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Title: Acetohydroxamic Acid Complexes with Trivalent f-Block Metal Cations

Abstract

Acetohydroxamic acid has been studied by optical absorbance spectroscopy as a complex forming reagent for the lighter trivalent lanthanides and actinides (Pu(III) and Am(III)) in aqueous solution at 2.0 M (NaClO4) ionic strength. The highest stoichiometry in all the cases studied has been found to be a 1:4 metal-to-ligand ratio; formation of tetrahydroxamato species requires a high excess of the ligand and alkaline pH, Spectrophotometric monitoring confirmed the presence of Pu(III) by electrochemical reduction of Pu(IV) in the course of the pH titration experiment. The formation constants can be used for optimization of processing flowsheets in the advanced PUREX process.

Authors:
;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
15010099
Report Number(s):
PNWD-SA-5946
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Nuclear Science and Technology, 350-362
Country of Publication:
United States
Language:
English
Subject:
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS

Citation Formats

Sinkov, Serguei I., and Choppin, Gregory. Acetohydroxamic Acid Complexes with Trivalent f-Block Metal Cations. United States: N. p., 2003. Web.
Sinkov, Serguei I., & Choppin, Gregory. Acetohydroxamic Acid Complexes with Trivalent f-Block Metal Cations. United States.
Sinkov, Serguei I., and Choppin, Gregory. 2003. "Acetohydroxamic Acid Complexes with Trivalent f-Block Metal Cations". United States. doi:.
@article{osti_15010099,
title = {Acetohydroxamic Acid Complexes with Trivalent f-Block Metal Cations},
author = {Sinkov, Serguei I. and Choppin, Gregory},
abstractNote = {Acetohydroxamic acid has been studied by optical absorbance spectroscopy as a complex forming reagent for the lighter trivalent lanthanides and actinides (Pu(III) and Am(III)) in aqueous solution at 2.0 M (NaClO4) ionic strength. The highest stoichiometry in all the cases studied has been found to be a 1:4 metal-to-ligand ratio; formation of tetrahydroxamato species requires a high excess of the ligand and alkaline pH, Spectrophotometric monitoring confirmed the presence of Pu(III) by electrochemical reduction of Pu(IV) in the course of the pH titration experiment. The formation constants can be used for optimization of processing flowsheets in the advanced PUREX process.},
doi = {},
journal = {Journal of Nuclear Science and Technology, 350-362},
number = ,
volume = ,
place = {United States},
year = 2003,
month =
}
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