skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Compositions and methods comprising conductive metal organic frameworks and uses thereof

Abstract

Compositions and methods comprising metal organic frameworks (MOFs) and related uses are generally provided. In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two sets of ortho-diimine groups arranged about an organic core.

Inventors:
; ; ; ;
Publication Date:
Research Org.:
Massachusetts Institute of Technology, Cambridge, MA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1496588
Patent Number(s):
10,174,063
Application Number:
15/309,023
Assignee:
Massachusetts Institute of Technology (Cambridge, MA)
DOE Contract Number:  
SC0006937; SC0001088
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 May 06
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Dinca, Mircea, Sheberla, Dennis, Sun, Lei, Wade, Casey R., and Campbell, Michael Glenn. Compositions and methods comprising conductive metal organic frameworks and uses thereof. United States: N. p., 2019. Web.
Dinca, Mircea, Sheberla, Dennis, Sun, Lei, Wade, Casey R., & Campbell, Michael Glenn. Compositions and methods comprising conductive metal organic frameworks and uses thereof. United States.
Dinca, Mircea, Sheberla, Dennis, Sun, Lei, Wade, Casey R., and Campbell, Michael Glenn. Tue . "Compositions and methods comprising conductive metal organic frameworks and uses thereof". United States. https://www.osti.gov/servlets/purl/1496588.
@article{osti_1496588,
title = {Compositions and methods comprising conductive metal organic frameworks and uses thereof},
author = {Dinca, Mircea and Sheberla, Dennis and Sun, Lei and Wade, Casey R. and Campbell, Michael Glenn},
abstractNote = {Compositions and methods comprising metal organic frameworks (MOFs) and related uses are generally provided. In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two sets of ortho-diimine groups arranged about an organic core.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}

Patent:

Save / Share:

Works referenced in this record:

Metal−Organic Thin-Film Transistor (MOTFT) Based on a Bis( o -diiminobenzosemiquinonate) Nickel(II) Complex
journal, July 2005

  • Noro, Shin-ichiro; Chang, Ho-Chol; Takenobu, Taishi
  • Journal of the American Chemical Society, Vol. 127, Issue 28
  • DOI: 10.1021/ja052663s

High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014

  • Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
  • Journal of the American Chemical Society, Vol. 136, Issue 25
  • DOI: 10.1021/ja502765n

Heterogenization of Metallocene Catalysts for Alkene Polymerization
journal, April 1999


Effect of functional groups in MIL-101 on water sorption behavior
journal, July 2012


Application of absorption heat pumps to multi-effect distillation: a case study of solar desalination
journal, June 2007


Dimerization of ethylene to butene-1 catalyzed by Ti(OR')4-AlR3
journal, November 1993


Post-Metallocenes in the Industrial Production of Polyolefins
journal, August 2014

  • Baier, Moritz C.; Zuideveld, Martin A.; Mecking, Stefan
  • Angewandte Chemie International Edition, Vol. 53, Issue 37
  • DOI: 10.1002/anie.201400799

When the Solvent Locks the Cage: Theoretical Insight into the Transmetalation of MOF-5 Lattices and Its Kinetic Limitations
journal, April 2015


A cubic coordination framework constructed from benzobistriazolate ligands and zinc ions having selective gas sorption properties
journal, January 2009

  • Biswas, Shyam; Grzywa, Maciej; Nayek, Hari Pada
  • Dalton Transactions, Issue 33
  • DOI: 10.1039/b904280f

Homo- and Heteropentanuclear Coordination Compounds with T d Symmetry - the Solid State Structures of [MZn 4 (L) 4 (L′) 6 ] (M = Co II or Zn; L = chloride or acac; L′ = 1,2,3-benzotriazolate)
journal, November 2008

  • Biswas, Shyam; Tonigold, Markus; Volkmer, Dirk
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 634, Issue 14
  • DOI: 10.1002/zaac.200800296

Hydrothermal and microwave synthesis of SAPO (CHA) zeolites on aluminium foams for heat pumping applications
journal, February 2013


Cation exchange at the secondary building units of metal–organic frameworks
journal, January 2014


Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
journal, July 2015


NO Disproportionation at a Mononuclear Site-Isolated Fe 2+ Center in Fe 2+ -MOF-5
journal, June 2015

  • Brozek, Carl K.; Miller, Jeffrey T.; Stoian, Sebastian A.
  • Journal of the American Chemical Society, Vol. 137, Issue 23
  • DOI: 10.1021/jacs.5b03761

Solvent-Dependent Cation Exchange in Metal-Organic Frameworks
journal, April 2014

  • Brozek, Carl K.; Bellarosa, Luca; Soejima, Tomohiro
  • Chemistry - A European Journal, Vol. 20, Issue 23
  • DOI: 10.1002/chem.201402682

Ti 3+ -, V 2+/3+ -, Cr 2+/3+ -, Mn 2+ -, and Fe 2+ -Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5
journal, August 2013

