Higher Mobility and Carrier Lifetimes in Solution-Processable Small-Molecule Ternary Solar Cells with 11% Efficiency

Liang, Ru -Ze; Zhang, Yiming; Savikhin, Victoria; Babics, Maxime; Kan, Zhipeng; Wohlfahrt, Markus; Wehbe, Nimer; Liu, Shengjian; Duan, Tainan; Toney, Michael F.; Laquai, Frédéric; Beaujuge, Pierre M.

doi:10.1002/aenm.201802836

Title: Higher Mobility and Carrier Lifetimes in Solution-Processable Small-Molecule Ternary Solar Cells with 11% Efficiency

Journal Article · Thu Dec 20 00:00:00 EST 2018 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201802836· OSTI ID:1506958

^[1]; Zhang, Yiming ^[1]; Savikhin, Victoria ^[2]; Babics, Maxime ^[1]; Kan, Zhipeng ^[1]; Wohlfahrt, Markus ^[1]; Wehbe, Nimer ^[1]; Liu, Shengjian ^[1]; Duan, Tainan ^[1]; Toney, Michael F. ^[3]; Laquai, Frédéric ^[1]; Beaujuge, Pierre M. ^[1]

King Abdullah Univ. of Science and Technology (KAUST), Thuwal (Saudi Arabia)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)

Abstract Solution‐processed small molecule (SM) solar cells have the prospect to outperform their polymer‐fullerene counterparts. Considering that both SM donors/acceptors absorb in visible spectral range, higher expected photocurrents should in principle translate into higher power conversion efficiencies (PCEs). However, limited bulk‐heterojunction (BHJ) charge carrier mobility (<10 ^‐4 cm ² V ^‐1 s ^‐1 ) and carrier lifetimes (<1 µs) often impose active layer thickness constraints on BHJ devices (≈100 nm), limiting external quantum efficiencies (EQEs) and photocurrent, and making large‐scale processing techniques particularly challenging. In this report, it is shown that ternary BHJs composed of the SM donor DR3TBDTT (DR3), the SM acceptor ICC6 and the fullerene acceptor PC ₇₁ BM can be used to achieve SM‐based ternary BHJ solar cells with active layer thicknesses >200 nm and PCEs nearing 11%. The examinations show that these remarkable figures are the result of i) significantly improved electron mobility (8.2 × 10 ^‐4 cm ² V ^‐1 s ^‐1 ), ii) longer carrier lifetimes (2.4 µs), and iii) reduced geminate recombination within BHJ active layers to which PC ₇₁ BM has been added as ternary component. Optically thick (up to ≈500 nm) devices are shown to maintain PCEs >8%, and optimized DR3:ICC6:PC ₇₁ BM solar cells demonstrate long‐term shelf stability (dark) for >1000 h, in 55% humidity air environment.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: CRG_R2_13_BEAU_KAUST_1; AC02-76SF00515; DE‐AC02‐76SF00515

OSTI ID:: 1506958

Alternate ID(s):: OSTI ID: 1488622

Journal Information:: Advanced Energy Materials, Vol. 9, Issue 7; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 52 works

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References (70)

