skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Dual-nitrogen-source engineered Fe–N x moieties as a booster for oxygen electroreduction

Abstract

The improved ORR performance is attributed to the rich density of the Fe–N x moieties derived from regulated coordination structures using dual-nitrogen-sources.

Authors:
 [1];  [1]; ORCiD logo [1];  [2];  [3];  [1];  [4];  [1];  [1];  [1];  [1]
  1. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, China
  2. Department of Chemistry, Virginia Tech, Blacksburg, USA
  3. ZhuHai Coslight Battery Co., Ltd., ZhuHai, China
  4. St. Petersburg State University, St. Petersburg, Russian Federation
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1506716
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 18; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Wang, Dan, Xiao, Lihui, Yang, Peixia, Xu, Zhengrui, Lu, Xiangyu, Du, Lei, Levin, Oleg, Ge, Liping, Pan, Xiaona, Zhang, Jinqiu, and An, Maozhong. Dual-nitrogen-source engineered Fe–N x moieties as a booster for oxygen electroreduction. United Kingdom: N. p., 2019. Web. doi:10.1039/C9TA01953G.
Wang, Dan, Xiao, Lihui, Yang, Peixia, Xu, Zhengrui, Lu, Xiangyu, Du, Lei, Levin, Oleg, Ge, Liping, Pan, Xiaona, Zhang, Jinqiu, & An, Maozhong. Dual-nitrogen-source engineered Fe–N x moieties as a booster for oxygen electroreduction. United Kingdom. doi:10.1039/C9TA01953G.
Wang, Dan, Xiao, Lihui, Yang, Peixia, Xu, Zhengrui, Lu, Xiangyu, Du, Lei, Levin, Oleg, Ge, Liping, Pan, Xiaona, Zhang, Jinqiu, and An, Maozhong. Tue . "Dual-nitrogen-source engineered Fe–N x moieties as a booster for oxygen electroreduction". United Kingdom. doi:10.1039/C9TA01953G.
@article{osti_1506716,
title = {Dual-nitrogen-source engineered Fe–N x moieties as a booster for oxygen electroreduction},
author = {Wang, Dan and Xiao, Lihui and Yang, Peixia and Xu, Zhengrui and Lu, Xiangyu and Du, Lei and Levin, Oleg and Ge, Liping and Pan, Xiaona and Zhang, Jinqiu and An, Maozhong},
abstractNote = {The improved ORR performance is attributed to the rich density of the Fe–N x moieties derived from regulated coordination structures using dual-nitrogen-sources.},
doi = {10.1039/C9TA01953G},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 18,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1039/C9TA01953G

Citation Metrics:
Cited by: 5 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Metal-Air Batteries with High Energy Density: Li-Air versus Zn-Air
journal, December 2010

  • Lee, Jang-Soo; Tai Kim, Sun; Cao, Ruiguo
  • Advanced Energy Materials, Vol. 1, Issue 1, p. 34-50
  • DOI: 10.1002/aenm.201000010

Atomically FeN2 moieties dispersed on mesoporous carbon: A new atomic catalyst for efficient oxygen reduction catalysis
journal, May 2017


Electrocatalytic valorisation of biomass derived chemicals
journal, January 2018

  • Du, Lei; Shao, Yuyan; Sun, Junming
  • Catalysis Science & Technology, Vol. 8, Issue 13
  • DOI: 10.1039/C8CY00533H

Uniform Multilayer Graphene-Coated Iron and Iron-Carbide as Oxygen Reduction Catalyst
journal, February 2018


Highly efficient and sustainable non-precious-metal Fe–N–C electrocatalysts for the oxygen reduction reaction
journal, January 2018

  • Sun, Meng; Davenport, Douglas; Liu, Huijuan
  • Journal of Materials Chemistry A, Vol. 6, Issue 6
  • DOI: 10.1039/C7TA09187G

Metal–Organic Coordination Networks: Prussian Blue and Its Synergy with Pt Nanoparticles to Enhance Oxygen Reduction Kinetics
journal, June 2016

  • Du, Lei; Du, Chunyu; Chen, Guangyu
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 24
  • DOI: 10.1021/acsami.6b02630

Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017

  • Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
  • Angewandte Chemie International Edition, Vol. 56, Issue 24
  • DOI: 10.1002/anie.201702473

Ancient Chemistry “Pharaoh’s Snakes” for Efficient Fe-/N-Doped Carbon Electrocatalysts
journal, March 2018

  • Ren, Guangyuan; Gao, Liangliang; Teng, Chao
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 13
  • DOI: 10.1021/acsami.7b16936

Mesoporous Metal–Nitrogen-Doped Carbon Electrocatalysts for Highly Efficient Oxygen Reduction Reaction
journal, October 2013

  • Liang, Hai-Wei; Wei, Wei; Wu, Zhong-Shuai
  • Journal of the American Chemical Society, Vol. 135, Issue 43
  • DOI: 10.1021/ja407552k

Active Sites Engineering toward Superior Carbon-Based Oxygen Reduction Catalysts via Confinement Pyrolysis
journal, April 2018


Polyelectrolyte Assisted Synthesis and Enhanced Oxygen Reduction Activity of Pt Nanocrystals with Controllable Shape and Size
journal, July 2014

  • Du, Lei; Zhang, Sheng; Chen, Guangyu
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 16
  • DOI: 10.1021/am503372f

Fe Isolated Single Atoms on S, N Codoped Carbon by Copolymer Pyrolysis Strategy for Highly Efficient Oxygen Reduction Reaction
journal, May 2018


High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
journal, April 2011


Electrocatalyst approaches and challenges for automotive fuel cells
journal, June 2012


Reversible Self-Assembly of Terpyridine-Functionalized Graphene Oxide for Energy Conversion
journal, December 2013

  • Song, Shungang; Xue, Yuhua; Feng, Lianfang
  • Angewandte Chemie International Edition, Vol. 53, Issue 5
  • DOI: 10.1002/anie.201309641

A Metal-Amino Acid Complex-Derived Bifunctional Oxygen Electrocatalyst for Rechargeable Zinc-Air Batteries
journal, August 2016


Hollow Spheres of Iron Carbide Nanoparticles Encased in Graphitic Layers as Oxygen Reduction Catalysts
journal, February 2014

  • Hu, Yang; Jensen, Jens Oluf; Zhang, Wei
  • Angewandte Chemie International Edition, Vol. 53, Issue 14
  • DOI: 10.1002/anie.201400358

FePt Nanoparticles Assembled on Graphene as Enhanced Catalyst for Oxygen Reduction Reaction
journal, January 2012

  • Guo, Shaojun; Sun, Shouheng
  • Journal of the American Chemical Society, Vol. 134, Issue 5
  • DOI: 10.1021/ja2104334

Ionically dispersed Fe( ii )–N and Zn( ii )–N in porous carbon for acidic oxygen reduction reactions
journal, January 2017

  • Liang, Sihui; Chen, Renjie; Yu, Peiwen
  • Chem. Commun., Vol. 53, Issue 83
  • DOI: 10.1039/C7CC06555H

Synthesis–structure–performance correlation for polyaniline–Me–C non-precious metal cathode catalysts for oxygen reduction in fuel cells
journal, January 2011

  • Wu, Gang; Johnston, Christina M.; Mack, Nathan H.
  • Journal of Materials Chemistry, Vol. 21, Issue 30
  • DOI: 10.1039/c0jm03613g

Iron-Nitrogen-Doped Vertically Aligned Carbon Nanotube Electrocatalyst for the Oxygen Reduction Reaction
journal, December 2015

  • Yasuda, Satoshi; Furuya, Atom; Uchibori, Yosuke
  • Advanced Functional Materials, Vol. 26, Issue 5
  • DOI: 10.1002/adfm.201503613

Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes
journal, January 2014

  • Wang, Zhong-Li; Xu, Dan; Xu, Ji-Jing
  • Chem. Soc. Rev., Vol. 43, Issue 22
  • DOI: 10.1039/C3CS60248F

Fe–N-Doped Mesoporous Carbon with Dual Active Sites Loaded on Reduced Graphene Oxides for Efficient Oxygen Reduction Catalysts
journal, January 2018

  • Zhang, Chao; Liu, Jun; Ye, Yixing
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 3
  • DOI: 10.1021/acsami.7b14443

