skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Evidence of molybdenum association with particulate organic matter under sulfidic conditions

 [1];  [2];  [1];  [3];  [3];  [1]
  1. Nordic Center for Earth Evolution and University of Southern Denmark, Odense M Denmark
  2. Department of Earth and Atmospheric Sciences, Central Michigan University, Mount Pleasant MI USA
  3. Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Odense M Denmark
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
OSTI Identifier:
Resource Type:
Journal Article
Journal Name:
Additional Journal Information:
Journal Volume: 15; Journal Issue: 2; Journal ID: ISSN 1472-4677
Country of Publication:
United States

Citation Formats

Dahl, T. W., Chappaz, A., Hoek, J., McKenzie, C. J., Svane, S., and Canfield, D. E. Evidence of molybdenum association with particulate organic matter under sulfidic conditions. United States: N. p., 2016. Web. doi:10.1111/gbi.12220.
Dahl, T. W., Chappaz, A., Hoek, J., McKenzie, C. J., Svane, S., & Canfield, D. E. Evidence of molybdenum association with particulate organic matter under sulfidic conditions. United States. doi:10.1111/gbi.12220.
Dahl, T. W., Chappaz, A., Hoek, J., McKenzie, C. J., Svane, S., and Canfield, D. E. Tue . "Evidence of molybdenum association with particulate organic matter under sulfidic conditions". United States. doi:10.1111/gbi.12220.
title = {Evidence of molybdenum association with particulate organic matter under sulfidic conditions},
author = {Dahl, T. W. and Chappaz, A. and Hoek, J. and McKenzie, C. J. and Svane, S. and Canfield, D. E.},
abstractNote = {},
doi = {10.1111/gbi.12220},
journal = {Geobiology},
issn = {1472-4677},
number = 2,
volume = 15,
place = {United States},
year = {2016},
month = {12}

Works referenced in this record:

Mechanism of molybdenum removal from the sea and its concentration in black shales: EXAFS evidence
journal, October 1996

Rhenium and molybdenum enrichments in sediments as indicators of oxic, suboxic and sulfidic conditions of deposition
journal, December 1996

Environmental analysis of paleoceanographic systems based on molybdenum–uranium covariation
journal, November 2009

Spectrophotometric Determination Of Hydrogen Sulfide In Natural Waters
journal, May 1969

The deposition of molybdenum in anoxic waters
journal, September 1972

Reduction of Cr, Mo, Se and U by Desulfovibrio desulfuricans immobilized in polyacrylamide gels
journal, January 1998

  • Tucker, M. D.; Barton, L. L.; Thomson, B. M.
  • Journal of Industrial Microbiology and Biotechnology, Vol. 20, Issue 1
  • DOI: 10.1038/sj.jim.2900472

Proterozoic Ocean Chemistry and Evolution: A Bioinorganic Bridge?
journal, August 2002

journal, January 1993

Electrometric investigations of an acid-thiomolybdate system and the formation of polyanions
journal, January 1968

  • Saxena, Rs; Jain, Mc; Mittal, Ml
  • Australian Journal of Chemistry, Vol. 21, Issue 1
  • DOI: 10.1071/CH9680091

The Crystal Structure of Molybdenite
journal, June 1923

  • Dickinson, Roscoe G.; Pauling, Linus
  • Journal of the American Chemical Society, Vol. 45, Issue 6
  • DOI: 10.1021/ja01659a020

A New Class of Sulfido/Oxo(dithiolene)−Molybdenum(IV) Complexes Derived from Sulfido/Oxo-Bis(tetrasulfido)molybdenum(IV) Anions
journal, November 2008

  • Sugimoto, Hideki; Suyama, Koichiro; Sugimoto, Kunihisa
  • Inorganic Chemistry, Vol. 47, Issue 21
  • DOI: 10.1021/ic800832a

Molybdenum reduction in a sulfidic lake: Evidence from X-ray absorption fine-structure spectroscopy and implications for the Mo paleoproxy
journal, February 2013