  • Brozek, Carl K.; Dincă, Mircea
  • Journal of the American Chemical Society, Vol. 135, Issue 34
  • DOI: 10.1021/ja4064475

Design of Hydrophilic Metal Organic Framework Water Adsorbents for Heat Reallocation
journal, July 2015

  • Cadiau, Amandine; Lee, Ji Sun; Damasceno Borges, Daiane
  • Advanced Materials, Vol. 27, Issue 32
  • DOI: 10.1002/adma.201502418

Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks
journal, October 2015

  • Campbell, Michael G.; Liu, Sophie F.; Swager, Timothy M.
  • Journal of the American Chemical Society, Vol. 137, Issue 43
  • DOI: 10.1021/jacs.5b09600

MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification
journal, March 2013

  • Canivet, Jerome; Aguado, Sonia; Schuurman, Yves
  • Journal of the American Chemical Society, Vol. 135, Issue 11
  • DOI: 10.1021/ja312120x

Structure–property relationships of water adsorption in metal–organic frameworks
journal, January 2014

  • Canivet, Jérôme; Bonnefoy, Jonathan; Daniel, Cécile
  • New J. Chem., Vol. 38, Issue 7
  • DOI: 10.1039/C4NJ00076E

Water adsorption in MOFs: fundamentals and applications
journal, January 2014

  • Canivet, Jérôme; Fateeva, Alexandra; Guo, Youmin
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00078A

Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008

  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
  • DOI: 10.1021/ja8036096

Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
journal, September 2006


Desolvation of Ions in Subnanometer Pores and Its Effect on Capacitance and Double-Layer Theory
journal, April 2008

  • Chmiola, John; Largeot, Celine; Taberna, Pierre-Louis
  • Angewandte Chemie International Edition, Vol. 47, Issue 18
  • DOI: 10.1002/anie.200704894

Broadly Hysteretic H 2 Adsorption in the Microporous Metal−Organic Framework Co(1,4-benzenedipyrazolate)
journal, June 2008

  • Choi, Hye Jin; Dincă, Mircea; Long, Jeffrey R.
  • Journal of the American Chemical Society, Vol. 130, Issue 25
  • DOI: 10.1021/ja8024092

Hydrogenstorage in water-stable metal–organic frameworks incorporating 1,3- and 1,4-benzenedipyrazolate
journal, January 2010

  • Choi, Hye Jin; Dincă, Mircea; Dailly, Anne
  • Energy Environ. Sci., Vol. 3, Issue 1
  • DOI: 10.1039/B917512A

Supported single-site catalysts for slurry and gas-phase olefin polymerisation
journal, June 2011

  • Choi, Yiyoung; Soares, João B. P.
  • The Canadian Journal of Chemical Engineering, Vol. 90, Issue 3
  • DOI: 10.1002/cjce.20583

A New Multicomponent Reaction Catalyzed by a [Lewis Acid] + [Co(CO) 4 ] - Catalyst:  Stereospecific Synthesis of 1,3-Oxazinane-2,4-diones from Epoxides, Isocyanates, and CO
journal, July 2007

  • Church, Tamara L.; Byrne, Christopher M.; Lobkovsky, Emil B.
  • Journal of the American Chemical Society, Vol. 129, Issue 26
  • DOI: 10.1021/ja069065d

Carbonylation of heterocycles by homogeneous catalysts
journal, January 2007

  • Church, Tamara L.; Getzler, Yutan D. Y. L.; Byrne, Christopher M.
  • Chemical Communications, Issue 7
  • DOI: 10.1039/b613476a

Temperature Effect on Adsorption/Desorption Isotherms for a Simple Fluid Confined within Various Nanopores
journal, July 2005


High thermal and chemical stability in pyrazolate-bridged metal–organic frameworks with exposed metal sites
journal, January 2011

  • Colombo, Valentina; Galli, Simona; Choi, Hye Jin
  • Chemical Science, Vol. 2, Issue 7, p. 1311-1319
  • DOI: 10.1039/c1sc00136a

Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework
journal, August 2016

  • Comito, Robert J.; Fritzsching, Keith J.; Sundell, Benjamin J.
  • Journal of the American Chemical Society, Vol. 138, Issue 32
  • DOI: 10.1021/jacs.6b05200

Engineering Metal Organic Frameworks for Heterogeneous Catalysis
journal, August 2010

  • Corma, A.; García, H.; Llabrés i Xamena, F. X.
  • Chemical Reviews, Vol. 110, Issue 8, p. 4606-4655
  • DOI: 10.1021/cr9003924

Evaluation of alternative refrigerant—adsorbent pairs for refrigeration cycles
journal, November 1996


Adsorption-Driven Heat Pumps: The Potential of Metal–Organic Frameworks
journal, October 2015

