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Title: Crystalline nickel, cobalt, and manganese antimonates as electrocatalysts for the chlorine evolution reaction

Abstract

Crystalline transition-metal antimonates (TMAs) such as NiSb 2 O x , CoSb 2 O x , and MnSb 2 O x are moderately active, stable catalysts for the electrochemical oxidation of chloride to chlorine under conditions relevant to the commercial chlor-alkali process.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]
  1. Division of Chemistry and Chemical Engineering, 127-72, California Institute of Technology, Pasadena, USA
  2. Beckman Institute Molecular Materials Research Center, California Institute of Technology, Pasadena, USA
  3. Division of Chemistry and Chemical Engineering, 127-72, California Institute of Technology, Pasadena, USA, Beckman Institute Molecular Materials Research Center
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1500144
Grant/Contract Number:  
SC0004993
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 12 Journal Issue: 4; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Moreno-Hernandez, Ivan A., Brunschwig, Bruce S., and Lewis, Nathan S. Crystalline nickel, cobalt, and manganese antimonates as electrocatalysts for the chlorine evolution reaction. United Kingdom: N. p., 2019. Web. doi:10.1039/C8EE03676D.
Moreno-Hernandez, Ivan A., Brunschwig, Bruce S., & Lewis, Nathan S. Crystalline nickel, cobalt, and manganese antimonates as electrocatalysts for the chlorine evolution reaction. United Kingdom. doi:10.1039/C8EE03676D.
Moreno-Hernandez, Ivan A., Brunschwig, Bruce S., and Lewis, Nathan S. Wed . "Crystalline nickel, cobalt, and manganese antimonates as electrocatalysts for the chlorine evolution reaction". United Kingdom. doi:10.1039/C8EE03676D.
@article{osti_1500144,
title = {Crystalline nickel, cobalt, and manganese antimonates as electrocatalysts for the chlorine evolution reaction},
author = {Moreno-Hernandez, Ivan A. and Brunschwig, Bruce S. and Lewis, Nathan S.},
abstractNote = {Crystalline transition-metal antimonates (TMAs) such as NiSb 2 O x , CoSb 2 O x , and MnSb 2 O x are moderately active, stable catalysts for the electrochemical oxidation of chloride to chlorine under conditions relevant to the commercial chlor-alkali process.},
doi = {10.1039/C8EE03676D},
journal = {Energy & Environmental Science},
issn = {1754-5692},
number = 4,
volume = 12,
place = {United Kingdom},
year = {2019},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on March 12, 2020
Publisher's Accepted Manuscript

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Works referenced in this record:

Electrocatalysis in the anodic evolution of oxygen and chlorine
journal, November 1984


Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni
journal, January 2011

  • Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P.
  • Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730
  • DOI: 10.1016/j.apsusc.2010.10.051