  • Dahl, Tais W.; Chappaz, Anthony; Fitts, Jeffrey P.
  • Geochimica et Cosmochimica Acta, Vol. 103
  • DOI: 10.1016/j.gca.2012.10.058

Molybdenum geochemistry in a seasonally dysoxic Mo-limited lacustrine ecosystem
journal, August 2013

  • Glass, Jennifer B.; Chappaz, Anthony; Eustis, Brooke
  • Geochimica et Cosmochimica Acta, Vol. 114
  • DOI: 10.1016/j.gca.2013.03.023

Reduction and Immobilization of Molybdenum by Desulfovibrio desulfuricans
journal, January 1997

The behavior of molybdenum and its isotopes across the chemocline and in the sediments of sulfidic Lake Cadagno, Switzerland
journal, January 2010

  • Dahl, Tais W.; Anbar, Ariel D.; Gordon, Gwyneth W.
  • Geochimica et Cosmochimica Acta, Vol. 74, Issue 1
  • DOI: 10.1016/j.gca.2009.09.018

Crystal structure of the first dissimilatory nitrate reductase at 1.9 Å solved by MAD methods
journal, January 1999

Tracing euxinia by molybdenum concentrations in sediments using handheld X-ray fluorescence spectroscopy (HHXRF)
journal, December 2013

Cell biology of molybdenum
journal, July 2006

  • Mendel, Ralf R.; Bittner, Florian
  • Biochimica et Biophysica Acta (BBA) - Molecular Cell Research, Vol. 1763, Issue 7
  • DOI: 10.1016/j.bbamcr.2006.03.013

Adsorption of molybdate and tetrathiomolybdate onto pyrite and goethite: Effect of pH and competitive anions
journal, March 2006

Does pyrite act as an important host for molybdenum in modern and ancient euxinic sediments?
journal, February 2014

  • Chappaz, Anthony; Lyons, Timothy W.; Gregory, Daniel D.
  • Geochimica et Cosmochimica Acta, Vol. 126
  • DOI: 10.1016/j.gca.2013.10.028

Molybdenum Isotope Evidence for Widespread Anoxia in Mid-Proterozoic Oceans
journal, April 2004

Diel variation of molybdenum and iron in marine diazotrophic cyanobacteria
journal, July 2004

  • Tuit, Caroline; Waterbury, John; Ravizza, Gregory
  • Limnology and Oceanography, Vol. 49, Issue 4
  • DOI: 10.4319/lo.2004.49.4.0978

The Mononuclear Molybdenum Enzymes
journal, January 1996

Enhanced trapping of molybdenum by sulfurized marine organic matter of marine origin in Mesozoic limestones and shales
journal, December 2004

Molybdenum(VI) speciation in sulfidic waters:
journal, April 2000

Structure of the Molybdenum Site of Dimethyl Sulfoxide Reductase
journal, February 1999

  • George, Graham N.; Hilton, James; Temple, Carrie
  • Journal of the American Chemical Society, Vol. 121, Issue 6
  • DOI: 10.1021/ja982843k

Interaction of Sulfate-Reducing Bacteria with Molybdenum Dissolved from Sputter-Deposited Molybdenum Thin Films and Pure Molybdenum Powder
journal, August 1998

  • Chen, G.; Ford, T. E.; Clayton, C. R.
  • Journal of Colloid and Interface Science, Vol. 204, Issue 2
  • DOI: 10.1006/jcis.1998.5578

Removal of U and Mo from water by immobilizedDesulfovibrio desulfuricans in column reactors
journal, October 1998

Metallic ion binding by Bacillus subtilis: Implications for the fossilization of microorganisms
journal, January 1988

Effect of thermal maturity on remobilization of molybdenum in black shales
journal, September 2016

Nouvel affinement de la structure cristalline du thiomolybdate d'ammonium
journal, November 1976