A High-Performing Solution-Processed Small Molecule:Perylene Diimide Bulk Heterojunction Solar Cell Sharenko, Alexander; Proctor, Christopher M.; van der Poll, Thomas S. Advanced Materials, Vol. 25, Issue 32 https://doi.org/10.1002/adma.201301167	journal	June 2013
Comparison of the Morphology Development of Polymer-Fullerene and Polymer-Polymer Solar Cells during Solution-Shearing Blade Coating Gu, Xiaodan; Yan, Hongping; Kurosawa, Tadanori Advanced Energy Materials, Vol. 6, Issue 22 https://doi.org/10.1002/aenm.201601225	journal	August 2016
Ternary blend polymer solar cells with enhanced power conversion efficiency Lu, Luyao; Xu, Tao; Chen, Wei Nature Photonics, Vol. 8, Issue 9 https://doi.org/10.1038/nphoton.2014.172	journal	August 2014
Impact of interfacial molecular orientation on radiative recombination and charge generation efficiency Ran, Niva A.; Roland, Steffen; Love, John A. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00107-4	journal	July 2017
Nonfullerene-Acceptor All-Small-Molecule Organic Solar Cells Based on Highly Twisted Perylene Bisimide with an Efficiency of over 6% Xin, Rui; Feng, Jiajing; Zeng, Cheng ACS Applied Materials & Interfaces, Vol. 9, Issue 3 https://doi.org/10.1021/acsami.6b13721	journal	January 2017
Recent advances in organic ternary solar cells Huang, Hui; Yang, Lei; Sharma, Bigyan Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA00887B	journal	January 2017
Versatile ternary organic solar cells: a critical review An, Qiaoshi; Zhang, Fujun; Zhang, Jian Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE02641E	journal	January 2016
Triperylene Hexaimides Based All‐Small‐Molecule Solar Cells with an Efficiency over 6% and Open Circuit Voltage of 1.04 V Liang, Ningning; Meng, Dong; Ma, Zetong Advanced Energy Materials, Vol. 7, Issue 6 https://doi.org/10.1002/aenm.201601664	journal	November 2016
Interplay Between Side Chain Pattern, Polymer Aggregation, and Charge Carrier Dynamics in PBDTTPD:PCBM Bulk-Heterojunction Solar Cells Dyer-Smith, Clare; Howard, Ian A.; Cabanetos, Clément Advanced Energy Materials, Vol. 5, Issue 9 https://doi.org/10.1002/aenm.201401778	journal	January 2015
Efficient inverted polymer solar cells employing favourable molecular orientation Vohra, Varun; Kawashima, Kazuaki; Kakara, Takeshi Nature Photonics, Vol. 9, Issue 6 https://doi.org/10.1038/nphoton.2015.84	journal	May 2015
Comparison of the Operation of Polymer/Fullerene, Polymer/Polymer, and Polymer/Nanocrystal Solar Cells: A Transient Photocurrent and Photovoltage Study Li, Zhe; Gao, Feng; Greenham, Neil C. Advanced Functional Materials, Vol. 21, Issue 8 https://doi.org/10.1002/adfm.201002154	journal	March 2011
High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor Holliday, Sarah; Ashraf, Raja Shahid; Wadsworth, Andrew Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11585	journal	June 2016
Solvent Annealing Effects in Dithieno[3,2- b :2′,3′- d ]pyrrole–5,6-Difluorobenzo[ c ][1,2,5]thiadiazole Small Molecule Donors for Bulk-Heterojunction Solar Cells Wang, Kai; Azouz, Mehdi; Babics, Maxime Chemistry of Materials, Vol. 28, Issue 15 https://doi.org/10.1021/acs.chemmater.6b01763	journal	July 2016
Morphology changes upon scaling a high-efficiency, solution-processed solar cell Ro, Hyun Wook; Downing, Jonathan M.; Engmann, Sebastian Energy & Environmental Science, Vol. 9, Issue 9 https://doi.org/10.1039/C6EE01623E	journal	January 2016
