Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode

Lopez, Michael J.; Sheridan, Matthew V.; McLachlan, Jeffrey R.; Grimes, Travis S.; Dares, Christopher J.

doi:10.1039/C9CC00837C

Title: Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode

Abstract

We present here the electrochemical oxidation of Am( iii ) to Am ^V O ₂ ⁺ and Am ^VI O ₂ ²⁺ in pH 1 nitric acid using a mesoporous tin-doped indium oxide electrode modified with a covalently attached dipyrazinylpyridine ligand.

Authors:

Lopez, Michael J. ^[1];

^[1];

^[2];

^[1]

Department of Chemistry and Biochemistry, Florida International University, Miami, USA
Idaho National Laboratory, Idaho Falls, USA

Publication Date:: Tue Apr 02 00:00:00 EDT 2019

Sponsoring Org.:: USDOE

OSTI Identifier:: 1501721

Grant/Contract Number:: NE0008539

Resource Type:: Journal Article: Publisher's Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Name: ChemComm Journal Volume: 55 Journal Issue: 28; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Lopez, Michael J., Sheridan, Matthew V., McLachlan, Jeffrey R., Grimes, Travis S., and Dares, Christopher J. Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9CC00837C.

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                    Lopez, Michael J., Sheridan, Matthew V., McLachlan, Jeffrey R., Grimes, Travis S., & Dares, Christopher J. Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode.  United Kingdom.  https://doi.org/10.1039/C9CC00837C

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                    Lopez, Michael J., Sheridan, Matthew V., McLachlan, Jeffrey R., Grimes, Travis S., and Dares, Christopher J. 2019.  
        "Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode".  United Kingdom.  https://doi.org/10.1039/C9CC00837C.

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@article{osti_1501721,

  title        = {Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode},

  author       = {Lopez, Michael J. and Sheridan, Matthew V. and McLachlan, Jeffrey R. and Grimes, Travis S. and Dares, Christopher J.},

  abstractNote = {We present here the electrochemical oxidation of Am( iii ) to Am V O 2 + and Am VI O 2 2+ in pH 1 nitric acid using a mesoporous tin-doped indium oxide electrode modified with a covalently attached dipyrazinylpyridine ligand.},

  doi          = {10.1039/C9CC00837C},

  url          = {https://www.osti.gov/biblio/1501721},
  journal      = {ChemComm},

  issn         = {1359-7345},

  number       = 28,

  volume       = 55,

  place        = {United Kingdom},

  year         = {Tue Apr 02 00:00:00 EDT 2019},

  month        = {Tue Apr 02 00:00:00 EDT 2019}

}

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Publisher's Version of Record at https://doi.org/10.1039/C9CC00837C

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Cited by: 16 works

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Works referenced in this record:

Tributylphosphate Extraction Behavior of Bismuthate-Oxidized Americium
journal, August 2008

Mincher, Bruce J.; Martin, Leigh R.; Schmitt, Nicholas C.
Inorganic Chemistry, Vol. 47, Issue 15
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Multi-Scale Modeling of the Gamma Radiolysis of Nitrate Solutions
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Understanding activity trends in electrochemical water oxidation to form hydrogen peroxide
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Shi, Xinjian; Siahrostami, Samira; Li, Guo-Ling
Nature Communications, Vol. 8, Issue 1
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Hydroxyphenyl- and octoxyphenyl-substituted dipyrazinylpyridine complexes of ruthenium(II), iron(II) and nickel(II)
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Dares, Christopher; Manivannan, Tharsini; Potvin, Pierre G.
Inorganica Chimica Acta, Vol. 374, Issue 1
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Synthesis of Phosphonic Acid Derivatized Bipyridine Ligands and Their Ruthenium Complexes
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Norris, Michael R.; Concepcion, Javier J.; Glasson, Christopher R. K.
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Alternatives to HDEHP and DTPA for Simplified TALSPEAK Separations
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Braley, Jenifer C.; Grimes, Travis S.; Nash, Kenneth L.
Industrial & Engineering Chemistry Research, Vol. 51, Issue 2
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Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands
journal, October 2012

