Progress in the Development of Fe-Based PGM-Free Electrocatalysts for the Oxygen Reduction Reaction

Martinez, Ulises; Komini Babu, Siddharth; Holby, Edward F.; Yin, Xi; Zelenay, Piotr

doi:10.1002/adma.201806545

Title: Progress in the Development of Fe-Based PGM-Free Electrocatalysts for the Oxygen Reduction Reaction

Journal Article · Thu Feb 21 00:00:00 EST 2019 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201806545· OSTI ID:1499359

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Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Development of alternative energy sources is crucial to tackle challenges encountered by the growing global energy demand. Hydrogen fuel, a promising way to store energy produced from renewable power sources, can be converted into electrical energy at high efficiency via direct electrochemical conversion in fuel cells, releasing water as the sole byproduct. One important drawback to current fuel-cell technology is the high content of platinum-group-metal (PGM) electrocatalysts required to perform the sluggish oxygen reduction reaction (ORR). Addressing this challenge, remarkable progress has been made in the development of low-cost PGM-free electrocatalysts synthesized from inexpensive, earth-abundant, and easily sourced materials such as iron, nitrogen, and carbon (Fe–N–C). PGM-free Fe–N–C electrocatalysts now exhibit ORR activities approaching that of PGM electrocatalysts but at a fraction of the cost, promising to significantly reduce overall fuel-cell technology costs. Here in this paper, recent developments in PGM-free electrocatalysis, demonstrating increased fuel-cell performance, as well as efforts aimed at understanding the key limiting factor, i.e., the nature of the PGM-free active site, are summarized. Further improvements will be accomplished through the controlled and/or rationally designed synthesis of materials with higher active-site densities, while at the same time establishing methods to mitigate catalyst degradation.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE). Fuel Cell Technologies Program (EE-3F); USDOE

Grant/Contract Number:: 89233218CNA000001

OSTI ID:: 1499359

Alternate ID(s):: OSTI ID: 1495531

Report Number(s):: LA-UR-18-29583

Journal Information:: Advanced Materials, Vol. 31, Issue 31; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 330 works

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Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa Nature Materials, Vol. 14, Issue 9 https://doi.org/10.1038/nmat4367	journal	August 2015
Use of H ₂ S to Probe the Active Sites in FeNC Catalysts for the Oxygen Reduction Reaction (ORR) in Acidic Media Singh, Deepika; Mamtani, Kuldeep; Bruening, Christopher R. ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs500612k	journal	September 2014
First Principles Study of Morphology, Doping Level, and Water Solvation Effects on the Catalytic Mechanism of Nitrogen-Doped Graphene in the Oxygen Reduction Reaction Kwak, Dohyun; Khetan, Abhishek; Noh, Seunghyo ChemCatChem, Vol. 6, Issue 9 https://doi.org/10.1002/cctc.201402248	journal	August 2014
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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