Polymer/Small Molecule/Fullerene Based Ternary Solar Cells Li, Huan; Lu, Kun; Wei, Zhixiang Advanced Energy Materials, Vol. 7, Issue 17 https://doi.org/10.1002/aenm.201602540	journal	April 2017
Highly efficient and thermally stable fullerene-free organic solar cells based on a small molecule donor and acceptor Badgujar, Sachin; Song, Chang Eun; Oh, Sora Journal of Materials Chemistry A, Vol. 4, Issue 42 https://doi.org/10.1039/C6TA06367E	journal	January 2016
Semi-crystalline photovoltaic polymers with efficiency exceeding 9% in a ∼300 nm thick conventional single-cell device Nguyen, T. L.; Choi, H.; Ko, S. -J. Energy Environ. Sci., Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01529K	journal	January 2014
Optimization of monochromated TEM for ultimate resolution imaging and ultrahigh resolution electron energy loss spectroscopy Lopatin, Sergei; Cheng, Bin; Liu, Wei-Ting Ultramicroscopy, Vol. 184 https://doi.org/10.1016/j.ultramic.2017.08.016	journal	January 2018
Recent progress in non-fullerene small molecule acceptors in organic solar cells (OSCs) Chen, Wangqiao; Zhang, Qichun Journal of Materials Chemistry C, Vol. 5, Issue 6 https://doi.org/10.1039/C6TC05066B	journal	January 2017
All-small-molecule organic solar cells based on an electron donor incorporating binary electron-deficient units Feng, Guitao; Xu, Yunhua; Zhang, Jianqi Journal of Materials Chemistry A, Vol. 4, Issue 16 https://doi.org/10.1039/C5TA10430K	journal	January 2016
Efficient organic solar cells processed from hydrocarbon solvents Zhao, Jingbo; Li, Yunke; Yang, Guofang Nature Energy, Vol. 1, Issue 2 https://doi.org/10.1038/nenergy.2015.27	journal	January 2016
Carrier Transport and Recombination in Efficient “All-Small-Molecule” Solar Cells with the Nonfullerene Acceptor IDTBR Liang, Ru-Ze; Babics, Maxime; Savikhin, Victoria Advanced Energy Materials, Vol. 8, Issue 19 https://doi.org/10.1002/aenm.201800264	journal	April 2018
High-Performance Ternary Organic Solar Cell Enabled by a Thick Active Layer Containing a Liquid Crystalline Small Molecule Donor Zhang, Guichuan; Zhang, Kai; Yin, Qingwu Journal of the American Chemical Society, Vol. 139, Issue 6 https://doi.org/10.1021/jacs.6b11991	journal	February 2017
Additive-Morphology Interplay and Loss Channels in “All-Small-Molecule” Bulk-heterojunction (BHJ) Solar Cells with the Nonfullerene Acceptor IDTTBM Liang, Ru-Ze; Babics, Maxime; Seitkhan, Akmaral Advanced Functional Materials, Vol. 28, Issue 7 https://doi.org/10.1002/adfm.201705464	journal	December 2017
High-efficiency small-molecule ternary solar cells with a hierarchical morphology enabled by synergizing fullerene and non-fullerene acceptors Zhou, Zichun; Xu, Shengjie; Song, Jingnan Nature Energy, Vol. 3, Issue 11 https://doi.org/10.1038/s41560-018-0234-9	journal	September 2018
Polymer solar cells with enhanced fill factors Guo, Xugang; Zhou, Nanjia; Lou, Sylvia J. Nature Photonics, Vol. 7, Issue 10 https://doi.org/10.1038/nphoton.2013.207	journal	August 2013
Recombination Dynamics as a Key Determinant of Open Circuit Voltage in Organic Bulk Heterojunction Solar Cells: A Comparison of Four Different Donor Polymers Maurano, Andrea; Hamilton, Rick; Shuttle, Chris G. Advanced Materials, Vol. 22, Issue 44 https://doi.org/10.1002/adma.201002360	journal	August 2010
Non-Fullerene Electron Acceptors for Use in Organic Solar Cells Nielsen, Christian B.; Holliday, Sarah; Chen, Hung-Yang Accounts of Chemical Research, Vol. 48, Issue 11 https://doi.org/10.1021/acs.accounts.5b00199	journal	October 2015
