Synthesis and Characterization of 2 × 4 Tunnel Structured Manganese Dioxides as Cathodes in Rechargeable Li, Na, and Mg Batteries

Poyraz, Altug S.; Quilty, Calvin D.; Housel, Lisa M.; Hu, Xiaobing; Bruck, Andrea M.; Li, Yue Ru; Yin, Jiefu; Zhang, Bingjie; Huang, Jianping; Wu, Lijun; Zhu, Yimei; Takeuchi, Esther S.; Marschilok, Amy C.; Takeuchi, Kenneth J.

doi:10.1149/2.1341902jes

Title: Synthesis and Characterization of 2 × 4 Tunnel Structured Manganese Dioxides as Cathodes in Rechargeable Li, Na, and Mg Batteries

Journal Article · Sat Mar 02 00:00:00 EST 2019 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.1341902jes· OSTI ID:1503510

^[1]; Quilty, Calvin D. ^[2]; Housel, Lisa M. ^[2]; Hu, Xiaobing ^[3]; Bruck, Andrea M. ^[2]; Li, Yue Ru ^[2];

^[2]; Zhang, Bingjie ^[2];

^[2]; Wu, Lijun ^[3]; Zhu, Yimei ^[3];

^[4];

^[5]

Kennesaw State Univ., GA (United States). Dept. of Chemistry and Biochemistry; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy and Photon Sciences Directorate
Stony Brook Univ., NY (United States). Dept. of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Energy and Photon Sciences Directorate
Brookhaven National Lab. (BNL), Upton, NY (United States). Energy and Photon Sciences Directorate; Stony Brook Univ., NY (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering
Stony Brook Univ., NY (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering

Sodium containing 2 × 4 (0.46nm × 0.92nm) tunnel structured manganese dioxide (Na-2 × 4-MnO₂) nanofibers are hydrothermally synthesized here. The nanofibrous Na-2 × 4-MnO₂ was thoroughly characterized using X-ray diffraction (XRD), thermogravimetric analysis (TGA), inductively coupled plasma optical emission spectroscopy (ICP-OES), N2 sorption, and electron microscopy (SEM and TEM) and is assigned a formula of Na_0.25MnO₂.0.16H₂O. The electrochemistry of Na-2 × 4-MnO₂ in non-aqueous Li, Na and Mg batteries is compared for the first time and first cycle delivered capacities were found to be 152mAh/g, 86mAh/g, and 307mAh/g, respectively. Characterization of the active material after electrochemical tests demonstrated that Na-2 × 4-MnO₂ preserved both its crystallographic structure and nanofibrous morphology after cycling in Na and Li cells, however, Na-2 × 4-MnO₂ lost its crystalline structure after cycling in a Mg based system.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; SC0012673; 1109408

OSTI ID:: 1503510

Report Number(s):: BNL-211466-2019-JAAM

Journal Information:: Journal of the Electrochemical Society, Vol. 166, Issue 4; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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