Panak, Petra J.; Geist, Andreas
Chemical Reviews, Vol. 113, Issue 2
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Ligands for f-element extraction used in the nuclear fuel cycle
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Leoncini, Andrea; Huskens, Jurriaan; Verboom, Willem
Chemical Society Reviews, Vol. 46, Issue 23
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Electrochemical oxidation of 243Am(III) in nitric acid by a terpyridyl-derivatized electrode
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Dares, C. J.; Lapides, A. M.; Mincher, B. J.
Science, Vol. 350, Issue 6261
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Thermodynamic Study of the Complexation of Trivalent Actinide and Lanthanide Cations by ADPTZ, a Tridentate N-Donor Ligand
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Miguirditchian, Manuel; Guillaneux, Denis; Guillaumont, Dominique
Inorganic Chemistry, Vol. 44, Issue 5
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A NEW VALENCE STATE OF AMERICIUM, AM(VI) ¹
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Asprey, L. B.; Stephanou, S. E.; Penneman, R. A.
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Higher Oxidation States of Americium: Preparation, Characterization and Use for Separations
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Runde, Wolfgang H.; Mincher, Bruce J.
Chemical Reviews, Vol. 111, Issue 9
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Organic and Aqueous Redox Speciation of Cu(III) Periodate Oxidized Transuranium Actinides
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McCann, Kevin; Sinkov, Sergey I.; Lumetta, Gregg J.
Industrial & Engineering Chemistry Research, Vol. 57, Issue 4
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Kinetics of the Autoreduction of Hexavalent Americium in Aqueous Nitric Acid
journal, June 2017

Grimes, Travis S.; Horne, Gregory P.; Dares, Christopher J.
Inorganic Chemistry, Vol. 56, Issue 14
https://doi.org/10.1021/acs.inorgchem.7b00990

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Similar Records

Title: Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode

Abstract

Citation Formats

Tributylphosphate Extraction Behavior of Bismuthate-Oxidized Americium journal, August 2008

Multi-Scale Modeling of the Gamma Radiolysis of Nitrate Solutions journal, November 2016

Understanding activity trends in electrochemical water oxidation to form hydrogen peroxide journal, September 2017

Hydroxyphenyl- and octoxyphenyl-substituted dipyrazinylpyridine complexes of ruthenium(II), iron(II) and nickel(II) journal, August 2011

Synthesis of Phosphonic Acid Derivatized Bipyridine Ligands and Their Ruthenium Complexes journal, October 2013

Alternatives to HDEHP and DTPA for Simplified TALSPEAK Separations journal, June 2011

Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands journal, October 2012

Ligands for f-element extraction used in the nuclear fuel cycle journal, January 2017

Electrochemical oxidation of 243Am(III) in nitric acid by a terpyridyl-derivatized electrode journal, November 2015

Thermodynamic Study of the Complexation of Trivalent Actinide and Lanthanide Cations by ADPTZ, a Tridentate N-Donor Ligand journal, March 2005

A NEW VALENCE STATE OF AMERICIUM, AM(VI) 1 journal, March 1950

Higher Oxidation States of Americium: Preparation, Characterization and Use for Separations journal, September 2011

Organic and Aqueous Redox Speciation of Cu(III) Periodate Oxidized Transuranium Actinides journal, January 2018

Kinetics of the Autoreduction of Hexavalent Americium in Aqueous Nitric Acid journal, June 2017

Tributylphosphate Extraction Behavior of Bismuthate-Oxidized Americium
journal, August 2008

Multi-Scale Modeling of the Gamma Radiolysis of Nitrate Solutions
journal, November 2016

Understanding activity trends in electrochemical water oxidation to form hydrogen peroxide
journal, September 2017

Hydroxyphenyl- and octoxyphenyl-substituted dipyrazinylpyridine complexes of ruthenium(II), iron(II) and nickel(II)
journal, August 2011

Synthesis of Phosphonic Acid Derivatized Bipyridine Ligands and Their Ruthenium Complexes
journal, October 2013

Alternatives to HDEHP and DTPA for Simplified TALSPEAK Separations
journal, June 2011

Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands
journal, October 2012

Ligands for f-element extraction used in the nuclear fuel cycle
journal, January 2017

Electrochemical oxidation of 243Am(III) in nitric acid by a terpyridyl-derivatized electrode
journal, November 2015

Thermodynamic Study of the Complexation of Trivalent Actinide and Lanthanide Cations by ADPTZ, a Tridentate N-Donor Ligand
journal, March 2005

A NEW VALENCE STATE OF AMERICIUM, AM(VI) ¹
journal, March 1950

Higher Oxidation States of Americium: Preparation, Characterization and Use for Separations
journal, September 2011

Organic and Aqueous Redox Speciation of Cu(III) Periodate Oxidized Transuranium Actinides
journal, January 2018

Kinetics of the Autoreduction of Hexavalent Americium in Aqueous Nitric Acid
journal, June 2017