Superconductivity in Y7Ru4InGe12

Bao, Jin -Ke; Bugaris, Daniel E.; Zheng, Huihuo; Willa, Kristin; Welp, Ulrich; Chung, Duck Young; Kanatzidis, Mercouri G.

doi:10.1103/PhysRevMaterials.3.024802

Title: Superconductivity in $Y_{7} R u_{4} InG e_{12}$

Journal Article · Tue Feb 12 00:00:00 EST 2019 · Physical Review Materials

DOI:https://doi.org/10.1103/PhysRevMaterials.3.024802· OSTI ID:1497390

Bao, Jin -Ke ^[1]; Bugaris, Daniel E. ^[1]; Zheng, Huihuo ^[1]; Willa, Kristin ^[1]; Welp, Ulrich ^[1]; Chung, Duck Young ^[1]; Kanatzidis, Mercouri G. ^[2]

Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)

We report a type-II intermetallic superconductor Y₇Ru₄InGe₁₂ with a transition temperature (T_c) of ~5.8 K, which is confirmed by zero resistivity, diamagnetic magnetic susceptibility, and specific-heat jump. Single crystals of Y₇Ru₄InGe₁₂ were grown from a reactive indium flux. Y₇Ru₄InGe₁₂ crystallizes in the tetragonal space group P4/m and features a [Ru₄InGe₁₂] polyanionic network with Y atoms located in three different channels. The upper critical fields of Y₇Ru₄InGe₁₂ at 0 K are determined to be ~5.3 and 2.4 T along the c axis and the ab plane, respectively. The estimated coherence length along the c axis (~174 Å) is much larger than the estimated mean free path along the c axis (~29 Å) in Y₇Ru₄InGe₁₂, placing its superconductivity in the so-called dirty regime. The compound exhibits a large superconducting specific-heat jump ΔC/γeT_c ≈ 2.4, significantly well above the weak-coupling Barden-Cooper-Schrieffer theoretical value of 1.43 and pointing to a strong-coupling scenario in Y₇Ru₄InGe₁₂. As a result, density-functional-theory calculations show that the density of states in Y₇Ru₄InGe₁₂ exhibits a broad peak near the Fermi level which mainly derives from Y–4d,Ru–4d, and Ge–4p states.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1497390

Alternate ID(s):: OSTI ID: 1494387

Journal Information:: Physical Review Materials, Vol. 3, Issue 2; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 4 works

Citation information provided by
Web of Science

References (59)