  • de Lange, Martijn F.; Verouden, Karlijn J. F. M.; Vlugt, Thijs J. H.
  • Chemical Reviews, Vol. 115, Issue 22
  • DOI: 10.1021/acs.chemrev.5b00059

Metal–Organic Frameworks in Adsorption-Driven Heat Pumps: The Potential of Alcohols as Working Fluids
journal, November 2015


Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes
journal, January 2011

  • Denysenko, Dmytro; Grzywa, Maciej; Tonigold, Markus
  • Chemistry - A European Journal, Vol. 17, Issue 6
  • DOI: 10.1002/chem.201001872

Postsynthetic Metal and Ligand Exchange in MFU-4 l : A Screening Approach toward Functional Metal-Organic Frameworks Comprising Single-Site Active Centers
journal, April 2015

  • Denysenko, Dmytro; Jelic, Jelena; Reuter, Karsten
  • Chemistry - A European Journal, Vol. 21, Issue 22
  • DOI: 10.1002/chem.201406564

Reversible gas-phase redox processes catalyzed by Co-exchanged MFU-4l(arge)
journal, January 2012

  • Denysenko, Dmytro; Werner, Tamas; Grzywa, Maciej
  • Chem. Commun., Vol. 48, Issue 9
  • DOI: 10.1039/C2CC16235K

Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites
journal, May 2014

  • Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena
  • Angewandte Chemie International Edition, Vol. 53, Issue 23
  • DOI: 10.1002/anie.201310004

Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement
journal, January 2014

  • Deria, Pravas; Mondloch, Joseph E.; Karagiaridi, Olga
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00067F

Techno-economic Analysis of Metal–Organic Frameworks for Hydrogen and Natural Gas Storage
journal, January 2017


Living alkene polymerization: New methods for the precision synthesis of polyolefins
journal, January 2007


Exceptional ammonia uptake by a covalent organic framework
journal, February 2010

  • Doonan, Christian J.; Tranchemontagne, David J.; Glover, T. Grant
  • Nature Chemistry, Vol. 2, Issue 3, p. 235-238
  • DOI: 10.1038/nchem.548

Water Adsorption Characteristics of MIL-101 for Heat-Transformation Applications of MOFs
journal, December 2010

  • Ehrenmann, Johannes; Henninger, Stefan K.; Janiak, Christoph
  • European Journal of Inorganic Chemistry, Vol. 2011, Issue 4
  • DOI: 10.1002/ejic.201001156

Metal-Organic Frameworks: Opportunities for Catalysis
journal, September 2009

  • Farrusseng, David; Aguado, Sonia; Pinel, Catherine
  • Angewandte Chemie International Edition, Vol. 48, Issue 41
  • DOI: 10.1002/anie.200806063

�ber Verbindungen des Nickels mito-Phenylendiamin und 1, 3, 4-Toluylendiamin
journal, July 1927

  • Feigl, Fritz; F�rth, Max
  • Monatshefte f�r Chemie, Vol. 48, Issue 7
  • DOI: 10.1007/BF01518062

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
journal, September 2005

  • Ferey, G.; Mellot-Draznieks, C.; Serre, C.
  • Science, Vol. 309, Issue 5743, p. 2040-2042
  • DOI: 10.1126/science.1116275

Nickel-based solid catalysts for ethylene oligomerization – a review
journal, January 2014

  • Finiels, Annie; Fajula, François; Hulea, Vasile
  • Catal. Sci. Technol., Vol. 4, Issue 8
  • DOI: 10.1039/C4CY00305E

Multicycle water vapour stability of microporous breathing MOF aluminium isophthalate CAU-10-H
journal, January 2014

  • Fröhlich, Dominik; Henninger, Stefan Kai; Janiak, Christoph
  • Dalton Trans., Vol. 43, Issue 41
  • DOI: 10.1039/C4DT02264E

Highly active zirconium(IV) catalyst containing sterically hindered hydridotris(pyrazolyl)borate ligand for the polymerization of ethylene
journal, October 2000


Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014

  • Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao
  • Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
  • DOI: 10.1021/ja500330a

Tris(pyrazolyl)methane–chromium(III) complexes as highly active catalysts for ethylene polymerization
journal, December 2006

  • García-Orozco, Ivan; Quijada, Raúl; Vera, Karen
  • Journal of Molecular Catalysis A: Chemical, Vol. 260, Issue 1-2
  • DOI: 10.1016/j.molcata.2006.06.048

Synthesis and characterization of a microporous copper triazolate as a water vapor adsorbent
journal, November 2011


Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields
journal, January 2015

  • Garzón-Tovar, L.; Carné-Sánchez, A.; Carbonell, C.
  • Journal of Materials Chemistry A, Vol. 3, Issue 41
  • DOI: 10.1039/C5TA04923G

Synthesis of β-Lactones:  A Highly Active and Selective Catalyst for Epoxide Carbonylation
journal, February 2002

