batteries
journal, April 2017

  • Kraytsberg, Alexander; Ein-Eli, Yair
  • Journal of Solid State Electrochemistry, Vol. 21, Issue 7
  • DOI: 10.1007/s10008-017-3580-9

Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

  • Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01598b

White lines and d -band occupancy for the 3 d transition-metal oxides and lithium transition-metal oxides
journal, June 2004


Li-Storage via Heterogeneous Reaction in Selected Binary Metal Fluorides and Oxides
journal, January 2004

  • Li, Hong; Balaya, Palani; Maier, Joachim
  • Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1878-A1885
  • DOI: 10.1149/1.1801451

Synthesis of NiO Nano Octahedron Aggregates as High-Performance Anode Materials for Lithium Ion Batteries
journal, March 2017


Morphological Evolution of Multilayer Ni/NiO Thin Film Electrodes during Lithiation
journal, July 2016

  • Evmenenko, Guennadi; Fister, Timothy T.; Buchholz, D. Bruce
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 31
  • DOI: 10.1021/acsami.6b05040

Real-Time Observations of Interfacial Lithiation in a Metal Silicide Thin Film
journal, October 2012

  • Fister, Tim T.; Long, Brandon R.; Gewirth, Andrew A.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 42
  • DOI: 10.1021/jp305465j

NiO nanomaterials: controlled fabrication, formation mechanism and the application in lithium-ion battery
journal, January 2012

  • Ma, Jianmin; Yang, Jiaqin; Jiao, Lifang
  • CrystEngComm, Vol. 14, Issue 2
  • DOI: 10.1039/C1CE05567D

Anomalous Surface Reflection of X Rays
journal, September 1963


Chemical Distribution and Bonding of Lithium in Intercalated Graphite: Identification with Optimized Electron Energy Loss Spectroscopy
journal, January 2011

  • Wang, Feng; Graetz, Jason; Moreno, M. Sergio
  • ACS Nano, Vol. 5, Issue 2
  • DOI: 10.1021/nn1028168

Thermodynamic analysis on energy densities of batteries
journal, January 2011

  • Zu, Chen-Xi; Li, Hong
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c0ee00777c

Nanostructured NiO electrode for high rate Li-ion batteries
journal, January 2011

  • Wang, Xinghui; Li, Xiuwan; Sun, Xiaolei
  • Journal of Materials Chemistry, Vol. 21, Issue 11
  • DOI: 10.1039/c0jm04356g

NiO nanocone array electrode with high capacity and rate capability for Li-ion batteries
journal, January 2011

  • Wang, Xinghui; Yang, Zhibo; Sun, Xiaolei
  • Journal of Materials Chemistry, Vol. 21, Issue 27
  • DOI: 10.1039/c1jm11490e

Oxidation state of cross-over manganese species on the graphite electrode of lithium-ion cells
journal, January 2014

  • Gowda, Sanketh R.; Gallagher, Kevin G.; Croy, Jason R.
  • Physical Chemistry Chemical Physics, Vol. 16, Issue 15
  • DOI: 10.1039/c4cp00764f

NiGa 2 O 4 /rGO Composite as Long-Cycle-Life Anode Material for Lithium-Ion Batteries
journal, January 2019

  • Huang, Yongmin; Ouyang, Jiaxing; Tang, Xun
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 8
  • DOI: 10.1021/acsami.8b21581

Effect of Manganese Contamination on the Solid-Electrolyte-Interphase Properties in Li-Ion Batteries
journal, January 2013

  • Delacourt, C.; Kwong, A.; Liu, X.
  • Journal of The Electrochemical Society, Vol. 160, Issue 8
  • DOI: 10.1149/2.035308jes

Structural and Electrical Functionality of NiO Interfacial Films in Bulk Heterojunction Organic Solar Cells
journal, April 2011

  • Irwin, Michael D.; Servaites, Jonathan D.; Buchholz, D. Bruce
  • Chemistry of Materials, Vol. 23, Issue 8
  • DOI: 10.1021/cm200229e

Structure and Bonding at Ni–ZrO 2 (Cubic) Interfaces Formed by the Reduction of a NiO–ZrO 2 (Cubic) Composite
journal, September 1997


Distribution of intercalated lithium in V2O5 thin films determined by SIMS depth profiling
journal, January 2006

  • Alamarguy, D.; Castle, J. E.; Liberatore, M.
  • Surface and Interface Analysis, Vol. 38, Issue 4
  • DOI: 10.1002/sia.2139

XPS depth profile analysis of non-stoichiometric NiO films
journal, January 2004

  • Oswald, S.; Brückner, W.
  • Surface and Interface Analysis, Vol. 36, Issue 1
  • DOI: 10.1002/sia.1640

Surface and interface sciences of Li-ion batteries
journal, December 2017


XPS and UPS studies on electronic structure of Li2O
journal, December 2000