Synchrotron X-ray diffraction study of double perovskites Sr2RNbO6 ( R = Sm, Gd, Dy, Ho, Y, Tm, and Lu)

Wong-Ng, W.; Kaduk, J. A.; Lapidus, S. H.; Ribaud, L.; Diwanji, S. P.

doi:10.1017/S0885715618000593

Title: Synchrotron X-ray diffraction study of double perovskites Sr₂RNbO₆ ( R = Sm, Gd, Dy, Ho, Y, Tm, and Lu)

Journal Article · Thu Oct 18 00:00:00 EDT 2018 · Powder Diffraction

DOI:https://doi.org/10.1017/S0885715618000593· OSTI ID:1503241

Wong-Ng, W. ^[1];

^[2]; Lapidus, S. H. ^[3]; Ribaud, L. ^[3]; Diwanji, S. P. ^[1]

National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
Illinois Inst. of Technology, Chicago, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

A series of double-perovskite oxides, Sr₂RNbO₆(R= Sm, Gd, Dy, Ho, Y, Tm, and Lu) were prepared and their crystal structure and powder diffraction reference patterns were determined using the Rietveld analysis technique. The crystal structure of each of the Sr₂RNbO₆phase is reported in this paper. TheR= Gd, Ho, and Lu samples were studied using synchrotron radiation, whileR= Sm, Dy, Y, and Tm samples were studied using laboratory X-ray diffraction. Members of Sr₂RNbO₆are monoclinic with a space group ofP2₁/nand are isostructural with each other. Following the trend of “lanthanide contraction”, fromR= Sm to Lu, the lattice parameters “a” of these compounds decreases from 5.84672(10) to 5.78100(3) Å,bfrom 5.93192(13) to 5.80977(3) Å,cfrom 8.3142(2) to 8.18957(5) Å, andVdecreases from 288.355(11) to 275.057(2) Å³. In this double-perovskite series, theR³⁺and Nb⁵⁺ions are structurally ordered. The average Nb–O bond length is nearly constant, while the averageR–O bond length decreases with the decreasing ionic radius ofR³⁺. Powder diffraction patterns for these compounds have been submitted to the Powder Diffraction File (PDF).

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1503241

Journal Information:: Powder Diffraction, Vol. 33, Issue 4; ISSN 0885-7156

Publisher:: Cambridge University PressCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 2 works

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Figures / Tables (11)

Table 1(p. 10)

Table 2(p. 11)

Table 3(p. 12)

Table 4 Part 1(p. 14)

Table 4 Part 2(p. 16)

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36 MATERIALS SCIENCE
Sr2RNbO6 (R = Sm, Gd, Dy, Ho, Y, Tm, and Lu)
X-ray diffraction patterns and structures
double perovskites
synchrotron X-ray studies

Title: Synchrotron X-ray diffraction study of double perovskites Sr2RNbO6 ( R = Sm, Gd, Dy, Ho, Y, Tm, and Lu)

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References (28)

Figures / Tables (11)

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Title: Synchrotron X-ray diffraction study of double perovskites Sr₂RNbO₆ ( R = Sm, Gd, Dy, Ho, Y, Tm, and Lu)