  • Getzler, Yutan D. Y. L.; Mahadevan, Viswanath; Lobkovsky, Emil B.
  • Journal of the American Chemical Society, Vol. 124, Issue 7, p. 1174-1175
  • DOI: 10.1021/ja017434u

Copolymerization of Ethylene with 1-Hexene Using Sterically Hindered Tris(pyrazolyl)borate Titanium (IV) Compounds
journal, January 2001


Sorption properties for different types of molecular sieve and their influence on optimum dehumidification performance of desiccant wheels
journal, August 2006


Adsorption of NH3 onto activated carbon prepared from palm shells impregnated with H2SO4
journal, January 2005

  • Guo, Jia; Xu, Wang Sheng; Chen, Yan Lin
  • Journal of Colloid and Interface Science, Vol. 281, Issue 2
  • DOI: 10.1016/j.jcis.2004.08.101

Characterisation and improvement of sorption materials with molecular modeling for the use in heat transformation applications
journal, March 2011


MOFs as Adsorbents for Low Temperature Heating and Cooling Applications
journal, March 2009

  • Henninger, Stefan K.; Habib, Hesham A.; Janiak, Christoph
  • Journal of the American Chemical Society, Vol. 131, Issue 8
  • DOI: 10.1021/ja808444z

MOFs for Use in Adsorption Heat Pump Processes
journal, December 2011

  • Henninger, Stefan K.; Jeremias, Felix; Kummer, Harry
  • European Journal of Inorganic Chemistry, Vol. 2012, Issue 16
  • DOI: 10.1002/ejic.201101056

Novel Sorption Materials for Solar Heating and Cooling
journal, January 2012


Water adsorption characteristics of novel materials for heat transformation applications
journal, September 2010


The synthesis and X-ray structure of trans-[CrCl2(nPrNH2)4]BF4·H2O and the thermal and Hg2+-assisted chloride release kinetics from some trans-[CrCl2(N)4]+ complexes
journal, September 1995


Studies of the water adsorption on Zeolites and modified mesoporous materials for seasonal storage of solar heat
journal, January 2004


Adjusting the Stability of Metal–Organic Frameworks under Humid Conditions by Ligand Functionalization
journal, October 2012

  • Jasuja, Himanshu; Huang, You-gui; Walton, Krista S.
  • Langmuir, Vol. 28, Issue 49
  • DOI: 10.1021/la304151r

MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application
journal, January 2012

  • Jeremias, Felix; Khutia, Anupam; Henninger, Stefan K.
  • J. Mater. Chem., Vol. 22, Issue 20
  • DOI: 10.1039/C2JM15615F

Programming MOFs for water sorption: amino-functionalized MIL-125 and UiO-66 for heat transformation and heat storage applications
journal, January 2013

  • Jeremias, Felix; Lozan, Vasile; Henninger, Stefan K.
  • Dalton Transactions, Vol. 42, Issue 45
  • DOI: 10.1039/c3dt51471d

High volumetric uptake of ammonia using Cu-MOF-74/Cu-CPO-27
journal, January 2016

  • Katz, Michael J.; Howarth, Ashlee J.; Moghadam, Peyman Z.
  • Dalton Transactions, Vol. 45, Issue 10
  • DOI: 10.1039/C5DT03436A

Water Sorption Cycle Measurements on Functionalized MIL-101Cr for Heat Transformation Application
journal, February 2013

  • Khutia, Anupam; Rammelberg, Holger Urs; Schmidt, Thomas
  • Chemistry of Materials, Vol. 25, Issue 5
  • DOI: 10.1021/cm304055k

Preparation of Linear α-Olefins Using Cationic Nickel(II) α-Diimine Catalysts
journal, May 1997

  • Killian, Christopher M.; Johnson, Lynda K.; Brookhart, Maurice
  • Organometallics, Vol. 16, Issue 10
  • DOI: 10.1021/om961057q

Single-Site Organozirconium Catalyst Embedded in a Metal–Organic Framework
journal, December 2015

  • Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua
  • Journal of the American Chemical Society, Vol. 137, Issue 50
  • DOI: 10.1021/jacs.5b11350

Practical β-Lactone Synthesis:  Epoxide Carbonylation at 1 atm
journal, August 2006

  • Kramer, John W.; Lobkovsky, Emil B.; Coates, Geoffrey W.
  • Organic Letters, Vol. 8, Issue 17
  • DOI: 10.1021/ol061292x

Highly Selective Nickel Ethylene Oligomerization Catalysts Based on Sterically Hindered Tris(pyrazolyl)borate Ligands
journal, November 2003

  • Kunrath, Fábio A.; de Souza, Roberto F.; Casagrande,, Osvaldo L.
  • Organometallics, Vol. 22, Issue 23
  • DOI: 10.1021/om034035u

Characterization of metal-organic frameworks by water adsorption
journal, April 2009