Crystal Growth and the Search for Highly Correlated Intermetallics Thomas, Evan Lyle; Millican, Jasmine N.; Okudzeto, Edem K. Comments on Inorganic Chemistry, Vol. 27, Issue 1-2 https://doi.org/10.1080/02603590600666215	journal	August 2006
Iron-Based Layered Superconductor La[O _1- _x F _x ]FeAs ( x = 0.05−0.12) with T _c = 26 K Kamihara, Yoichi; Watanabe, Takumi; Hirano, Masahiro Journal of the American Chemical Society, Vol. 130, Issue 11 https://doi.org/10.1021/ja800073m	journal	March 2008
Specific Heats at Low Temperatures Gopal, E. S. R. https://doi.org/10.1007/978-1-4684-9081-7	book	January 1966
Superconductivity in the Presence of Strong Pauli Paramagnetism: Ce ${Cu}_{2}$ ${Si}_{2}$ Steglich, F.; Aarts, J.; Bredl, C. D. Physical Review Letters, Vol. 43, Issue 25 https://doi.org/10.1103/PhysRevLett.43.1892	journal	December 1979
The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds Kanatzidis, Mercouri G.; Pöttgen, Rainer; Jeitschko, Wolfgang Angewandte Chemie International Edition, Vol. 44, Issue 43 https://doi.org/10.1002/anie.200462170	journal	November 2005
Growth of single crystals from metallic fluxes Canfield, P. C.; Fisk, Z. Philosophical Magazine B, Vol. 65, Issue 6 https://doi.org/10.1080/13642819208215073	journal	June 1992
CRYSTAL: a computational tool for the ab initio study of the electronic properties of crystals Dovesi, Roberto; Orlando, Roberto; Civalleri, Bartolomeo Zeitschrift für Kristallographie - Crystalline Materials, Vol. 220, Issue 5/6 https://doi.org/10.1524/zkri.220.5.571.65065	journal	January 2005
Superconductivity in Quasi-One-Dimensional $K_{2} {Cr}_{3} {As}_{3}$ with Significant Electron Correlations Bao, Jin-Ke; Liu, Ji-Yong; Ma, Cong-Wei Physical Review X, Vol. 5, Issue 1 https://doi.org/10.1103/PhysRevX.5.011013	journal	February 2015
Materials design for new superconductors Norman, M. R. Reports on Progress in Physics, Vol. 79, Issue 7 https://doi.org/10.1088/0034-4885/79/7/074502	journal	May 2016
Mixed Valency in Yb ₇ Co ₄ InGe ₁₂ : A Novel Intermetallic Compound Stabilized in Liquid Indium Chondroudi, Maria; Balasubramanian, Mahalingam; Welp, Ulrich Chemistry of Materials, Vol. 19, Issue 19 https://doi.org/10.1021/cm071687q	journal	September 2007
Signatures of valence fluctuations in ${CeCu}_{2} {Si}_{2}$ under high pressure Holmes, Alexander T.; Jaccard, Didier; Miyake, Kazumasa Physical Review B, Vol. 69, Issue 2 https://doi.org/10.1103/PhysRevB.69.024508	journal	January 2004
Tunneling measurements of the electron-phonon interaction in ${Ba}_{1 - x}$ $K_{x}$ ${BiO}_{3}$ Samuely, P.; Bobrov, N. L.; Jansen, A. G. M. Physical Review B, Vol. 48, Issue 18 https://doi.org/10.1103/PhysRevB.48.13904	journal	November 1993
Superconductivity in Single Crystals of Lu ₃ T ₄ Ge _{13– x} ( T = Co, Rh, Os) and Y ₃ T ₄ Ge _{13– x} ( T = Ir, Rh, Os) Rai, Binod K.; Oswald, Iain W. H.; Wang, Jiakui K. Chemistry of Materials, Vol. 27, Issue 7 https://doi.org/10.1021/cm504658h	journal	March 2015
Reentrant ferromagnetism observed in SmMn2Ge2 Fujii, H.; Okamoto, T.; Shigeoka, T. Solid State Communications, Vol. 53, Issue 8 https://doi.org/10.1016/0038-1098(85)90385-0	journal	February 1985
The contribution to the electrical resistance of metals from collisions between electrons Baber, W. G. Proceedings of the Royal Society of London. Series A - Mathematical and Physical Sciences, Vol. 158, Issue 894, p. 383-396 https://doi.org/10.1098/rspa.1937.0027	journal	January 1937
