A novel strategy to purify conductive polymer particles

Spence, Daron; Polizos, Georgios; Joshi, Pooran; Sharma, Jaswinder

doi:10.1039/C8RA08372J

Title: A novel strategy to purify conductive polymer particles

Journal Article · Fri Feb 08 00:00:00 EST 2019 · RSC Advances

DOI:https://doi.org/10.1039/C8RA08372J· OSTI ID:1493939

Spence, Daron ^[1]; Polizos, Georgios ^[2]; Joshi, Pooran ^[3];

^[4]

Roll-to-Roll Manufacturing Group, Oak Ridge National Laboratory, Oak Ridge TN 37831, USA, Georgia Institute of Technology
Roll-to-Roll Manufacturing Group, Oak Ridge National Laboratory, Oak Ridge TN 37831, USA
Material Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge TN 37831, USA
Roll-to-Roll Manufacturing Group, Oak Ridge National Laboratory, Oak Ridge TN 37831, USA, Building Envelope & Urban Systems Research Group

The purification of conductive polymer (e.g., polyaniline) particles is a challenging task, especially when the particle size is small. Herein, we demonstrate a unique strategy (electrode-based) to purify polyaniline particles by exploiting the difference in surface charge between particles and surfactants, and compare the results with a commonly used purification strategy (washing).

View Journal Article

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Building Technologies Office; USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1493939

Alternate ID(s):: OSTI ID: 1494894

Journal Information:: RSC Advances, Journal Name: RSC Advances Vol. 9 Journal Issue: 9; ISSN 2046-2069

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

Citation Metrics:

Cited by: 1 work

Citation information provided by
Web of Science

References (21)

