Impacts of lean electrolyte on cycle life for rechargeable Li metal batteries

Nagpure, Shrikant C.; Tanim, Tanvir R.; Dufek, Eric J.; Viswanathan, Vilayanur V.; Crawford, Alasdair J.; Wood, Sean M.; Xiao, Jie; Dickerson, Charles C.; Liaw, Boryann

doi:10.1016/j.jpowsour.2018.10.060

Title: Impacts of lean electrolyte on cycle life for rechargeable Li metal batteries

Journal Article · Tue Oct 23 00:00:00 EDT 2018 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2018.10.060· OSTI ID:1498783

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^[1]; Viswanathan, Vilayanur V. ^[2]; Crawford, Alasdair J. ^[2];

^[1]; Xiao, Jie ^[2];

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Idaho National Lab. (INL), Idaho Falls, ID (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Rechargeable lithium batteries hold the promise of significantly increasing specific energy above the current state-of-the-art for Li-ion batteries. One of the key limitations with the Li metal systems is the overall cycle life. This work describes efforts to better understand the link between cycle life and evaluating advanced battery materials in conditions which more closely align with high energy cell designs. Combining a single particle model to design cells which are feasible for attaining 300 Wh kg-1 with electrochemical evaluation of coin cells with reduced electrolyte volumes found that there is a significant gap when comparing performance for lean electrolyte conditions versus flooded conditions. Reducing the amount of electrolyte from 37 g Ah-1 to 6 g Ah-1, using a well performing electrolyte for Li metal, reduced the cycle life by over a factor of 7 while also changing the overall failure mode. Combined these results suggest that greater attention needs to be used when evaluating electrolytes and materials for high specific energy cells.

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Research Organization:: Idaho National Lab. (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1498783

Alternate ID(s):: OSTI ID: 1636546

Report Number(s):: INL/JOU-17-44244-Rev000

Journal Information:: Journal of Power Sources, Vol. 407, Issue C; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 51 works

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References (31)

