Scalable Polymer Nanocomposites with Record High‐Temperature Capacitive Performance Enabled by Rationally Designed Nanostructured Inorganic Fillers

Li, He; Ai, Ding; Ren, Lulu; Yao, Bin; Han, Zhubing; Shen, Zhonghui; Wang, Jianjun; Chen, Long‐Qing; Wang, Qing

doi:10.1002/adma.201900875

Title: Scalable Polymer Nanocomposites with Record High‐Temperature Capacitive Performance Enabled by Rationally Designed Nanostructured Inorganic Fillers

Journal Article · Fri Apr 12 00:00:00 EDT 2019 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201900875· OSTI ID:1506729

Li, He ^[1]; Ai, Ding ^[1]; Ren, Lulu ^[1]; Yao, Bin ^[1]; Han, Zhubing ^[1]; Shen, Zhonghui ^[1]; Wang, Jianjun ^[1]; Chen, Long‐Qing ^[1];

^[1]

Department of Materials Science and Engineering The Pennsylvania State University University Park PA 16802 USA

Abstract Next‐generation microelectronics and electrical power systems call for high‐energy‐density dielectric polymeric materials that can operate efficiently under elevated temperatures. However, the currently available polymer dielectrics are limited to relatively low working temperatures. Here, the solution‐processable polymer nanocomposites consisting of readily prepared Al ₂ O ₃ fillers with systematically varied morphologies including nanoparticles, nanowires, and nanoplates are reported. The field‐dependent electrical conduction of the polymer nanocomposites at elevated temperatures is investigated. A strong dependence of the conduction behavior and breakdown strength of the polymer composites on the filler morphology is revealed experimentally and is further rationalized via computations. The polymer composites containing Al ₂ O ₃ nanoplates display a record capacitive performance, e.g., a discharged energy density of 3.31 J cm ⁻³ and a charge–discharge efficiency of >90% measured at 450 MV m ⁻¹ and 150 °C, significantly outperforming the state‐of‐the‐art dielectric polymers and nanocomposites that are typically prepared via tedious, low‐yield approaches.

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Sponsoring Organization:: USDOE

OSTI ID:: 1506729

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Vol. 31 Journal Issue: 23; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 206 works

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