Recombination in polymer-fullerene bulk heterojunction solar cells Cowan, Sarah R.; Roy, Anshuman; Heeger, Alan J. Physical Review B, Vol. 82, Issue 24 https://doi.org/10.1103/PhysRevB.82.245207	journal	December 2010
Highly oriented crystals at the buried interface in polythiophene thin-film transistors Joseph Kline, R.; McGehee, Michael D.; Toney, Michael F. Nature Materials, Vol. 5, Issue 3 https://doi.org/10.1038/nmat1590	journal	February 2006
Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells Liu, Yuhang; Zhao, Jingbo; Li, Zhengke Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6293	journal	November 2014
Effects of Solvent Additives on Morphology, Charge Generation, Transport, and Recombination in Solution-Processed Small-Molecule Solar Cells Kyaw, Aung Ko Ko; Wang, Dong Hwan; Luo, Chan Advanced Energy Materials, Vol. 4, Issue 7 https://doi.org/10.1002/aenm.201301469	journal	January 2014
Morphology evolution via self-organization and lateral and vertical diffusion in polymer:fullerene solar cell blends Campoy-Quiles, Mariano; Ferenczi, Toby; Agostinelli, Tiziano Nature Materials, Vol. 7, Issue 2 https://doi.org/10.1038/nmat2102	journal	January 2008
High-Performance Organic Solar Cells Based on a Small Molecule with Alkylthio-Thienyl-Conjugated Side Chains without Extra Treatments Cui, Chaohua; Guo, Xia; Min, Jie Advanced Materials, Vol. 27, Issue 45 https://doi.org/10.1002/adma.201503815	journal	October 2015
Solution-Processed and High-Performance Organic Solar Cells Using Small Molecules with a Benzodithiophene Unit Zhou, Jiaoyan; Zuo, Yi; Wan, Xiangjian Journal of the American Chemical Society, Vol. 135, Issue 23 https://doi.org/10.1021/ja403318y	journal	May 2013
Understanding the morphology of solution processed fullerene-free small molecule bulk heterojunction blends Namepetra, Andrew; Kitching, Elizabeth; Eftaiha, Ala'a F. Physical Chemistry Chemical Physics, Vol. 18, Issue 18 https://doi.org/10.1039/C6CP01269H	journal	January 2016
Structural Origins for Tunable Open-Circuit Voltage in Ternary-Blend Organic Solar Cells Khlyabich, Petr P.; Rudenko, Andrey E.; Thompson, Barry C. Advanced Functional Materials, Vol. 25, Issue 34 https://doi.org/10.1002/adfm.201502287	journal	August 2015
Ternary solar cells with a mixed face-on and edge-on orientation enable an unprecedented efficiency of 12.1% Kumari, Tanya; Lee, Sang Myeon; Kang, So-Huei Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/C6EE02851A	journal	January 2017
25th Anniversary Article: Bulk Heterojunction Solar Cells: Understanding the Mechanism of Operation Heeger, Alan J. Advanced Materials, Vol. 26, Issue 1 https://doi.org/10.1002/adma.201304373	journal	December 2013
Schematic Studies on the Structural Properties and Device Physics of All Small Molecule Ternary Photovoltaic Cells Kim, Yu Jin; Hong, Jisu; Park, Chan Eon ACS Applied Materials & Interfaces, Vol. 7, Issue 38 https://doi.org/10.1021/acsami.5b06365	journal	September 2015
Status and prospects for ternary organic photovoltaics Lu, Luyao; Kelly, Mary Allison; You, Wei Nature Photonics, Vol. 9, Issue 8 https://doi.org/10.1038/nphoton.2015.128	journal	July 2015
Film morphology evolution during solvent vapor annealing of highly efficient small molecule donor/acceptor blends Engmann, Sebastian; Ro, Hyun Wook; Herzing, Andrew Journal of Materials Chemistry A, Vol. 4, Issue 40 https://doi.org/10.1039/C6TA05056E	journal	January 2016