Catalytic oligomerization of ethylene over Ni-containing dealuminated Y zeolites
journal, February 2006


Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

Highly active self-immobilized FI-Zr catalysts in a PCP framework for ethylene polymerization
journal, January 2015

  • Li, He; Xu, Bo; He, Jianghao
  • Chemical Communications, Vol. 51, Issue 93
  • DOI: 10.1039/C5CC06460K

Reductive Electrosynthesis of Crystalline Metal–Organic Frameworks
journal, August 2011

  • Li, Minyuan; Dincă, Mircea
  • Journal of the American Chemical Society, Vol. 133, Issue 33
  • DOI: 10.1021/ja2041546

Drastic Enhancement of Catalytic Activity via Post-oxidation of a Porous Mn II Triazolate Framework
journal, July 2014

  • Liao, Pei-Qin; Li, Xu-Yu; Bai, Jie
  • Chemistry - A European Journal, Vol. 20, Issue 36
  • DOI: 10.1002/chem.201403123

Postsynthetic modification of mixed-linker metal–organic frameworks for ethylene oligomerization
journal, January 2014


Single-Walled Carbon Nanotube–Metalloporphyrin Chemiresistive Gas Sensor Arrays for Volatile Organic Compounds
journal, May 2015


Virtual High Throughput Screening Confirmed Experimentally: Porous Coordination Polymer Hydration
journal, November 2009

  • Low, John J.; Benin, Annabelle I.; Jakubczak, Paulina
  • Journal of the American Chemical Society, Vol. 131, Issue 43
  • DOI: 10.1021/ja9061344

A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis
journal, July 2010

  • Ma, Liqing; Falkowski, Joseph M.; Abney, Carter
  • Nature Chemistry, Vol. 2, Issue 10
  • DOI: 10.1038/nchem.738

[Lewis Acid]+[Co(CO)4] Complexes: A Versatile Class of Catalysts for Carbonylative Ring Expansion of Epoxides and Aziridines
journal, August 2002


Methane storage in advanced porous materials
journal, January 2012

  • Makal, Trevor A.; Li, Jian-Rong; Lu, Weigang
  • Chemical Society Reviews, Vol. 41, Issue 23
  • DOI: 10.1039/c2cs35251f

Electron Paramagnetic Resonance Studies of the Electronic Structures of Bis(maleonitriledithiolato)copper(II), -nickel(III), -cobalt(II), and -rhodium(II) Complexes
journal, November 1964

  • Maki, A. H.; Edelstein, N.; Davison, A.
  • Journal of the American Chemical Society, Vol. 86, Issue 21
  • DOI: 10.1021/ja01075a013

Single-Crystal to Single-Crystal Mechanical Contraction of Metal–Organic Frameworks through Stereoselective Postsynthetic Bromination
journal, July 2015

  • Marshall, Ross J.; Griffin, Sarah L.; Wilson, Claire
  • Journal of the American Chemical Society, Vol. 137, Issue 30
  • DOI: 10.1021/jacs.5b05434

Synthesis of nitropolychlorinated dibenzo- p -dioxins (NPCDDs) and their photochemical reaction with nucleophiles
journal, June 1995

  • Merica, Simona G.; Bunce, Nigel J.
  • Canadian Journal of Chemistry, Vol. 73, Issue 6
  • DOI: 10.1139/v95-103

Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst
journal, February 2016


Selective Propene Oligomerization with Nickel(II)-Based Metal–Organic Frameworks
journal, January 2014

  • Mlinar, Anton N.; Keitz, Benjamin K.; Gygi, David
  • ACS Catalysis, Vol. 4, Issue 3
  • DOI: 10.1021/cs401189a

Destruction of chemical warfare agents using metal–organic frameworks
journal, March 2015

  • Mondloch, Joseph E.; Katz, Michael J.; Isley III, William C.
  • Nature Materials, Vol. 14, Issue 5
  • DOI: 10.1038/nmat4238

Ethylene Polymerization Behavior of Tris(pyrazolyl)borate Titanium(IV) Complexes
journal, March 2002

  • Murtuza, Shahid; Casagrande, Osvaldo L.; Jordan, Richard F.
  • Organometallics, Vol. 21, Issue 9
  • DOI: 10.1021/om010530j

Optimization of adsorption processes for climate control and thermal energy storage
journal, October 2014


Experimental investigation of the silica gel–water adsorption isotherm characteristics
journal, November 2001


High Methanol Uptake Capacity in Two New Series of Metal–Organic Frameworks: Promising Materials for Adsorption-Driven Heat Pump Applications
journal, August 2016


Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks
journal, January 2015

  • Park, Sarah S.; Hontz, Eric R.; Sun, Lei
  • Journal of the American Chemical Society, Vol. 137, Issue 5
  • DOI: 10.1021/ja512437u

Heterogeneous Epoxide Carbonylation by Cooperative Ion-Pair Catalysis in Co(CO) 4 -Incorporated Cr-MIL-101
journal, March 2017