  • Lapasset, J.; Chezau, N.; Belougne, P.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 32, Issue 11
  • DOI: 10.1107/S056774087600959X

Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database
journal, August 1985

  • Brown, I. D.; Altermatt, D.
  • Acta Crystallographica Section B Structural Science, Vol. 41, Issue 4
  • DOI: 10.1107/S0108768185002063

The effect of a thiol-containing organic molecule on molybdenum adsorption onto pyrite
journal, February 2016

Tracing the stepwise oxygenation of the Proterozoic ocean
journal, March 2008

Geochemical and anthropogenic enrichments of Mo in sediments from perennially oxic and seasonally anoxic lakes in Eastern Canada
journal, January 2008

  • Chappaz, Anthony; Gobeil, Charles; Tessier, André
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 1
  • DOI: 10.1016/j.gca.2007.10.014

Evidence for a gradual rise of oxygen between 2.6 and 2.5Ga from Mo isotopes and Re-PGE signatures in shales
journal, May 2007

  • Wille, M.; Kramers, J. D.; Nägler, T. F.
  • Geochimica et Cosmochimica Acta, Vol. 71, Issue 10
  • DOI: 10.1016/j.gca.2007.02.019

Tracking Euxinia in the Ancient Ocean: A Multiproxy Perspective and Proterozoic Case Study
journal, May 2009

Suboxic trace metal geochemistry in the Eastern Tropical North Pacific
journal, April 2002

The geochemical evolution of the continental crust
journal, January 1995

  • Taylor, Stuart Ross; McLennan, Scott M.
  • Reviews of Geophysics, Vol. 33, Issue 2
  • DOI: 10.1029/95RG00262

EXAFS studies of amorphous molybdenum and tungsten trisulfides and triselenides
journal, April 1984

  • Cramer, S. P.; Liang, K. S.; Jacobson, A. J.
  • Inorganic Chemistry, Vol. 23, Issue 9
  • DOI: 10.1021/ic00177a010

Molybdenum active centre of DMSO reductase from Rhodobacter capsulatus: crystal structure of the oxidised enzyme at 1.82-Å resolution and the dithionite-reduced enzyme at 2.8-Å resolution
journal, December 1997

  • McAlpine, A. S.; McEwan, A. G.; Shaw, A. L.
  • JBIC Journal of Biological Inorganic Chemistry, Vol. 2, Issue 6
  • DOI: 10.1007/s007750050185

Induced internal redox processes in molybdenum-sulfur chemistry: conversion of tetrathiomolybdate(2-) ion to octathiodimolybdate(2-) ion by organic disulfides
journal, January 1984

  • Pan, Wie Hin; Harmer, Mark A.; Halbert, Thomas R.
  • Journal of the American Chemical Society, Vol. 106, Issue 2
  • DOI: 10.1021/ja00314a054

The automatic searching for chemical bonds in inorganic crystal structures
journal, August 1985

  • Altermatt, D.; Brown, I. D.
  • Acta Crystallographica Section B Structural Science, Vol. 41, Issue 4
  • DOI: 10.1107/S0108768185002051

Devonian rise in atmospheric oxygen correlated to the radiations of terrestrial plants and large predatory fish
journal, September 2010

  • Dahl, T. W.; Hammarlund, E. U.; Anbar, A. D.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 42
  • DOI: 10.1073/pnas.1011287107

Iron availability as a dominant control on the primary composition and diagenetic overprint of organic-matter-rich rocks
journal, April 2015

Capture of molybdenum in pyrite-forming sediments: role of ligand-induced reduction by polysulfides
journal, February 2004

Isolation and characterization of a molybdenum iron-sulfur protein from Desulfovibrioafricanus
journal, February 1979

  • Hatchikian, E. C.; Bruschi, M.; Bonicel, J.
  • Biochemical and Biophysical Research Communications, Vol. 86, Issue 3
  • DOI: 10.1016/0006-291X(79)91773-X