Yb ₇ Ni ₄ InGe ₁₂ : a quaternary compound having mixed valent Yb atoms grown from indium flux Subbarao, Udumula; Jana, Rajkumar; Chondroudi, Maria Dalton Transactions, Vol. 44, Issue 12 https://doi.org/10.1039/C4DT03783A	journal	January 2015
Charge Density Wave in the New Polymorphs of RE ₂ Ru ₃ Ge ₅ ( RE = Pr, Sm, Dy) Bugaris, Daniel E.; Malliakas, Christos D.; Han, Fei Journal of the American Chemical Society, Vol. 139, Issue 11 https://doi.org/10.1021/jacs.7b00284	journal	March 2017
Superconductivity in the Platinum Germanides ${MPt}_{4} {Ge}_{12}$ ( $M = Rare − Earth$ or Alkaline-Earth Metal) with Filled Skutterudite Structure Gumeniuk, R.; Schnelle, W.; Rosner, H. Physical Review Letters, Vol. 100, Issue 1 https://doi.org/10.1103/PhysRevLett.100.017002	journal	January 2008
Pressure induced heavy fermion superconductivity of CeCu2Ge2 Jaccard, D.; Behnia, K.; Sierro, J. Physics Letters A, Vol. 163, Issue 5-6 https://doi.org/10.1016/0375-9601(92)90860-O	journal	March 1992
The Challenge of Unconventional Superconductivity Norman, M. R. Science, Vol. 332, Issue 6026 https://doi.org/10.1126/science.1200181	journal	April 2011
Transition Temperature of Strong-Coupled Superconductors McMillan, W. L. Physical Review, Vol. 167, Issue 2 https://doi.org/10.1103/PhysRev.167.331	journal	March 1968
Upper Limit for the Critical Field in Hard Superconductors Clogston, A. M. Physical Review Letters, Vol. 9, Issue 6 https://doi.org/10.1103/PhysRevLett.9.266	journal	September 1962
Properties of boson-exchange superconductors Carbotte, J. P. Reviews of Modern Physics, Vol. 62, Issue 4 https://doi.org/10.1103/RevModPhys.62.1027	journal	October 1990
Unconventional superconductivity Stewart, G. R. Advances in Physics, Vol. 66, Issue 2 https://doi.org/10.1080/00018732.2017.1331615	journal	April 2017
Unconventional Superconductivity in the Layered Iron Germanide ${YFe}_{2} {Ge}_{2}$ Chen, Jiasheng; Semeniuk, Konstantin; Feng, Zhuo Physical Review Letters, Vol. 116, Issue 12 https://doi.org/10.1103/PhysRevLett.116.127001	journal	March 2016
Clusters, Assemble: Growth of Intermetallic Compounds from Metal Flux Reactions Latturner, Susan E. Accounts of Chemical Research, Vol. 51, Issue 1 https://doi.org/10.1021/acs.accounts.7b00483	journal	December 2017
Evolution des coordinations dans les structures d'isotypes de U2Co3Si5:R2T3X5 (R ≡; La, Y; T ≡; Ru, Rh, Ir; X ≡; Si, Ge, Sn) Venturini, G.; Malaman, B.; Roques, B. Journal of the Less Common Metals, Vol. 152, Issue 1 https://doi.org/10.1016/0022-5088(89)90071-4	journal	June 1989
Superfluid Density and Energy Gap Function of Superconducting ${PrPt}_{4} {Ge}_{12}$ Maisuradze, A.; Nicklas, M.; Gumeniuk, R. Physical Review Letters, Vol. 103, Issue 14 https://doi.org/10.1103/PhysRevLett.103.147002	journal	September 2009
Structures and Physical Properties of Rare-Earth Chromium Germanides RECrGe₃ (RE = La−Nd, Sm) Bie, Haiying; Zelinska, Oksana Ya.; Tkachuk, Andriy V. Chemistry of Materials, Vol. 19, Issue 18 https://doi.org/10.1021/cm071276+	journal	August 2007
Ab Initio Energy Landscape of GeF2: A System Featuring Lone Pair Structure Candidates Doll, Klaus; Jansen, Martin Angewandte Chemie International Edition, Vol. 50, Issue 20 https://doi.org/10.1002/anie.201008070	journal	April 2011
Differential membrane-based nanocalorimeter for high-resolution measurements of low-temperature specific heat Tagliati, S.; Krasnov, V. M.; Rydh, A. Review of Scientific Instruments, Vol. 83, Issue 5 https://doi.org/10.1063/1.4717676	journal	May 2012