Rapidly falling costs of battery packs for electric vehicles Nykvist, Björn; Nilsson, Måns Nature Climate Change, Vol. 5, Issue 4 https://doi.org/10.1038/nclimate2564	journal	March 2015
Ultimate Limits to Intercalation Reactions for Lithium Batteries Whittingham, M. Stanley Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr5003003	journal	October 2014
A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries Manthiram, Arumugam; Song, Bohang; Li, Wangda Energy Storage Materials, Vol. 6 https://doi.org/10.1016/j.ensm.2016.10.007	journal	January 2017
Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries Noh, Hyung-Joo; Youn, Sungjune; Yoon, Chong Seung Journal of Power Sources, Vol. 233 https://doi.org/10.1016/j.jpowsour.2013.01.063	journal	July 2013
Dead lithium: mass transport effects on voltage, capacity, and failure of lithium metal anodes Chen, Kuan-Hung; Wood, Kevin N.; Kazyak, Eric Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA00371D	journal	January 2017
Negating interfacial impedance in garnet-based solid-state Li metal batteries Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin) Nature Materials, Vol. 16, Issue 5 https://doi.org/10.1038/nmat4821	journal	December 2016
Grain boundary modification to suppress lithium penetration through garnet-type solid electrolyte Hongahally Basappa, Rajendra; Ito, Tomoko; Morimura, Takao Journal of Power Sources, Vol. 363 https://doi.org/10.1016/j.jpowsour.2017.07.088	journal	September 2017
Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid Yang, Chunpeng; Fu, Kun; Zhang, Ying Advanced Materials, Vol. 29, Issue 36 https://doi.org/10.1002/adma.201701169	journal	July 2017
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes Xiang, Hongfa; Shi, Pengcheng; Bhattacharya, Priyanka Journal of Power Sources, Vol. 318 https://doi.org/10.1016/j.jpowsour.2016.04.017	journal	June 2016
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.12	journal	March 2017
Predicting Calendar Aging in Lithium Metal Secondary Batteries: The Impacts of Solid Electrolyte Interphase Composition and Stability Wood, Sean M.; Fang, Chengcheng; Dufek, Eric J. Advanced Energy Materials, Vol. 8, Issue 26 https://doi.org/10.1002/aenm.201801427	journal	August 2018
Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D. Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee21892e	journal	January 2012
Aging formula for lithium ion batteries with solid electrolyte interphase layer growth Tanim, Tanvir R.; Rahn, Christopher D. Journal of Power Sources, Vol. 294 https://doi.org/10.1016/j.jpowsour.2015.06.014	journal	October 2015
Microelectrode investigation of ultrahigh-rate lithium deposition and stripping Verbrugge, Mark W.; Koch, Brian J. Journal of Electroanalytical Chemistry, Vol. 367, Issue 1-2 https://doi.org/10.1016/0022-0728(93)03047-S	journal	March 1994
Design optimization of LiNi0.6Co0.2Mn0.2O2/graphite lithium-ion cells based on simulation and experimental data Appiah, Williams Agyei; Park, Joonam; Song, Seonghyun Journal of Power Sources, Vol. 319 https://doi.org/10.1016/j.jpowsour.2016.04.052	journal	July 2016
Mathematical Modeling of the Lithium Deposition Overcharge Reaction in Lithium-Ion Batteries Using Carbon-Based Negative Electrodes Arora, Pankaj Journal of The Electrochemical Society, Vol. 146, Issue 10 https://doi.org/10.1149/1.1392512	journal	January 1999
Optimized Temperature Effect of Li-Ion Diffusion with Layer Distance in Li(Ni _x Mn _y Co _z )O ₂ Cathode Materials for High Performance Li-Ion Battery Cui, Suihan; Wei, Yi; Liu, Tongchao Advanced Energy Materials, Vol. 6, Issue 4 https://doi.org/10.1002/aenm.201501309	journal	December 2015
Transport Properties of LiPF[sub 6]-Based Li-Ion Battery Electrolytes Valo̸en, Lars Ole; Reimers, Jan N. Journal of The Electrochemical Society, Vol. 152, Issue 5 https://doi.org/10.1149/1.1872737	journal	January 2005
Comparison of Modeling Predictions with Experimental Data from Plastic Lithium Ion Cells Doyle, Marc Journal of The Electrochemical Society, Vol. 143, Issue 6 https://doi.org/10.1149/1.1836921	journal	January 1996
Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes Lu, Dongping; Shao, Yuyan; Lozano, Terence Advanced Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1002/aenm.201400993	journal	September 2014
Anode-Free Rechargeable Lithium Metal Batteries Qian, Jiangfeng; Adams, Brian D.; Zheng, Jianming Advanced Functional Materials, Vol. 26, Issue 39 https://doi.org/10.1002/adfm.201602353	journal	August 2016
Dendrite-Free and Performance-Enhanced Lithium Metal Batteries through Optimizing Solvent Compositions and Adding Combinational Additives Li, Xing; Zheng, Jianming; Ren, Xiaodi Advanced Energy Materials, Vol. 8, Issue 15 https://doi.org/10.1002/aenm.201703022	journal	February 2018
Synthesize battery degradation modes via a diagnostic and prognostic model Dubarry, Matthieu; Truchot, Cyril; Liaw, Bor Yann Journal of Power Sources, Vol. 219 https://doi.org/10.1016/j.jpowsour.2012.07.016	journal	December 2012
Evaluation of commercial lithium-ion cells based on composite positive electrode for plug-in hybrid electric vehicle applications. Part I: Initial characterizations Dubarry, Matthieu; Truchot, Cyril; Cugnet, Mikaël Journal of Power Sources, Vol. 196, Issue 23 https://doi.org/10.1016/j.jpowsour.2011.08.077	journal	December 2011
Evaluation of commercial lithium-ion cells based on composite positive electrode for plug-in hybrid electric vehicle applications. Part II. Degradation mechanism under 2C cycle aging Dubarry, Matthieu; Truchot, Cyril; Liaw, Bor Yann Journal of Power Sources, Vol. 196, Issue 23 https://doi.org/10.1016/j.jpowsour.2011.08.078	journal	December 2011
Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode Bieker, Georg; Winter, Martin; Bieker, Peter Physical Chemistry Chemical Physics, Vol. 17, Issue 14 https://doi.org/10.1039/C4CP05865H	journal	January 2015
Dendrites and Pits: Untangling the Complex Behavior of Lithium Metal Anodes through Operando Video Microscopy Wood, Kevin N.; Kazyak, Eric; Chadwick, Alexander F. ACS Central Science, Vol. 2, Issue 11 https://doi.org/10.1021/acscentsci.6b00260	journal	October 2016
Use of phosphoranimines to reduce organic carbonate content in Li-ion battery electrolytes Dufek, Eric J.; Klaehn, John R.; McNally, Joshua S. Electrochimica Acta, Vol. 209 https://doi.org/10.1016/j.electacta.2016.05.038	journal	August 2016
Unsaturated phosphazenes as co-solvents for lithium-ion battery electrolytes Harrup, Mason K.; Rollins, Harry W.; Jamison, David K. Journal of Power Sources, Vol. 278 https://doi.org/10.1016/j.jpowsour.2014.07.109	journal	March 2015
Fluorinated phosphazene co-solvents for improved thermal and safety performance in lithium-ion battery electrolytes Rollins, Harry W.; Harrup, Mason K.; Dufek, Eric J. Journal of Power Sources, Vol. 263 https://doi.org/10.1016/j.jpowsour.2014.04.015	journal	October 2014

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Pathways for practical high-energy long-cycling lithium metal batteries Liu, Jun; Bao, Zhenan; Cui, Yi Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0338-x	journal	February 2019
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25 ENERGY STORAGE
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