Single-Ion Li + , Na + , and Mg 2+ Solid Electrolytes Supported by a Mesoporous Anionic Cu–Azolate Metal–Organic Framework
journal, September 2017

  • Park, Sarah S.; Tulchinsky, Yuri; Dincă, Mircea
  • Journal of the American Chemical Society, Vol. 139, Issue 38
  • DOI: 10.1021/jacs.7b06197

The role of sulfur-containing groups in ammonia retention on activated carbons
journal, March 2010


Toward Understanding Reactive Adsorption of Ammonia on Cu-MOF/Graphite Oxide Nanocomposites
journal, November 2011

  • Petit, Camille; Huang, Liangliang; Jagiello, Jacek
  • Langmuir, Vol. 27, Issue 21
  • DOI: 10.1021/la202924y

Recent Advances in β-Lactone Chemistry
journal, January 1993


Enhanced ammonia adsorption on functionalized nanoporous carbons
journal, December 2015


High and Reversible Ammonia Uptake in Mesoporous Azolate Metal–Organic Frameworks with Open Mn, Co, and Ni Sites
journal, July 2016

  • Rieth, Adam J.; Tulchinsky, Yuri; Dincă, Mircea
  • Journal of the American Chemical Society, Vol. 138, Issue 30
  • DOI: 10.1021/jacs.6b05723

The Performance of Small-Pore Microporous Aluminophosphates in Low-Temperature Solar Energy Storage: The Structure-Property Relationship
journal, February 2012

  • Ristić, Alenka; Logar, Nataša Zabukovec; Henninger, Stefan K.
  • Advanced Functional Materials, Vol. 22, Issue 9
  • DOI: 10.1002/adfm.201102734

Fundamental and application aspects of adsorption cooling and desalination
journal, March 2016


A Readily Synthesized and Highly Active Epoxide Carbonylation Catalyst Based on a Chromium Porphyrin Framework:  Expanding the Range of Available β-Lactones
journal, February 2004

  • Schmidt, Joseph A. R.; Mahadevan, Viswanath; Getzler, Yutan D. Y. L.
  • Organic Letters, Vol. 6, Issue 3, p. 373-376
  • DOI: 10.1021/ol036244g

Chromium(III) Octaethylporphyrinato Tetracarbonylcobaltate:  A Highly Active, Selective, and Versatile Catalyst for Epoxide Carbonylation
journal, August 2005

  • Schmidt, Joseph A. R.; Lobkovsky, Emil B.; Coates, Geoffrey W.
  • Journal of the American Chemical Society, Vol. 127, Issue 32
  • DOI: 10.1021/ja051874u

Effect of Water Adsorption on Retention of Structure and Surface Area of Metal–Organic Frameworks
journal, April 2012

  • Schoenecker, Paul M.; Carson, Cantwell G.; Jasuja, Himanshu
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 18
  • DOI: 10.1021/ie202325p

New synthesis of chromium trichloride tetrahydrofuranate
journal, February 1989


Catalytic Ethylene Dimerization and Oligomerization:  Recent Developments with Nickel Complexes Containing P , N-Chelating Ligands
journal, October 2005

  • Speiser, Fredy; Braunstein, Pierre; Saussine, Lucien
  • Accounts of Chemical Research, Vol. 38, Issue 10
  • DOI: 10.1021/ar050040d

The Myth of Nickel(III) and Nickel(IV) in Planar Complexes 1
journal, July 1965

  • Stiefel, Edward I.; Waters, James H.; Billig, E.
  • Journal of the American Chemical Society, Vol. 87, Issue 13
  • DOI: 10.1021/ja01091a047

Specific and non-specific interactions between ammonia and activated carbons
journal, January 2004


Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011

  • Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri
  • Chemical Reviews, Vol. 112, Issue 2, p. 782-835
  • DOI: 10.1021/cr200274s

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Ethylene Oligomerization and Propylene Dimerization Using Cationic (α-Diimine)nickel(II) Catalysts
journal, January 1999

  • Svejda, Steven A.; Brookhart, Maurice
  • Organometallics, Vol. 18, Issue 1
  • DOI: 10.1021/om980736t

Carbon–ammonia pairs for adsorption refrigeration applications: ice making, air conditioning and heat pumping
journal, September 2009


A review of potential materials for thermal energy storage in building applications
journal, February 2013

  • Tatsidjodoung, Parfait; Le Pierrès, Nolwenn; Luo, Lingai
  • Renewable and Sustainable Energy Reviews, Vol. 18
  • DOI: 10.1016/j.rser.2012.10.025

MFU-4 - A Metal-Organic Framework for Highly Effective H 2 /D 2 Separation
journal, November 2012

  • Teufel, Julia; Oh, Hyunchul; Hirscher, Michael
  • Advanced Materials, Vol. 25, Issue 4
  • DOI: 10.1002/adma.201203383

