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Title: Heat transfer from glass melt to cold cap: Melting rate correlation equation

Journal Article · · International Journal of Applied Glass Science
DOI:https://doi.org/10.1111/ijag.12666· OSTI ID:1506686
 [1]; ORCiD logo [2];  [1];  [3]
  1. Pacific Northwest National Laboratory, Richland, Washington
  2. Laboratory of Inorganic Materials, Joint Workplace of the University of Chemistry and Technology Prague, and the Institute of Rock Structure and Mechanics of the ASCR, Prague Czechia
  3. U.S. Department of Energy, Office of River Protection, Richland WA 99352.

Increasing the efficiency of all-electric melters is a hot topic not only in the waste glass melting industry, where the melting rate directly influences the life cycle of the cleanup process, but also in the commercial glass industry, where increasingly stringent environmental regulations and rapid development of renewable energy sources ask for transformation of traditional fossil fuel technology. Batch-to-glass conversion in an all-electric melter proceeds in the cold cap—a layer of reacting and melting material floating on molten glass. The heat transfer into the cold cap is controlled by convection and conduction in the thermal boundary layer on the melt side, and by the properties of the foam layer at the cold cap/melt boundary. An overview of factors affecting heat transfer is presented and assessed using data from laboratory and pilot-scale experiments. The heat flux can be improved by (i) decreasing glass melt viscosity, (ii) decreasing the temperature at which the foam starts to collapse at the cold cap bottom, and (iii) increasing melt convection by bubbling gas into the glass melt under the cold cap. Detailed understanding of the conversion process can guide the formulation of feeds that melt easily and quickly.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1506686
Report Number(s):
PNNL-SA-130430
Journal Information:
International Journal of Applied Glass Science, Vol. 10, Issue 2; ISSN 2041-1286
Publisher:
American Ceramic Society
Country of Publication:
United States
Language:
English

References (11)

Effect of melter feed foaming on heat flux to the cold cap journal December 2017
Effects of heating rate, quartz particle size, viscosity, and form of glass additives on high‐level waste melter feed volume expansion journal October 2016
Mathematical modeling of cold cap journal October 2012
Model for the conversion of nuclear waste melter feed to glass journal February 2014
Control of Radioactive Waste Glass Melters: II, Residence Time and Melt Rate Limitations journal October 1990
Nuclear waste vitrification efficiency: Cold cap reactions journal December 2012
The effects of melting reactions on laboratory-scale waste vitrification journal August 1995
Advances in JHCM HLW Vitrification Technology at VSL through Scaled Melter Testing book January 2013
Glass Science in the United States: Current Status and Future Directions journal January 2014
Effect of furnace atmosphere on E-glass foaming journal December 2006
Conversion of batch to molten glass, I: Volume expansion journal February 2011

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