Zeolite-Encapsulated Pt Nanoparticles for Tandem Catalysis

Cho, Hong Je; Kim, Doyoung; Li, Jing; Su, Dong; Xu, Bingjun

doi:10.1021/jacs.8b09568

Title: Zeolite-Encapsulated Pt Nanoparticles for Tandem Catalysis

Journal Article · Fri Sep 21 00:00:00 EDT 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b09568· OSTI ID:1495319

Cho, Hong Je ^[1]; Kim, Doyoung ^[1]; Li, Jing ^[2];

^[2];

^[1]

Univ. of Delaware, Newark, DE (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Encapsulation of metal nanoparticles in a zeolite matrix is a promising route to integrate multiple sequential reactions into a one-pot and one-step tandem catalytic reaction. We report a cationic polymer-assisted synthetic strategy to encapsulate Pt nanoparticles (NPs) into MFI zeolites. Degrees of encapsulation of Pt NPs in the synthesized catalysts exceeding 90% were demonstrated via kinetic studies of model reactions involving substrates with different molecular dimensions. HZSM-5 zeolite-encapsulated Pt NPs are able to selectively mediate the tandem Aldol condensation and hydrogenation of furfural and acetone to form hydrogenated C8 products with a combined yield of 87%. In contrast, hydrogenation and decarbonylation of furfural dominate on Pt NPs supported on HZSM-5 at otherwise identical conditions. The high selectivity towards the tandem reaction on the encapsulated catalyst is attributed to the distribution of metal and acid sites, which limits the access of furfural to Pt sites and promotes the acid-catalyzed Aldol condensation. This is the first demonstration that the product distribution in a tandem reaction is manipulated by tailoring the architecture of catalytic materials via encapsulation.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI); Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1495319

Report Number(s):: BNL-211286-2019-JAAM

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 41; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 120 works

Citation information provided by
Web of Science

References (53)

