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Title: Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd 3Bi 7 and Sm 3Bi 7

Abstract

The binary bismuthides Nd 3Bi 7 and Sm 3Bi 7 were synthesized and structurally characterized for the first time. Here, the results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Univ. of Delaware, Newark, DE (United States)
Publication Date:
Research Org.:
Univ. of Delaware, Newark, DE (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1504902
Alternate Identifier(s):
OSTI ID: 1441062
Grant/Contract Number:  
SC0008885
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 51; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats

Ovchinnikov, Alexander, Makongo, Julien P. A., and Bobev, Svilen. Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7. United States: N. p., 2018. Web. doi:10.1039/c8cc02563k.
Ovchinnikov, Alexander, Makongo, Julien P. A., & Bobev, Svilen. Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7. United States. doi:10.1039/c8cc02563k.
Ovchinnikov, Alexander, Makongo, Julien P. A., and Bobev, Svilen. Mon . "Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7". United States. doi:10.1039/c8cc02563k. https://www.osti.gov/servlets/purl/1504902.
@article{osti_1504902,
title = {Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7},
author = {Ovchinnikov, Alexander and Makongo, Julien P. A. and Bobev, Svilen},
abstractNote = {The binary bismuthides Nd3Bi7 and Sm3Bi7 were synthesized and structurally characterized for the first time. Here, the results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.},
doi = {10.1039/c8cc02563k},
journal = {ChemComm},
issn = {1359-7345},
number = 51,
volume = 54,
place = {United States},
year = {2018},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

Figures / Tables:

Fig. 1 Fig. 1: Crystal structure of RE3Bi7 (RE = Nd, Sm). RE and Bi atoms are shown in orange and purple, respectively. The unit cell is outlined wish dashed lines.

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Works referenced in this record:

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    Works referencing / citing this record:

    Weak Interactions under Pressure: hp -CuBi and Its Analogues
    journal, April 2017

    • Guo, Kai; Akselrud, Lev; Bobnar, Matej
    • Angewandte Chemie International Edition, Vol. 56, Issue 20
    • DOI: 10.1002/anie.201700712

    Crystal Structure and Magnetism of Ternary CompoundsRE6MSb15,RE= La, Ce andM= Mn, Cu, Zn
    journal, March 1996

    • Sologub, O.; Vybornov, M.; Rogl, P.
    • Journal of Solid State Chemistry, Vol. 122, Issue 2
    • DOI: 10.1006/jssc.1996.0112

    Building up Complexity from Strips and Sheets: The Electronic Structure of the La12Mn2Sb30Alloy
    journal, August 1998

    • Papoian, Garegin; Hoffmann, Roald
    • Journal of Solid State Chemistry, Vol. 139, Issue 1
    • DOI: 10.1006/jssc.1998.7773

    Rare-earth bismuthides
    journal, July 1975


    Ternary pnictides MNi2−xPn2 (M ≡ Sr and rare earth metals, Pn ≡ Sb, Bi) with defect CaBe2Ge2 and defect ThCr2Si2 structures
    journal, March 1988


    Anisotropic magnetization and resistivity of single crystalline RNi1−xBi2±y (R=La–Nd, Sm, Gd–Dy)
    journal, March 2013


    Synthesis and crystal structure of EuBi2
    journal, October 2004


    Synthesis and crystal structures of La3MgBi5 and LaLiBi2
    journal, April 2006

    • Pan, Da-Chun; Sun, Zhong-Ming; Mao, Jiang-Gao
    • Journal of Solid State Chemistry, Vol. 179, Issue 4
    • DOI: 10.1016/j.jssc.2005.12.030

    Permanent magnets: Plugging the gap
    journal, September 2012


    The Ternary Alkaline-Earth Metal Manganese Bismuthides Sr 2 MnBi 2 and Ba 2 Mn 1– x Bi 2 ( x ≈ 0.15)
    journal, October 2017


    Structure and properties of the transition-metal zintl compounds: A14MnBi11 (A = Ca, Sr, Ba)
    journal, March 1992

    • Kuromoto, Traci Y.; Kauzlarich, Susan M.; Webb, David J.
    • Chemistry of Materials, Vol. 4, Issue 2
    • DOI: 10.1021/cm00020a036

    Yb 14 MnSb 11 :  New High Efficiency Thermoelectric Material for Power Generation
    journal, April 2006

    • Brown, Shawna R.; Kauzlarich, Susan M.; Gascoin, Franck
    • Chemistry of Materials, Vol. 18, Issue 7
    • DOI: 10.1021/cm060261t

    Lanthanide-Based Luminescent Hybrid Materials
    journal, September 2009


    Structures and Physical Properties of Rare-Earth Zinc Antimonides Pr 6 Zn 1+ x Sb 14+ y and RE 6 Zn 1+ x Sb 14 ( RE = Sm, Gd−Ho)
    journal, December 2008

    • Liu, Yi; Chen, Ling; Li, Long-Hua
    • Inorganic Chemistry, Vol. 47, Issue 24
    • DOI: 10.1021/ic800524d

    Catalytic Properties of Ceria and CeO 2 -Containing Materials
    journal, November 1996


    The single crystal structure determination of Ln6MnSb15 (Ln=La, Ce), Ln6Mn1−xZnxSb15 (x~0.5), and Ln6ZnSb15 (Ln=La–Pr)
    journal, January 2017

    • Benavides, Katherine A.; McCandless, Gregory T.; Chan, Julia Y.
    • Zeitschrift für Kristallographie - Crystalline Materials, Vol. 232, Issue 7-9
    • DOI: 10.1515/zkri-2016-2025

      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.