Design Rules for Metal‐Organic Framework Stability in High‐Pressure Hydrogen Environments

Wang, Timothy C.; White, James L.; Bie, Binglin; Deng, Hexiang; Edgington, Jane; Sugar, Joshua D.; Stavila, Vitalie; Allendorf, Mark D.

doi:10.1002/cphc.201801190

Title: Design Rules for Metal‐Organic Framework Stability in High‐Pressure Hydrogen Environments

Journal Article · Mon Apr 08 00:00:00 EDT 2019 · ChemPhysChem

DOI:https://doi.org/10.1002/cphc.201801190· OSTI ID:1505653

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^[1]; Bie, Binglin ^[2]; Deng, Hexiang ^[2]; Edgington, Jane ^[1]; Sugar, Joshua D. ^[1];

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Chemistry, Combustion, and Materials Center Sandia National Laboratories Livermore, California 94551 United States
College of Chemistry and Molecular Sciences Wuhan University Wuhan 430072 China

Abstract Stability of metal‐organic frameworks (MOFs) under hydrogen is of particular importance for a diverse range of applications, including catalysis, gas separations, and hydrogen storage. Hydrogen in gaseous form is known to be a strong reducing agent and can potentially react with the secondary building units of a MOF and decompose the porous framework structure. Moreover, rapid pressure swings expected in vehicular hydrogen storage could create significant mechanical stresses within MOF crystals that cause partial or complete pore collapse. In this work, we examined the stability of a structurally representative suite of MOFs by testing them under both static (70 MPa) and dynamic hydrogen exposure (0.5 to 10 MPa, 1000 pressure cycles) at room temperature. We aim to provide stability information for development of near room‐temperature hydrogen storage media based on MOFs and suggest framework design rules to avoid materials unstable for hydrogen storage under relevant technical conditions.

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Sponsoring Organization:: USDOE

OSTI ID:: 1505653

Journal Information:: ChemPhysChem, Journal Name: ChemPhysChem Vol. 20 Journal Issue: 10; ISSN 1439-4235

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 7 works

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