Orthogonal tandem catalysis Lohr, Tracy L.; Marks, Tobin J. Nature Chemistry, Vol. 7, Issue 6 https://doi.org/10.1038/nchem.2262	journal	May 2015
Towards resource efficient chemistry: tandem reactions with renewables Behr, Arno; Vorholt, Andreas J.; Ostrowski, Karoline A. Green Chem., Vol. 16, Issue 3 https://doi.org/10.1039/C3GC41960F	journal	January 2014
Heterogeneous Catalysis for Tandem Reactions Climent, Maria J.; Corma, Avelino; Iborra, Sara ACS Catalysis, Vol. 4, Issue 3 https://doi.org/10.1021/cs401052k	journal	January 2014
Insights into the Mechanism of Tandem Alkene Hydroformylation over a Nanostructured Catalyst with Multiple Interfaces Su, Ji; Xie, Chenlu; Chen, Chen Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b03915	journal	September 2016
Multifunctional nanocatalysts for tandem reactions: A leap toward sustainability Jagadeesan, Dinesh Applied Catalysis A: General, Vol. 511 https://doi.org/10.1016/j.apcata.2015.11.033	journal	February 2016
Oriented synthesis of target products in liquid-phase tandem reaction over a tripartite zeolite capsule catalyst Yang, Guohui; Kawata, Hajime; Lin, Qihang Chemical Science, Vol. 4, Issue 10 https://doi.org/10.1039/c3sc51499d	journal	January 2013
One-pot Aldol Condensation and Hydrodeoxygenation of Biomass-derived Carbonyl Compounds for Biodiesel Synthesis Faba, Laura; Díaz, Eva; Ordóñez, Salvador ChemSusChem, Vol. 7, Issue 10 https://doi.org/10.1002/cssc.201402236	journal	August 2014
Solid Nanoparticles that Catalyze Biofuel Upgrade Reactions at the Water/Oil Interface Crossley, S.; Faria, J.; Shen, M. Science, Vol. 327, Issue 5961 https://doi.org/10.1126/science.1180769	journal	December 2009
Nanoscale intimacy in bifunctional catalysts for selective conversion of hydrocarbons Zecevic, Jovana; Vanbutsele, Gina; de Jong, Krijn P. Nature, Vol. 528, Issue 7581 https://doi.org/10.1038/nature16173	journal	December 2015
Platinum–nickel frame within metal-organic framework fabricated in situ for hydrogen enrichment and molecular sieving Li, Zhi; Yu, Rong; Huang, Jinglu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9248	journal	September 2015
On Spatial Control in Heterogeneous Multifunctional Catalysts Murzin, Dmitry Yu. Catalysis Letters, Vol. 147, Issue 3 https://doi.org/10.1007/s10562-017-1970-3	journal	February 2017
Base free, one-pot synthesis of lactic acid from glycerol using a bifunctional Pt/Sn-MFI catalyst Cho, Hong Je; Chang, Chun-Chih; Fan, Wei Green Chem., Vol. 16, Issue 7 https://doi.org/10.1039/C4GC00723A	journal	January 2014
A novel mesoporous Pd/cobalt aluminate bifunctional catalyst for aldol condensation and following hydrogenation Xu, Wenjie; Liu, Xiaohui; Ren, Jiawen Catalysis Communications, Vol. 11, Issue 8 https://doi.org/10.1016/j.catcom.2010.02.002	journal	March 2010
Heterogeneous Catalysis: A Central Science for a Sustainable Future Friend, Cynthia M.; Xu, Bingjun Accounts of Chemical Research, Vol. 50, Issue 3 https://doi.org/10.1021/acs.accounts.6b00510	journal	March 2017
Foundational techniques for catalyst design in the upgrading of biomass-derived multifunctional molecules Murphy, Brian M.; Xu, Bingjun Progress in Energy and Combustion Science, Vol. 67 https://doi.org/10.1016/j.pecs.2018.01.003	journal	July 2018
Heterogeneous Catalyst Deactivation and Regeneration: A Review Argyle, Morris; Bartholomew, Calvin Catalysts, Vol. 5, Issue 1 https://doi.org/10.3390/catal5010145	journal	February 2015
Concerted Bimetallic Nanocluster Synthesis and Encapsulation via Induced Zeolite Framework Demetallation for Shape and Substrate Selective Heterogeneous Catalysis Iida, Takayuki; Zanchet, Daniela; Ohara, Koji Angewandte Chemie International Edition, Vol. 57, Issue 22 https://doi.org/10.1002/anie.201800557	journal	May 2018
A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores Zhang, Jian; Wang, Liang; Shao, Yi Angewandte Chemie International Edition, Vol. 56, Issue 33 https://doi.org/10.1002/anie.201703938	journal	May 2017
Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D Liu, Lichen; Díaz, Urbano; Arenal, Raul Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4757	journal	September 2016