Competition between recombination and extraction of free charges determines the fill factor of organic solar cells Bartesaghi, Davide; Pérez, Irene del Carmen; Kniepert, Juliane Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8083	journal	May 2015
A molecular nematic liquid crystalline material for high-performance organic photovoltaics Sun, Kuan; Xiao, Zeyun; Lu, Shirong Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7013	journal	January 2015
Solution-processed small-molecule solar cells with 6.7% efficiency Sun, Yanming; Welch, Gregory C.; Leong, Wei Lin Nature Materials, Vol. 11, Issue 1, p. 44-48 https://doi.org/10.1038/nmat3160	journal	November 2011
High performance all-small-molecule solar cells: engineering the nanomorphology via processing additives Min, Jie; Kwon, Oh Kyu; Cui, Chaohua Journal of Materials Chemistry A, Vol. 4, Issue 37 https://doi.org/10.1039/C6TA05303C	journal	January 2016
Tuning the optoelectronic properties for high-efficiency (>7.5%) all small molecule and fullerene-free solar cells Privado, María; Cuesta, Virginia; de la Cruz, Pilar Journal of Materials Chemistry A, Vol. 5, Issue 27 https://doi.org/10.1039/C7TA03815A	journal	January 2017
Benzo[1,2- b :4,5- b ′]dithiophene–Pyrido[3,4- b ]pyrazine Small-Molecule Donors for Bulk Heterojunction Solar Cells Wolf, Jannic; Babics, Maxime; Wang, Kai Chemistry of Materials, Vol. 28, Issue 7 https://doi.org/10.1021/acs.chemmater.5b04726	journal	February 2016
Ternary Organic Solar Cells with >11% Efficiency Incorporating Thick Photoactive Layer and Nonfullerene Small Molecule Acceptor Zhang, Tong; Zhao, Xiaoli; Yang, Dalei Advanced Energy Materials, Vol. 8, Issue 4 https://doi.org/10.1002/aenm.201701691	journal	September 2017
Panchromatic Sequentially Cast Ternary Polymer Solar Cells Ghasemi, Masoud; Ye, Long; Zhang, Qianqian Advanced Materials, Vol. 29, Issue 4 https://doi.org/10.1002/adma.201604603	journal	November 2016
Benzo[1,2- b :4,5- b ′]Dithiophene-6,7-Difluoroquinoxaline Small Molecule Donors with >8% BHJ Solar Cell Efficiency Liang, Ru-Ze; Wang, Kai; Wolf, Jannic Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201602804	journal	July 2017
Reducing the efficiency–stability–cost gap of organic photovoltaics with highly efficient and stable small molecule acceptor ternary solar cells Baran, Derya; Ashraf, Raja Shahid; Hanifi, David A. Nature Materials, Vol. 16, Issue 3 https://doi.org/10.1038/nmat4797	journal	November 2016
Trap-Induced Losses in Hybrid Photovoltaics Gao, Feng; Li, Zhe; Wang, Jianpu ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn501185h	journal	March 2014
High-performance ternary blend polymer solar cells involving both energy transfer and hole relay processes Lu, Luyao; Chen, Wei; Xu, Tao Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8327	journal	June 2015
Small is Powerful: Recent Progress in Solution-Processed Small Molecule Solar Cells Collins, Samuel D.; Ran, Niva A.; Heiber, Michael C. Advanced Energy Materials, Vol. 7, Issue 10 https://doi.org/10.1002/aenm.201602242	journal	January 2017
Achieving Highly Efficient Nonfullerene Organic Solar Cells with Improved Intermolecular Interaction and Open-Circuit Voltage Yao, Huifeng; Ye, Long; Hou, Junxian Advanced Materials, Vol. 29, Issue 21 https://doi.org/10.1002/adma.201700254	journal	March 2017
A Facile Planar Fused-Ring Electron Acceptor for As-Cast Polymer Solar Cells with 8.71% Efficiency Lin, Yuze; He, Qiao; Zhao, Fuwen Journal of the American Chemical Society, Vol. 138, Issue 9 https://doi.org/10.1021/jacs.6b00853	journal	February 2016