Nanostructured Polyaniline Sensors Huang, Jiaxing; Virji, Shabnam; Weiller, Bruce H. Chemistry - A European Journal, Vol. 10, Issue 6 https://doi.org/10.1002/chem.200305211	journal	March 2004
In situ polymerized polyaniline nanofiber-based functional cotton and nylon fabrics as millimeter-wave absorbers Joseph, Nina; Varghese, Jobin; Sebastian, Mailadil Thomas Polymer Journal, Vol. 49, Issue 4 https://doi.org/10.1038/pj.2016.121	journal	January 2017
Processable colloidal dispersions of polyaniline-based copolymers for transparent electrodes Wang, Yue; Guan, Xin N.; Wu, Che-Yu Polymer Chemistry, Vol. 4, Issue 17 https://doi.org/10.1039/c3py00672g	journal	January 2013
Inkjet Printable Polyaniline Nanoformulations Ngamna, Orawan; Morrin, Aoife; Killard, Anthony J. Langmuir, Vol. 23, Issue 16 https://doi.org/10.1021/la700540g	journal	July 2007
Counter-ion induced processibility of conducting polyaniline and of conducting polyblends of polyaniline in bulk polymers Cao, Yong; Smith, Paul; Heeger, Alan J. Synthetic Metals, Vol. 48, Issue 1 https://doi.org/10.1016/0379-6779(92)90053-L	journal	June 1992
Ultrasensitive NH ₃ Gas Sensor from Polyaniline Nanograin Enchased TiO ₂ Fibers Gong, Jian; Li, Yinhua; Hu, Zeshan The Journal of Physical Chemistry C, Vol. 114, Issue 21 https://doi.org/10.1021/jp100685r	journal	May 2010
Graphene quantum dot-doped polyaniline nanofiber as high performance supercapacitor electrode materials Mondal, Sanjoy; Rana, Utpal; Malik, Sudip Chemical Communications, Vol. 51, Issue 62 https://doi.org/10.1039/C5CC03981A	journal	January 2015
Influence of oxidation state, pH, and counterion on the conductivity of polyaniline Focke, Walter W.; Wnek, Gary E.; Wei, Yen. The Journal of Physical Chemistry, Vol. 91, Issue 22 https://doi.org/10.1021/j100306a059	journal	October 1987
Synthesis of Polyaniline Particles via Inverse and Direct Miniemulsion Marie, Emmanuelle; Rothe, Regina; Antonietti, Markus Macromolecules, Vol. 36, Issue 11 https://doi.org/10.1021/ma0257550	journal	June 2003
Polyaniline pH Electrodes Hamdani, Kahkashan; Cheng, K. L. Microchemical Journal, Vol. 61, Issue 3 https://doi.org/10.1006/mchj.1998.1682	journal	March 1999
Humidity sensing investigation on nanostructured polyaniline synthesized via chemical polymerization method Kumar, Ravindra; Yadav, B. C. Materials Letters, Vol. 167 https://doi.org/10.1016/j.matlet.2016.01.082	journal	March 2016
In situ preparation of fluorescent polyaniline nanotubes doped with perylene tetracarboxylic acids Rana, Utpal; Chakrabarti, Kuntal; Malik, Sudip Journal of Materials Chemistry, Vol. 21, Issue 30 https://doi.org/10.1039/c1jm12051d	journal	January 2011
Ascorbate sensor based on ‘self-doped’ polyaniline Zhou, Dong-Mei; Xu, Jing-Juan; Chen, Hong-Yuan Electroanalysis, Vol. 9, Issue 15 https://doi.org/10.1002/elan.1140091512	journal	October 1997
Fabrication of an ammonia gas sensor using inkjet-printed polyaniline nanoparticles Crowley, K.; Morrin, A.; Hernandez, A. Talanta, Vol. 77, Issue 2 https://doi.org/10.1016/j.talanta.2008.07.022	journal	December 2008
Electrochemical synthesis: a novel technique for processing multi-functional coatings Iroh, Jude O.; Zhu, Yanrong; Shah, Kunal Progress in Organic Coatings, Vol. 47, Issue 3-4 https://doi.org/10.1016/j.porgcoat.2003.07.006	journal	September 2003
Polymerisation and characterisation of conducting polyaniline nanoparticle dispersions Moulton, S. E.; Innis, P. C.; Kane-Maguire, L. A. P. Current Applied Physics, Vol. 4, Issue 2-4 https://doi.org/10.1016/j.cap.2003.11.059	journal	April 2004
Equilibrium doping of polyaniline by dodecylbenzenesulfonic acid Baćani, M.; Babić, D.; Novak, M. Synthetic Metals, Vol. 159, Issue 23-24 https://doi.org/10.1016/j.synthmet.2009.09.016	journal	December 2009
Electrochemical synthesis of polyaniline and its comparison with chemically synthesized polyaniline Bhadra, Sambhu; Singha, Nikhil K.; Khastgir, Dipak Journal of Applied Polymer Science, Vol. 104, Issue 3 https://doi.org/10.1002/app.25867	journal	January 2007
Polyaniline-based glucose biosensor: A review Lai, Jiahui; Yi, Yingchun; Zhu, Ping Journal of Electroanalytical Chemistry, Vol. 782 https://doi.org/10.1016/j.jelechem.2016.10.033	journal	December 2016
Recent advances in polyaniline composites with metals, metalloids and nonmetals Ćirić-Marjanović, Gordana Synthetic Metals, Vol. 170 https://doi.org/10.1016/j.synthmet.2013.02.028	journal	April 2013
Doping of polyaniline films with organic sulfonic acids in aqueous media and the effect of water on these doped films Ayad, Mohamad M.; Zaki, Eman A. European Polymer Journal, Vol. 44, Issue 11 https://doi.org/10.1016/j.eurpolymj.2008.08.012	journal	November 2008

Cited By (1)

Synthesis and Novel Purification Process of PANI and PANI/AgNPs Composite Mota, María L.; Carrillo, Amanda; Verdugo, Ana J. Molecules, Vol. 24, Issue 8 https://doi.org/10.3390/molecules24081621	journal	April 2019