Reversible Capture and Release of Cl 2 and Br 2 with a Redox-Active Metal–Organic Framework
journal, April 2017

  • Tulchinsky, Yuri; Hendon, Christopher H.; Lomachenko, Kirill A.
  • Journal of the American Chemical Society, Vol. 139, Issue 16
  • DOI: 10.1021/jacs.7b02161

Facile Deposition of Multicolored Electrochromic Metal-Organic Framework Thin Films
journal, October 2013

  • Wade, Casey R.; Li, Minyuan; Dincă, Mircea
  • Angewandte Chemie International Edition, Vol. 52, Issue 50
  • DOI: 10.1002/anie.201306162

Postsynthetic tuning of hydrophilicity in pyrazolate MOFs to modulate water adsorption properties
journal, January 2013

  • Wade, Casey R.; Corrales-Sanchez, Tachmajal; Narayan, Tarun C.
  • Energy & Environmental Science, Vol. 6, Issue 7
  • DOI: 10.1039/c3ee40876k

A review on adsorption working pairs for refrigeration
journal, April 2009

  • Wang, L. W.; Wang, R. Z.; Oliveira, R. G.
  • Renewable and Sustainable Energy Reviews, Vol. 13, Issue 3
  • DOI: 10.1016/j.rser.2007.12.002

Pyrazolate-Based Porphyrinic Metal–Organic Framework with Extraordinary Base-Resistance
journal, January 2016

  • Wang, Kecheng; Lv, Xiu-Liang; Feng, Dawei
  • Journal of the American Chemical Society, Vol. 138, Issue 3
  • DOI: 10.1021/jacs.5b10881

Grafting of hydrophilic ethylene glycols or ethylenediamine on coordinatively unsaturated metal sites in MIL-100(Cr) for improved water adsorption characteristics
journal, October 2013

  • Wickenheisser, Martin; Jeremias, Felix; Henninger, Stefan K.
  • Inorganica Chimica Acta, Vol. 407
  • DOI: 10.1016/j.ica.2013.07.024

A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis
journal, June 2005

  • Wu, Chuan-De; Hu, Aiguo; Zhang, Lin
  • Journal of the American Chemical Society, Vol. 127, Issue 25
  • DOI: 10.1021/ja052431t

Adsorption Sites and Binding Nature of CO 2 in Prototypical Metal−Organic Frameworks: A Combined Neutron Diffraction and First-Principles Study
journal, June 2010

  • Wu, Hui; Simmons, Jason M.; Srinivas, Gadipelli
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 13
  • DOI: 10.1021/jz100558r

Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites
journal, May 2014

  • Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A.
  • Nature Chemistry, Vol. 6, Issue 7
  • DOI: 10.1038/nchem.1956

Temperature-Triggered Collection and Release of Water from Fogs by a Sponge-Like Cotton Fabric
journal, January 2013

  • Yang, Helen; Zhu, Haijin; Hendrix, Marco M. R. M.
  • Advanced Materials, Vol. 25, Issue 8
  • DOI: 10.1002/adma.201204278

Ethylene Oligomerization Over Heterogeneous Catalysts
journal, September 2014

  • Zhang, Hongpeng; Li, Xiangping; Zhang, Yufei
  • Energy and Environment Focus, Vol. 3, Issue 3
  • DOI: 10.1166/eef.2014.1107

Metal-Organic Frameworks for Sensing Applications in the Gas Phase
journal, March 2009

  • Achmann, Sabine; Hagen, Gunter; Kita, Jaroslaw
  • Sensors, Vol. 9, Issue 3
  • DOI: 10.3390/s90301574

Thiophene-based covalent organic frameworks
journal, March 2013

  • Bertrand, G. H. V.; Michaelis, V. K.; Ong, T. -C.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 13
  • DOI: 10.1073/pnas.1221824110

Cu 3 (hexaiminotriphenylene) 2 : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing
journal, February 2015

  • Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F.
  • Angewandte Chemie International Edition, Vol. 54, Issue 14
  • DOI: 10.1002/anie.201411854

Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates
journal, June 2009

  • Chen, Long; Kim, Jangbae; Ishizuka, Tomoya
  • Journal of the American Chemical Society, Vol. 131, Issue 21, p. 7287-7292
  • DOI: 10.1021/ja901357h

An electroactive porous network from covalent metal–dithiolene links
journal, January 2014


The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method
journal, June 2012

  • Gándara, Felipe; Uribe-Romo, Fernando J.; Britt, David K.
  • Chemistry - A European Journal, Vol. 18, Issue 34, p. 10595-10601
  • DOI: 10.1002/chem.201103433

π-Electron Conjugation in Two Dimensions
journal, October 2013

  • Gutzler, Rico; Perepichka, Dmitrii F.
  • Journal of the American Chemical Society, Vol. 135, Issue 44
  • DOI: 10.1021/ja408355p