An oxygen reduction electrocatalyst based on carbon nanotube–graphene complexes
journal, May 2012

  • Li, Yanguang; Zhou, Wu; Wang, Hailiang
  • Nature Nanotechnology, Vol. 7, Issue 6
  • DOI: 10.1038/nnano.2012.72

From 3D ZIF Nanocrystals to Co-N x /C Nanorod Array Electrocatalysts for ORR, OER, and Zn-Air Batteries
journal, November 2017

  • Amiinu, Ibrahim Saana; Liu, Xiaobo; Pu, Zonghua
  • Advanced Functional Materials, Vol. 28, Issue 5
  • DOI: 10.1002/adfm.201704638

Single-Site Active Iron-Based Bifunctional Oxygen Catalyst for a Compressible and Rechargeable Zinc–Air Battery
journal, January 2018


Highly doped and exposed Cu( i )–N active sites within graphene towards efficient oxygen reduction for zinc–air batteries
journal, January 2016

  • Wu, Haihua; Li, Haobo; Zhao, Xinfei
  • Energy & Environmental Science, Vol. 9, Issue 12
  • DOI: 10.1039/C6EE01867J

A Polymer Encapsulation Strategy to Synthesize Porous Nitrogen-Doped Carbon-Nanosphere-Supported Metal Isolated-Single-Atomic-Site Catalysts
journal, March 2018

  • Han, Aijuan; Chen, Wenxing; Zhang, Shaolong
  • Advanced Materials, Vol. 30, Issue 15
  • DOI: 10.1002/adma.201706508

Synthesis of nanoporous structured iron carbide/Fe–N–carbon composites for efficient oxygen reduction reaction in Zn–air batteries
journal, January 2016

  • Yang, Zheng Kun; Zhao, Zhi-Wei; Liang, Kuang
  • Journal of Materials Chemistry A, Vol. 4, Issue 48
  • DOI: 10.1039/C6TA08050B

Highly active and stable single iron site confined in graphene nanosheets for oxygen reduction reaction
journal, February 2017


Fe-N/C catalysts for oxygen reduction reaction supported on different carbonaceous materials. Performance in acidic and alkaline direct alcohol fuel cells
journal, May 2017


Atomic interpretation of high activity on transition metal and nitrogen-doped carbon nanofibers for catalyzing oxygen reduction
journal, January 2017

  • Yan, Xingxu; Liu, Kexi; Wang, Tuo
  • Journal of Materials Chemistry A, Vol. 5, Issue 7
  • DOI: 10.1039/C6TA09462G

Noble-Metal-Free Fe–N/C Catalyst for Highly Efficient Oxygen Reduction Reaction under Both Alkaline and Acidic Conditions
journal, July 2014

  • Lin, Ling; Zhu, Qing; Xu, An-Wu
  • Journal of the American Chemical Society, Vol. 136, Issue 31
  • DOI: 10.1021/ja504696r

Advanced catalyst supports for PEM fuel cell cathodes
journal, November 2016


Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011

  • Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1427

Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
journal, January 2018

  • Wang, Xiao Xia; Cullen, David A.; Pan, Yung-Tin
  • Advanced Materials, Vol. 30, Issue 11
  • DOI: 10.1002/adma.201706758

Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells
journal, April 2009

  • Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric
  • Science, Vol. 324, Issue 5923, p. 71-74
  • DOI: 10.1126/science.1170051

Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
journal, August 2017


Combining theory and experiment in electrocatalysis: Insights into materials design
journal, January 2017


Stable N-doped & FeNi-decorated graphene non-precious electrocatalyst for Oxygen Reduction Reaction in Acid Medium
journal, February 2018

  • Barakat, Nasser A. M.; El-Deen, Ahmed G.; Ghouri, Zafar Khan
  • Scientific Reports, Vol. 8, Issue 1
  • DOI: 10.1038/s41598-018-22114-1

Graphene-Based Non-Noble-Metal Catalysts for Oxygen Reduction Reaction in Acid
journal, August 2011

  • Byon, Hye Ryung; Suntivich, Jin; Shao-Horn, Yang
  • Chemistry of Materials, Vol. 23, Issue 15, p. 3421-3428
  • DOI: 10.1021/cm2000649

General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities
journal, January 2018