In-situ anomalous small angle x-ray scattering and absorption on an operating rechargeable lithium ion battery cell.

Title: In-situ anomalous small angle x-ray scattering and absorption on an operating rechargeable lithium ion battery cell.

Full Record
Other Related Research

Abstract

No abstract prepared.

Authors:: Braun, A.; Seifert, S.; Thiyagarajan, P.; Cramer, S. P.; Cairns, E. J.; CHM; IPNS

Publication Date:: Tue Jul 01 00:00:00 EDT 2003

Research Org.:: Intense Pulsed Neutron Source, Argonne National Lab., IL (US); LBNL (US); Univ. of California at Davis (US); Univ. of California at Berkeley (US)

Sponsoring Org.:: US Department of Energy (US)

OSTI Identifier:: 15000822

DOE Contract Number:: W-31-109-ENG-38

Resource Type:: Journal Article

Resource Relation:: Journal Name: Electrochem. Commun.; Journal Volume: 3; Journal Issue: 3; Other Information: PBD: [2003]; Related Information: March 2001

Country of Publication:: United States

Language:: English

Subject:: 74 ATOMIC AND MOLECULAR PHYSICS; ABSORPTION; LITHIUM IONS; SCATTERING; INTENSE PULSED NEUTRON SOURCE

Citation Formats


                    Braun, A., Seifert, S., Thiyagarajan, P., Cramer, S. P., Cairns, E. J., CHM, and IPNS. In-situ anomalous small angle x-ray scattering and absorption on an operating rechargeable lithium ion battery cell..  United States: N. p., 2003. 
        Web.

Copy to clipboard


                    Braun, A., Seifert, S., Thiyagarajan, P., Cramer, S. P., Cairns, E. J., CHM, & IPNS. In-situ anomalous small angle x-ray scattering and absorption on an operating rechargeable lithium ion battery cell..  United States.

Copy to clipboard


                    Braun, A., Seifert, S., Thiyagarajan, P., Cramer, S. P., Cairns, E. J., CHM, and IPNS. Tue .  
        "In-situ anomalous small angle x-ray scattering and absorption on an operating rechargeable lithium ion battery cell.".  United States.

Copy to clipboard


                    
@article{osti_15000822,

  title        = {In-situ anomalous small angle x-ray scattering and absorption on an operating rechargeable lithium ion battery cell.},

  author       = {Braun, A. and Seifert, S. and Thiyagarajan, P. and Cramer, S. P. and Cairns, E. J. and CHM and IPNS},

  abstractNote = {No abstract prepared.},

  doi          = {},

  journal      = {Electrochem. Commun.},

  number       = 3,

  volume       = 3,

  place        = {United States},

  year         = {Tue Jul 01 00:00:00 EDT 2003},

  month        = {Tue Jul 01 00:00:00 EDT 2003}

}

Copy to clipboard

Journal Article:

Other availability

Find in Google Scholar

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Similar records in OSTI.GOV collections:

In situ anomalous small angle X-ray scattering and absorption onan operating rechargeable lithium ion battery cell

Journal Article Braun, Artur ; Seifert, Soenke ; Thiyagarajan, Pappannan ; ... - Electrochemistry Communications

No abstract prepared.
DOI: 10.1016/S1388-2481(01)00121-7
Study of the Jahn-Teller distortion in LiNiO{sub 2}, a cathode material in a rechargeable lithium battery, by in situ X-ray absorption fine structure analysis

Journal Article Nakai, Izumi ; Takahashi, Kouta ; Shiraishi, Youhei ; ... - Journal of Solid State Chemistry

Structural changes accompanying the electrochemical Li deintercalation of Li{sub 1{minus}x}NiO{sub 2} and Li{sub 1{minus}x}CoO{sub 2} were studied by the transmission X-ray absorption fine structure (XAFS) technique using an in situ X-ray cell of original design. The results revealed that the Jahn-Teller distortion of the Ni-O octahedra found in LiNiO{sub 2} decreased as the Li ion was removed from the cathode. The observed X-ray absorption near-edge structures (XANES) of Li{sub 1{minus}x}NiO{sub 2} and Li{sub 1{minus}x}CoO{sub 2} as a function of x are consistent with the phase transitions found by powder-diffraction studies. The Ni-O, Co-O, and Ni-Ni interatomic distances decreased almost linearlymore »« less
DOI: 10.1006/jssc.1998.7943
In situ transmission x-ray absorption fine structure analysis of the charge-discharge process in LiMn{sub 2}O{sub 4}, at rechargeable lithium battery material

Journal Article Shiraishi, Youhei ; Nakai, Izumi ; Tsubata, Toshio - Journal of Solid State Chemistry

The in situ XAFS technique has been applied for the first time to reveal variations in the local structures of Mn atoms during the charge-discharge process of LiMn{sub 2}O{sub 4}, Li(Mn{sub 1.93}Li{sub 0.07})O{sub 4}, and Li(Mn{sub 1.85}Li{sub 0.7})O{sub 4} cathode materials of lithium-ion secondary batteries. It has been demonstrated that the valence state of manganese is in a linear correlation with the peak energy of the Mn K-edge XANES spectrum. EXAFS analysis disclosed the {sup 3}+ Mn{sup 4}+ coexistence of Mn and in LiMn{sub 2}O{sub 4}, with two distinct Mn-O bond distances of 1.98 and 1.88{angstrom} for the Mn{sup 3+}.
DOI: 10.1006/jssc.1997.7615
Operando Grazing Incidence Small-Angle X-ray Scattering/X-ray Diffraction of Model Ordered Mesoporous Lithium-Ion Battery Anodes

Journal Article Bhaway, Sarang M. ; Qiang, Zhe ; Xia, Yanfeng ; ... - ACS Nano

Emergent lithium-ion (Li ⁺) batteries commonly rely on nanostructuring of the active electrode materials to decrease the Li ⁺ ion diffusion path length and to accommodate the strains associated with the insertion and de-insertion of Li ⁺, but in many cases these nanostructures evolve during electrochemical charging–discharging. This change in the nanostructure can adversely impact performance, and challenges remain regarding how to control these changes from the perspective of morphological design. In order to address these questions, operando grazing-incidence small-angle X-ray scattering and X-ray diffraction (GISAXS/GIXD) were used to assess the structural evolution of a family of model ordered mesoporousmore »« less
Cited by 4
DOI: 10.1021/acsnano.6b06708

Full Text Available
Operando Grazing Incidence Small-Angle X-ray Scattering/X-ray Diffraction of Model Ordered Mesoporous Lithium-Ion Battery Anodes

Journal Article Bhaway, Sarang M. ; Qiang, Zhe ; Xia, Yanfeng ; ... - ACS Nano

Emergent lithium ion batteries commonly rely on nanostructuring of the active electrode materials to decrease the Li+ ion diffusion path length and to accommodate the strains associated with the insertion and de-insertion of Li+, but in many cases these nanostructures evolve during electrochemical charging-discharging. This change in the nanostructure can adversely impact performance, but challenges remain on how to control these changes from the perspective of morphological design. In order to start to address these questions, in-operando grazing incidence small angle x-ray scattering and x-ray diffraction (GISAXS/GIXD) were used to assess the structural evolution of a family of model orderedmore »« less
Cited by 4
DOI: 10.1021/acsnano.6b06708

Full Text Available

Similar Records