Encapsulation of Metal Clusters within MFI via Interzeolite Transformations and Direct Hydrothermal Syntheses and Catalytic Consequences of Their Confinement Goel, Sarika; Zones, Stacey I.; Iglesia, Enrique Journal of the American Chemical Society, Vol. 136, Issue 43 https://doi.org/10.1021/ja507956m	journal	October 2014
Challenges and strategies in the encapsulation and stabilization of monodisperse Au clusters within zeolites Otto, Trenton; Zones, Stacey I.; Iglesia, Enrique Journal of Catalysis, Vol. 339 https://doi.org/10.1016/j.jcat.2016.04.015	journal	July 2016
Hydrothermal synthesis of LTA-encapsulated metal clusters and consequences for catalyst stability, reactivity, and selectivity Wu, Zhijie; Goel, Sarika; Choi, Minkee Journal of Catalysis, Vol. 311 https://doi.org/10.1016/j.jcat.2013.12.021	journal	March 2014
Mercaptosilane-Assisted Synthesis of Metal Clusters within Zeolites and Catalytic Consequences of Encapsulation Choi, Minkee; Wu, Zhijie; Iglesia, Enrique Journal of the American Chemical Society, Vol. 132, Issue 26 https://doi.org/10.1021/ja102778e	journal	July 2010
In Situ Confinement of Ultrasmall Pd Clusters within Nanosized Silicalite-1 Zeolite for Highly Efficient Catalysis of Hydrogen Generation Wang, Ning; Sun, Qiming; Bai, Risheng Journal of the American Chemical Society, Vol. 138, Issue 24 https://doi.org/10.1021/jacs.6b03518	journal	June 2016
The Hydrothermal Synthesis of Zeolites: History and Development from the Earliest Days to the Present Time Cundy, Colin S.; Cox, Paul A. Chemical Reviews, Vol. 103, Issue 3, p. 663-702 https://doi.org/10.1021/cr020060i	journal	March 2003
Application of the xenon-adsorption method for the study of metal cluster formation and growth on Y zeolite Ryoo, Ryong; Cho, Sung June; Pak, Chanho Journal of the American Chemical Society, Vol. 114, Issue 1 https://doi.org/10.1021/ja00027a011	journal	January 1992
Heck Reaction Catalyzed by Pd-Modified Zeolites Djakovitch, Laurent; Koehler, Klaus Journal of the American Chemical Society, Vol. 123, Issue 25 https://doi.org/10.1021/ja001087r	journal	June 2001
Zeolite supported mono- and bimetallic systems: structure and performance as CO hydrogenation catalysts Guczi, László; Kiricsi, Imre Applied Catalysis A: General, Vol. 186, Issue 1-2 https://doi.org/10.1016/S0926-860X(99)00156-8	journal	October 1999
Real-Time Characterization of Formation and Breakup of Iridium Clusters in Highly Dealuminated Zeolite Y Uzun, Alper; Gates, Bruce C. Angewandte Chemie International Edition, Vol. 47, Issue 48 https://doi.org/10.1002/anie.200802140	journal	August 2008
Gold Nanoclusters Entrapped in the α-Cages of Y Zeolites: Structural Characterization by X-ray Absorption Spectroscopy Fierro-Gonzalez, Juan C.; Hao, Yalin; Gates, Bruce C. The Journal of Physical Chemistry C, Vol. 111, Issue 18 https://doi.org/10.1021/jp0685176	journal	May 2007
Reversible Transformation of Pt Nanoparticles into Single Atoms inside High-Silica Chabazite Zeolite Moliner, Manuel; Gabay, Jadeene E.; Kliewer, Chris E. Journal of the American Chemical Society, Vol. 138, Issue 48 https://doi.org/10.1021/jacs.6b10169	journal	November 2016
Subnanometric Hybrid Pd-M(OH)2, M = Ni, Co, Clusters in Zeolites as Highly Efficient Nanocatalysts for Hydrogen Generation Sun, Qiming; Wang, Ning; Bing, Qiming Chem, Vol. 3, Issue 3 https://doi.org/10.1016/j.chempr.2017.07.001	journal	September 2017
The hydrodeoxygenation of bioderived furans into alkanes Sutton, Andrew D.; Waldie, Fraser D.; Wu, Ruilian Nature Chemistry, Vol. 5, Issue 5, p. 428-432 https://doi.org/10.1038/nchem.1609	journal	April 2013
Production of Liquid Alkanes by Aqueous-Phase Processing of Biomass-Derived Carbohydrates Huber, George W.; Chheda, Juben N.; Barrett, Christopher J. Science, Vol. 308, Issue 5727, p. 1446-1450 https://doi.org/10.1126/science.1111166	journal	June 2005
Pd/NbOPO ₄ Multifunctional Catalyst for the Direct Production of Liquid Alkanes from Aldol Adducts of Furans Xia, Qi-Neng; Cuan, Qian; Liu, Xiao-Hui Angewandte Chemie International Edition, Vol. 53, Issue 37 https://doi.org/10.1002/anie.201403440	journal	July 2014