Structurally Designed Synthesis of Mechanically Stable Poly(benzoxazine-co-resol)-Based Porous Carbon Monoliths and Their Application as High-Performance CO 2 Capture Sorbents
journal, July 2011

  • Hao, Guang-Ping; Li, Wen-Cui; Qian, Dan
  • Journal of the American Chemical Society, Vol. 133, Issue 29
  • DOI: 10.1021/ja203857g

New Porous Crystals of Extended Metal-Catecholates
journal, August 2012

  • Hmadeh, Mohamad; Lu, Zheng; Liu, Zheng
  • Chemistry of Materials, Vol. 24, Issue 18, p. 3511-3513
  • DOI: 10.1021/cm301194a

Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator
journal, October 2014

  • Kambe, Tetsuya; Sakamoto, Ryota; Kusamoto, Tetsuro
  • Journal of the American Chemical Society, Vol. 136, Issue 41
  • DOI: 10.1021/ja507619d

π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet
journal, February 2013

  • Kambe, Tetsuya; Sakamoto, Ryota; Hoshiko, Ken
  • Journal of the American Chemical Society, Vol. 135, Issue 7
  • DOI: 10.1021/ja312380b

Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal−Organic Framework
journal, July 2010

  • Kobayashi, Yoji; Jacobs, Benjamin; Allendorf, Mark D.
  • Chemistry of Materials, Vol. 22, Issue 14
  • DOI: 10.1021/cm101238m

Opportunities in chemistry and materials science for topological insulators and their nanostructures
journal, October 2011


Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011

  • Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
  • Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
  • DOI: 10.1021/cr200324t

High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012

  • Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 134, Issue 31
  • DOI: 10.1021/ja3059827

Conductive MOF electrodes for stable supercapacitors with high areal capacitance
journal, October 2016

  • Sheberla, Dennis; Bachman, John C.; Elias, Joseph S.
  • Nature Materials, Vol. 16, Issue 2
  • DOI: 10.1038/nmat4766

Selective Turn-On Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal–Organic Frameworks with Open Metal Sites
journal, August 2013

  • Shustova, Natalia B.; Cozzolino, Anthony F.; Reineke, Sebastian
  • Journal of the American Chemical Society, Vol. 135, Issue 36
  • DOI: 10.1021/ja407778a

MOF-based electronic and opto-electronic devices
journal, January 2014

  • Stavila, V.; Talin, A. A.; Allendorf, M. D.
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00096J

Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016

  • Sun, Lei; Campbell, Michael G.; Dincă, Mircea
  • Angewandte Chemie International Edition, Vol. 55, Issue 11
  • DOI: 10.1002/anie.201506219

Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd 2 (TTFTB) as a Case Study
journal, October 2016

  • Sun, Lei; Park, Sarah S.; Sheberla, Dennis
  • Journal of the American Chemical Society, Vol. 138, Issue 44
  • DOI: 10.1021/jacs.6b09345

Mn 2 (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) Chains and High Intrinsic Charge Mobility
journal, May 2013

  • Sun, Lei; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 135, Issue 22
  • DOI: 10.1021/ja4037516

Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013

  • Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C.
  • Science, Vol. 343, Issue 6166, p. 66-69
  • DOI: 10.1126/science.1246738

Prediction of a Two-Dimensional Organic Topological Insulator
journal, May 2013

  • Wang, Z. F.; Su, Ninghai; Liu, Feng
  • Nano Letters, Vol. 13, Issue 6, p. 2842-2845
  • DOI: 10.1021/nl401147u

Receptor Function and Response of Semiconductor Gas Sensor
journal, January 2009


First-principles design of a half-filled flat band of the kagome lattice in two-dimensional metal-organic frameworks
journal, August 2016


Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brønsted Acid Groups
journal, January 2014

  • Van Humbeck, Jeffrey F.; McDonald, Thomas M.; Jing, Xiaofei
  • Journal of the American Chemical Society, Vol. 136, Issue 6, p. 2432-2440
  • DOI: 10.1021/ja4105478

Homogeneous Chromium Catalysts for Olefin Polymerization
journal, January 1998


Record Atmospheric Fresh Water Capture and Heat Transfer with a Material Operating at the Water Uptake Reversibility Limit
journal, May 2017


Evaluation of Commercial Off-the-Shelf Sorbents & Catalysts for Control of Ammonia and Carbon Monoxide
conference, November 2012

  • Luna, Bernadette; Somi, George; Winchester, James
  • 40th International Conference on Environmental Systems
  • DOI: 10.2514/6.2010-6062

Water Stability of Microporous Coordination Polymers and the Adsorption of Pharmaceuticals from Water
journal, November 2010

  • Cychosz, Katie A.; Matzger, Adam J.
  • Langmuir, Vol. 26, Issue 22
  • DOI: 10.1021/la103234u

An overview on adsorption pairs for cooling
journal, March 2013