Unique Reversible Crystal-to-Crystal Phase Transition—Structural and Functional Properties of Fused Ladder Thienoarenes Abe, Yuichiro; Savikhin, Victoria; Yin, Jun Chemistry of Materials, Vol. 29, Issue 18 https://doi.org/10.1021/acs.chemmater.7b01226	journal	September 2017
On the Efficiency Limit of Conjugated Polymer:Fullerene-Based Bulk Heterojunction Solar Cells Scharber, Markus C. Advanced Materials, Vol. 28, Issue 10 https://doi.org/10.1002/adma.201504914	journal	January 2016
Highly crystalline low-bandgap polymer nanowires towards high-performance thick-film organic solar cells exceeding 10% power conversion efficiency Lee, Jaewon; Sin, Dong Hun; Moon, Byungho Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/C6EE02466A	journal	January 2017
Linear Side Chains in Benzo[1,2- b :4,5- b ′]dithiophene–Thieno[3,4- c ]pyrrole-4,6-dione Polymers Direct Self-Assembly and Solar Cell Performance Cabanetos, Clément; El Labban, Abdulrahman; Bartelt, Jonathan A. Journal of the American Chemical Society, Vol. 135, Issue 12 https://doi.org/10.1021/ja400365b	journal	March 2013
Solution-Processed Organic Solar Cells Based on Dialkylthiol-Substituted Benzodithiophene Unit with Efficiency near 10% Kan, Bin; Zhang, Qian; Li, Miaomiao Journal of the American Chemical Society, Vol. 136, Issue 44 https://doi.org/10.1021/ja509703k	journal	October 2014
A Series of Simple Oligomer-like Small Molecules Based on Oligothiophenes for Solution-Processed Solar Cells with High Efficiency Kan, Bin; Li, Miaomiao; Zhang, Qian Journal of the American Chemical Society, Vol. 137, Issue 11 https://doi.org/10.1021/jacs.5b00305	journal	March 2015
Polymer Main-Chain Substitution Effects on the Efficiency of Nonfullerene BHJ Solar Cells Firdaus, Yuliar; Maffei, Luna Pratali; Cruciani, Federico Advanced Energy Materials, Vol. 7, Issue 21 https://doi.org/10.1002/aenm.201700834	journal	July 2017
Efficient ternary bulk heterojunction solar cells based on small molecules only Huang, Tzu-Yen; Patra, Dhananjaya; Hsiao, Yu-Sheng Journal of Materials Chemistry A, Vol. 3, Issue 19 https://doi.org/10.1039/C5TA00592B	journal	January 2015
New Wide Band Gap Donor for Efficient Fullerene-Free All-Small-Molecule Organic Solar Cells Yang, Liyan; Zhang, Shaoqing; He, Chang Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b11612	journal	January 2017
Donor and Acceptor Unit Sequences Influence Material Performance in Benzo[1,2- b :4,5- b ′]dithiophene-6,7-Difluoroquinoxaline Small Molecule Donors for BHJ Solar Cells Wang, Kai; Liang, Ru-Ze; Wolf, Jannic Advanced Functional Materials, Vol. 26, Issue 39 https://doi.org/10.1002/adfm.201602162	journal	August 2016
9.73% Efficiency Nonfullerene All Organic Small Molecule Solar Cells with Absorption-Complementary Donor and Acceptor Bin, Haijun; Yang, Yankang; Zhang, Zhi-Guo Journal of the American Chemical Society, Vol. 139, Issue 14 https://doi.org/10.1021/jacs.6b12826	journal	March 2017
Synergistic Effects of Morphological Control and Complementary Absorption in Efficient All-Small-Molecule Ternary-Blend Solar Cells Farahat, Mahmoud E.; Patra, Dhananjaya; Lee, Chih-Hao ACS Applied Materials & Interfaces, Vol. 7, Issue 40 https://doi.org/10.1021/acsami.5b06831	journal	September 2015
Panchromatic Sequentially Cast Ternary Polymer Solar Cells L., Yan,; A., Gadisa,; Q., Zhang, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/z3fr-3x75	text	January 2017

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