The Molybdenum Site of Sulfite Oxidase:  A Comparison of Wild-Type and the Cysteine 207 to Serine Mutant Using X-ray Absorption Spectroscopy
journal, January 1996

  • George, Graham N.; Garrett, Robert M.; Prince, Roger C.
  • Journal of the American Chemical Society, Vol. 118, Issue 36
  • DOI: 10.1021/ja961218h

The molybdenum site of nitrogenase. Preliminary structural evidence from x-ray absorption spectroscopy
journal, May 1978

  • Cramer, Stephen P.; Hodgson, Keith O.; Gillum, William O.
  • Journal of the American Chemical Society, Vol. 100, Issue 11
  • DOI: 10.1021/ja00479a023

Crystal Structure of the Xanthine Oxidase-Related Aldehyde Oxido-Reductase from D. gigas
journal, November 1995

Plausible structure of the iron-molybdenum cofactor of nitrogenase.
journal, July 1992

  • Madden, M. S.; Krezel, A. M.; Allen, R. M.
  • Proceedings of the National Academy of Sciences, Vol. 89, Issue 14
  • DOI: 10.1073/pnas.89.14.6487

The Cambridge Structural Database: a quarter of a million crystal structures and rising
journal, May 2002

Molybdenum isotope records as a potential new proxy for paleoceanography
journal, June 2003

  • Siebert, Christopher; Nägler, Thomas F.; von Blanckenburg, Friedhelm
  • Earth and Planetary Science Letters, Vol. 211, Issue 1-2
  • DOI: 10.1016/S0012-821X(03)00189-4

Molybdenum behavior during early diagenesis: Insights from Mo isotopes: Mo ISOTOPES AND EARLY DIAGENESIS
journal, June 2009

  • Poulson Brucker, Rebecca L.; McManus, James; Severmann, Silke
  • Geochemistry, Geophysics, Geosystems, Vol. 10, Issue 6
  • DOI: 10.1029/2008GC002180

Stabilities of thiomolybdate complexes of iron; implications for retention of essential trace elements (Fe, Cu, Mo) in sulfidic waters
journal, January 2014

  • Helz, George R.; Erickson, Britt E.; Vorlicek, Trent P.
  • Metallomics, Vol. 6, Issue 6
  • DOI: 10.1039/C3MT00217A

Gene sequence and crystal structure of the aldehyde oxidoreductase from Desulfovibrio desulfuricans ATCC 27774
journal, March 2000

  • Rebelo, Jorge; Macieira, Sofia; Dias, João M.
  • Journal of Molecular Biology, Vol. 297, Issue 1
  • DOI: 10.1006/jmbi.2000.3552

Catalysis by mineral surfaces
journal, November 2002

Molybdate transport and regulation in bacteria
journal, October 1997

  • Grunden, A. M.; Shanmugam, K. T.
  • Archives of Microbiology, Vol. 168, Issue 5
  • DOI: 10.1007/s002030050508

New model for molybdenum behavior in euxinic waters
journal, May 2011

Use of one‐electron theory for the interpretation of near edge structure in K ‐shell x‐ray absorption spectra of transition metal complexes
journal, October 1980

  • Kutzler, Frank W.; Natoli, C. R.; Misemer, D. K.
  • The Journal of Chemical Physics, Vol. 73, Issue 7
  • DOI: 10.1063/1.440523

Reduction of molybdate by sulfate-reducing bacteria
journal, January 2009

Isolation of an iron-molybdenum cofactor from nitrogenase
journal, August 1977

  • Shah, V. K.; Brill, W. J.
  • Proceedings of the National Academy of Sciences, Vol. 74, Issue 8
  • DOI: 10.1073/pnas.74.8.3249

Differential Adsorption of Molybdate and Tetrathiomolybdate on Pyrite (FeS 2 )
journal, January 2003

  • Bostick, Benjamin C.; Fendorf, Scott; Helz, George R.
  • Environmental Science & Technology, Vol. 37, Issue 2
  • DOI: 10.1021/es0257467