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Title: Templating metastable Pd 2 carboxylate aggregates

Abstract

Evaluation of the potential for metal–metal (M–M) cooperation to enable catalysis requires access to specific polynuclear aggregates that display appropriate geometry and size. Here we demonstrate ion metathesis within pre-formed metal–organic frameworks (MOFs) to prepare metastable Pd 2tetracarboxylates sites.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2]; ORCiD logo [1]
  1. Texas A&M University; Department of Chemistry; College Station; USA
  2. DND-CAT; Northwestern Synchrotron Research Centre at the Advanced Photon Source; Argonne; USA
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
DOE - BASIC ENERGY SCIENCESUNIVERSITYOTHER
OSTI Identifier:
1497104
Resource Type:
Journal Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 10; Journal Issue: 6; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, and Powers, David C. Templating metastable Pd2 carboxylate aggregates. United States: N. p., 2019. Web. doi:10.1039/C8SC04940H.
Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, & Powers, David C. Templating metastable Pd2 carboxylate aggregates. United States. doi:10.1039/C8SC04940H.
Wang, Chen-Hao, Gao, Wen-Yang, Ma, Qing, and Powers, David C. Tue . "Templating metastable Pd2 carboxylate aggregates". United States. doi:10.1039/C8SC04940H.
@article{osti_1497104,
title = {Templating metastable Pd2 carboxylate aggregates},
author = {Wang, Chen-Hao and Gao, Wen-Yang and Ma, Qing and Powers, David C.},
abstractNote = {Evaluation of the potential for metal–metal (M–M) cooperation to enable catalysis requires access to specific polynuclear aggregates that display appropriate geometry and size. Here we demonstrate ion metathesis within pre-formed metal–organic frameworks (MOFs) to prepare metastable Pd2tetracarboxylates sites.},
doi = {10.1039/C8SC04940H},
journal = {Chemical Science},
issn = {2041-6520},
number = 6,
volume = 10,
place = {United States},
year = {2019},
month = {1}
}