Crystallization of high silica BEA by dry gel conversion Hari Prasad Rao, P. R.; Ueyama, K.; Matsukata, M. Applied Catalysis A: General, Vol. 166, Issue 1 https://doi.org/10.1016/S0926-860X(98)80005-7	journal	January 1998
Direct Synthetic Strategy of Mesoporous ZSM-5 Zeolites by Using Conventional Block Copolymer Templates and the Improved Catalytic Properties Zhou, Jian; Hua, Zile; Liu, Zhicheng ACS Catalysis, Vol. 1, Issue 4 https://doi.org/10.1021/cs1000976	journal	February 2011
Fluoride-free synthesis of a Sn-BEA catalyst by dry gel conversion Chang, Chun-Chih; Cho, Hong Je; Wang, Zhuopeng Green Chemistry, Vol. 17, Issue 5 https://doi.org/10.1039/C4GC02457E	journal	January 2015
Recent advances in hierarchically structured zeolites: synthesis and material performances Hua, Zi Le; Zhou, Jian; Shi, Jian Lin Chemical Communications, Vol. 47, Issue 38 https://doi.org/10.1039/c1cc10261c	journal	January 2011
Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts Choi, Minkee; Na, Kyungsu; Kim, Jeongnam Nature, Vol. 461, Issue 7261, p. 246-249 https://doi.org/10.1038/nature08288	journal	September 2009
Direct, single-step synthesis of hierarchical zeolites without secondary templating Wang, Zhuopeng; Li, Chao; Cho, Hong Je Journal of Materials Chemistry A, Vol. 3, Issue 3 https://doi.org/10.1039/C4TA05031B	journal	January 2015
Synthesis of Hierarchical Sn-MFI as Lewis Acid Catalysts for Isomerization of Cellulosic Sugars Cho, Hong Je; Dornath, Paul; Fan, Wei ACS Catalysis, Vol. 4, Issue 6 https://doi.org/10.1021/cs500295u	journal	April 2014
An Effective Hydrothermal Route for the Synthesis of Multiple PDDA-Protected Noble-Metal Nanostructures Chen, Hongjun; Wang, Yuling; Dong, Shaojun Inorganic Chemistry, Vol. 46, Issue 25 https://doi.org/10.1021/ic7009572	journal	November 2007
Preparation and electrochemical performance for methanol oxidation of pt/graphene nanocomposites Li, Yueming; Tang, Longhua; Li, Jinghong Electrochemistry Communications, Vol. 11, Issue 4 https://doi.org/10.1016/j.elecom.2009.02.009	journal	April 2009
Zeolites by confined space synthesis – characterization of the acid sites in nanosized ZSM-5 by ammonia desorption and 27Al/29Si-MAS NMR spectroscopy Jacobsen, Claus J. H.; Madsen, Claus; Janssens, Ton V. W. Microporous and Mesoporous Materials, Vol. 39, Issue 1-2 https://doi.org/10.1016/S1387-1811(00)00215-8	journal	September 2000
Synthesis of mesoporous ZSM-5 zeolites through desilication and re-assembly processes Yoo, Won Cheol; Zhang, Xueyi; Tsapatsis, Michael Microporous and Mesoporous Materials, Vol. 149, Issue 1 https://doi.org/10.1016/j.micromeso.2011.08.014	journal	February 2012
Aldol condensation of furfural and acetone on zeolites Kikhtyanin, Oleg; Kelbichová, Vendula; Vitvarová, Dana Catalysis Today, Vol. 227 https://doi.org/10.1016/j.cattod.2013.10.059	journal	May 2014
Oxidation of Bioethanol using Zeolite-Encapsulated Gold Nanoparticles Mielby, Jerrik; Abildstrøm, Jacob Oskar; Wang, Feng Angewandte Chemie International Edition https://doi.org/10.1002/anie.201406354	journal	September 2014
Physical adsorption characterization of nanoporous materials: progress and challenges Thommes, Matthias; Cychosz, Katie A. Adsorption, Vol. 20, Issue 2-3 https://doi.org/10.1007/s10450-014-9606-z	journal	February 2014
On the effectiveness of tailored mesoporous MFI zeolites for biomass catalytic fast pyrolysis Gamliel, David P.; Cho, Hong Je; Fan, Wei Applied Catalysis A: General, Vol. 522 https://doi.org/10.1016/j.apcata.2016.04.026	journal	July 2016
Polyelectrolyte Assisted Synthesis and Enhanced Oxygen Reduction Activity of Pt Nanocrystals with Controllable Shape and Size Du, Lei; Zhang, Sheng; Chen, Guangyu ACS Applied Materials & Interfaces, Vol. 6, Issue 16 https://doi.org/10.1021/am503372f	journal	July 2014
Hierarchically porous BEA stannosilicates as unique catalysts for bulky ketone conversion and continuous operation Al-Nayili, Abbas; Yakabi, Keiko; Hammond, Ceri Journal of Materials Chemistry A, Vol. 4, Issue 4 https://doi.org/10.1039/C5TA08709K	journal	January 2016
Peculiar behavior of MWW materials in aldol condensation of furfural and acetone Kikhtyanin, Oleg; Chlubná, Pavla; Jindrová, Tereza Dalton Transactions, Vol. 43, Issue 27 https://doi.org/10.1039/c4dt00184b	journal	January 2014

