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Title: An Aqueous Dual-Ion Battery Cathode of Mn3O4 via Reversible Insertion of Nitrate

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [2];  [3];  [3];  [1];  [1];  [1];  [1];  [4];  [5];  [6];  [7];  [7]; ORCiD logo [1]
  1. Oregon State Univ., Corvallis, OR (United States). Dept. of Chemistry
  2. Oregon State Univ., Corvallis, OR (United States). Dept. of Chemistry; Jilin Univ., Changchun (China). Key Lab. of Physics and Technology for Advanced Batteries (Ministry of Education)
  3. Chemical Sciences and Engineering Division and X-ray Science Division, Advanced Photon Sources, Argonne National Laboratory, Lemont IL 60439 USA
  4. Univ. of Oregon, Eugene, OR (United States). Center for Advanced Materials Characterization in Oregon (CAMCOR)
  5. Hewlett-Packard Co., Corvallis, OR (United States)
  6. Jilin Univ., Changchun (China). Key Lab. of Physics and Technology for Advanced Batteries (Ministry of Education)
  7. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), Chemical Sciences and Engineering Division, and X-ray Science Division
+ Show Author Affiliations

Abstract We report reversible electrochemical insertion of NO 3 − into manganese(II, III) oxide (Mn 3 O 4 ) as a cathode for aqueous dual‐ion batteries. Characterization by TGA, FTIR, EDX, XANES, EXAFS, and EQCM collectively provides unequivocal evidence that reversible oxidative NO 3 − insertion takes place inside Mn 3 O 4 . Ex situ HRTEM and corresponding EDX mapping results suggest that NO 3 − insertion de‐crystallizes the structure of Mn 3 O 4 . Kinetic studies reveal fast migration of NO 3 − in the Mn 3 O 4 structure. This finding may open a new direction for novel low‐cost aqueous dual‐ion batteries.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1510087
Alternate ID(s):
OSTI ID: 1501946
Journal Information:
Angewandte Chemie (International Edition), Vol. 58, Issue 16; ISSN 1433-7851
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 71 works
Citation information provided by
Web of Science

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Development of Safe and Sustainable Dual‐Ion Batteries Through Hybrid Aqueous/Nonaqueous Electrolytes journal January 2020

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