Analysis of Hanford-related Organics using Matrix-assisted Laser Desorption Ionization Time-of-flight Mass Spectrometry
Journal Article
·
· Journal of Radioanalytical and Nuclear Chemistry
- BATTELLE (PACIFIC NW LAB)
- ASSOC WESTERN UNIVERSITY
Matrix-assisted laser desorption/ionization coupled with time-of-flight mass spectrometry (MALDI/TOF-MS) was used for the analysis of low-molecular phosphate compounds found in Hanford tank wastes. The mass spectra of these compounds indicate protonated peaks as well as sodium adducts. Analytical methods presently utilized for the analysis of the phosphate-related organics are both time consuming and labor intensive. A promising alternative is MALDI/TOFMS. The MALDI process produces both positive and negative ions directly and very little sample is required. In addition,there is limited sample preparation and minimal hazardous waste production.
- Research Organization:
- Pacific Northwest National Lab., Richland, WA (US)
- Sponsoring Organization:
- US Department of Energy (US)
- DOE Contract Number:
- AC06-76RL01830
- OSTI ID:
- 15001820
- Report Number(s):
- PNNL-SA-37067; TRN: US0400704
- Journal Information:
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 250, Issue 2; Other Information: PBD: 1 Jan 2001
- Country of Publication:
- United States
- Language:
- English
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