Cited By (11)

Single-atomic cobalt sites embedded in hierarchically ordered porous nitrogen-doped carbon as a superior bifunctional electrocatalyst Sun, Tingting; Zhao, Shu; Chen, Wenxing Proceedings of the National Academy of Sciences, Vol. 115, Issue 50 https://doi.org/10.1073/pnas.1813605115	journal	November 2018
Confinement Effects in Zeolite‐Confined Noble Metals Wu, Si‐Ming; Yang, Xiao‐Yu; Janiak, Christoph Angewandte Chemie, Vol. 131, Issue 36 https://doi.org/10.1002/ange.201900013	journal	June 2019
Characterization of Metal‐zeolite Composite Catalysts: Determining the Environment of the Active Phase Juneau, Mitchell; Liu, Renjie; Peng, Yikang ChemCatChem, Vol. 12, Issue 7 https://doi.org/10.1002/cctc.201902039	journal	April 2020
Highly Active Mesoporous Cu−Al ₂ O ₃ Catalyst for the Hydrodeoxygenation of Furfural to 2‐methylfuran Park, Seyeon; Kannapu, Hari Prasad Reddy; Jeong, Cheonwoo ChemCatChem, Vol. 12, Issue 1 https://doi.org/10.1002/cctc.201901312	journal	October 2019
Direct synthesis of hollow single-crystalline zeolite beta using a small organic lactam as a recyclable hollow-directing agent Zhao, Dongpu; Wang, Yanan; Chu, Weifeng Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta01693g	journal	January 2019
Confinement Effects in Zeolite‐Confined Noble Metals Wu, Si‐Ming; Yang, Xiao‐Yu; Janiak, Christoph Angewandte Chemie International Edition, Vol. 58, Issue 36 https://doi.org/10.1002/anie.201900013	journal	September 2019
The catalytic behaviour in aqueous-phase hydrogenation over a renewable Ni catalyst derived from a perovskite-type oxide Chen, Chun; Fan, Ruoyu; Gong, Wanbing Dalton Transactions, Vol. 47, Issue 48 https://doi.org/10.1039/c8dt03907k	journal	January 2018
Framework-confined Sn in Si-beta stabilizing ultra-small Pt nanoclusters as direct propane dehydrogenation catalysts with high selectivity and stability Wang, Yansu; Hu, Zhong-Pan; Tian, Wenwen Catalysis Science & Technology, Vol. 9, Issue 24 https://doi.org/10.1039/c9cy01907c	journal	January 2019
Monodisperse nanoparticles for catalysis and nanomedicine Muzzio, Michelle; Li, Junrui; Yin, Zhouyang Nanoscale, Vol. 11, Issue 41 https://doi.org/10.1039/c9nr06080d	journal	January 2019
Assessment of the Location of Pt Nanoparticles in Pt/zeolite Y/γ‐Al ₂ O ₃ Composite Catalysts Oenema, Jogchum; Hofmann, Jan P.; Hensen, Emiel J. M. ChemCatChem, Vol. 12, Issue 2 https://doi.org/10.1002/cctc.201901617	journal	October 2019
Novel CoNi-metal–organic framework crystal-derived CoNi@C: synthesis and effective cascade catalysis Wang, Lin; Zhang, Jian-Wei; Li, Chenchen Dalton Transactions, Vol. 49, Issue 30 https://doi.org/10.1039/d0dt01558j	journal	January 2020