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Title: Mn 2CoReO 6: a robust multisublattice antiferromagnetic perovskite with small A-site cations

Abstract

Mn 2CoReO 6, the fourth known magnetic transition-metal-only double perovskite oxide (space group P2 1/n) was synthesized here at high pressure and temperature (8 GPa, 1350 °C). Large structural distortions are induced by the small A-site Mn 2+ cations. Mn 2CoReO 6 exhibits complex magnetic properties with a robust antiferromagnetic order (T N = 94 K) involving all cation sublattices.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3];  [3]; ORCiD logo [4]; ORCiD logo [5];  [6];  [2];  [1]; ORCiD logo [1];  [7];  [5]; ORCiD logo [8]; ORCiD logo [8];  [9];  [9];  [10];  [5];  [11]; ORCiD logo [1]
  1. Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology
  2. Univ. of Kent, Canterbury (United Kingdom). School of Physical Sciences
  3. Science and Technology Facilities Council (STFC), Chilton (United Kingdom). Rutherford Appleton Lab. (RAL). ISIS Facility
  4. George Mason Univ., Fairfax, VA (United States). Dept. of Chemistry and Biochemistry
  5. Univ. of Chinese Academy of Sciences, Beijing (China). Inst. of Physics
  6. Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy
  7. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
  8. Sun Yat-Sen Univ., Guangzhou (China). MOE Key Lab. of Bioinorganic and Synthetic Chemistry. School of Chemistry
  9. Brookhaven National Lab. (BNL), Upton, NY (United States). NSLS-II
  10. National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Materials Measurement Science Division. Material Measurement Lab.
  11. Columbia Univ., Palisades, NY (United States). Lamont Doherty Earth Observatory
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States); Rutgers Univ., Piscataway, NJ (United States); Univ. of Kent, Canterbury (United Kingdom); Univ. of Chinese Academy of Sciences, Beijing (China); Sun Yat-Sen Univ., Guangzhou (China)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF); Leverhulme Trust (United Kingdom); National Natural Science Foundation of China (NNSFC)
OSTI Identifier:
1502801
Alternate Identifier(s):
OSTI ID: 1497244
Report Number(s):
BNL-211429-2019-JAAM
Journal ID: ISSN 1359-7345
Grant/Contract Number:  
SC0012704; DMR-1507252; RPG-2017-362; NSFC-11804404
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 55; Journal Issue: 23; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Frank, Corey E., McCabe, Emma E., Orlandi, Fabio, Manuel, Pascal, Tan, Xiaoyan, Deng, Zheng, Croft, Mark, Cascos, Vanessa, Emge, Thomas, Feng, Hai L., Lapidus, Saul, Jin, Changqing, Wu, MeiXia, Li, Man Rong, Ehrlich, Steven, Khalid, Syed, Quackenbush, Nicholas, Yu, Shuang, Walker, David, and Greenblatt, Martha. Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations. United States: N. p., 2019. Web. doi:10.1039/C9CC00038K.
Frank, Corey E., McCabe, Emma E., Orlandi, Fabio, Manuel, Pascal, Tan, Xiaoyan, Deng, Zheng, Croft, Mark, Cascos, Vanessa, Emge, Thomas, Feng, Hai L., Lapidus, Saul, Jin, Changqing, Wu, MeiXia, Li, Man Rong, Ehrlich, Steven, Khalid, Syed, Quackenbush, Nicholas, Yu, Shuang, Walker, David, & Greenblatt, Martha. Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations. United States. doi:10.1039/C9CC00038K.
Frank, Corey E., McCabe, Emma E., Orlandi, Fabio, Manuel, Pascal, Tan, Xiaoyan, Deng, Zheng, Croft, Mark, Cascos, Vanessa, Emge, Thomas, Feng, Hai L., Lapidus, Saul, Jin, Changqing, Wu, MeiXia, Li, Man Rong, Ehrlich, Steven, Khalid, Syed, Quackenbush, Nicholas, Yu, Shuang, Walker, David, and Greenblatt, Martha. Tue . "Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations". United States. doi:10.1039/C9CC00038K.
@article{osti_1502801,
title = {Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations},
author = {Frank, Corey E. and McCabe, Emma E. and Orlandi, Fabio and Manuel, Pascal and Tan, Xiaoyan and Deng, Zheng and Croft, Mark and Cascos, Vanessa and Emge, Thomas and Feng, Hai L. and Lapidus, Saul and Jin, Changqing and Wu, MeiXia and Li, Man Rong and Ehrlich, Steven and Khalid, Syed and Quackenbush, Nicholas and Yu, Shuang and Walker, David and Greenblatt, Martha},
abstractNote = {Mn2CoReO6, the fourth known magnetic transition-metal-only double perovskite oxide (space group P21/n) was synthesized here at high pressure and temperature (8 GPa, 1350 °C). Large structural distortions are induced by the small A-site Mn2+ cations. Mn2CoReO6 exhibits complex magnetic properties with a robust antiferromagnetic order (TN = 94 K) involving all cation sublattices.},
doi = {10.1039/C9CC00038K},
journal = {ChemComm},
issn = {1359-7345},
number = 23,
volume = 55,
place = {United States},
year = {2019},
month = {2}
}

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Works referenced in this record:

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976