A note on the Maximum Critical Field of High‐Field Superconductors Chandrasekhar, B. S. Applied Physics Letters, Vol. 1, Issue 1 https://doi.org/10.1063/1.1777362	journal	September 1962
Superconducting materials classes: Introduction and overview Hirsch, J. E.; Maple, M. B.; Marsiglio, F. Physica C: Superconductivity and its Applications, Vol. 514 https://doi.org/10.1016/j.physc.2015.03.002	journal	July 2015
Nanocalorimeter platform for in situ specific heat measurements and x-ray diffraction at low temperature Willa, K.; Diao, Z.; Campanini, D. Review of Scientific Instruments, Vol. 88, Issue 12 https://doi.org/10.1063/1.5016592	journal	December 2017
The orthorhombic crystal structure of Ru2Si3, Ru2Ge3, Os2Si3 and Os2Ge3 Poutcharovsky, D. J.; Parthé, E. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 30, Issue 11 https://doi.org/10.1107/S0567740874007825	journal	November 1974
Resistivity and magnetic-susceptibility studies in the $R_{3}$ ${Ru}_{4}$ ${Ge}_{13}$ ( R =Nd, Dy, Ho, Er, Yb, Lu, and Y) system Ghosh, K.; Ramakrishnan, S.; Chandra, Girish Physical Review B, Vol. 48, Issue 14 https://doi.org/10.1103/PhysRevB.48.10435	journal	October 1993
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Temperature and Purity Dependence of the Superconducting Critical Field, $H_{c 2}$ . III. Electron Spin and Spin-Orbit Effects Werthamer, N. R.; Helfand, E.; Hohenberg, P. C. Physical Review, Vol. 147, Issue 1 https://doi.org/10.1103/PhysRev.147.295	journal	July 1966
Direct observation of dissipative flux motion and pinning by twin boundaries in YBa_{2}Cu_{3}O_{7-δ} single crystals Kwok, W.; Welp, U.; Crabtree, G. Physical Review Letters, Vol. 64, Issue 8 https://doi.org/10.1103/PhysRevLett.64.966	journal	February 1990
Superconductivity in the A15 structure Stewart, G. R. Physica C: Superconductivity and its Applications, Vol. 514 https://doi.org/10.1016/j.physc.2015.02.013	journal	July 2015
Theory of dirty superconductors Anderson, P. W. Journal of Physics and Chemistry of Solids, Vol. 11, Issue 1-2 https://doi.org/10.1016/0022-3697(59)90036-8	journal	September 1959
Heavy-fermion systems Stewart, G. R. Reviews of Modern Physics, Vol. 56, Issue 4 https://doi.org/10.1103/RevModPhys.56.755	journal	October 1984
Possible highT c superconductivity in the Ba?La?Cu?O system Bednorz, J. G.; M�ller, K. A. Zeitschrift f�r Physik B Condensed Matter, Vol. 64, Issue 2 https://doi.org/10.1007/BF01303701	journal	June 1986
Theory of Superconductivity Bardeen, J.; Cooper, L. N.; Schrieffer, J. R. Physical Review, Vol. 108, Issue 5 https://doi.org/10.1103/PhysRev.108.1175	journal	December 1957
Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE ₄ M ₂ InGe ₄ (M = Fe, Co, Ni, Ru, Rh, Ir) and RE ₄ RhInGe ₄ Derived from Excision of Slabs in RE ₂ InGe ₂ Oliynyk, Anton O.; Stoyko, Stanislav S.; Mar, Arthur Inorganic Chemistry, Vol. 54, Issue 6 https://doi.org/10.1021/ic502955h	journal	February 2015
Demagnetizing Factors of the General Ellipsoid Osborn, J. A. Physical Review, Vol. 67, Issue 11-12 https://doi.org/10.1103/PhysRev.67.351	journal	June 1945
Consistent gaussian basis sets of double- and triple-zeta valence with polarization quality of the fifth period for solid-state calculations: Fifth Period for Solid-State Calculations Laun, Joachim; Vilela Oliveira, Daniel; Bredow, Thomas Journal of Computational Chemistry, Vol. 39, Issue 19 https://doi.org/10.1002/jcc.25195	journal	February 2018
Specific heat of ${Nb}_{3} Sn$ : The case for a second energy gap Guritanu, V.; Goldacker, W.; Bouquet, F. Physical Review B, Vol. 70, Issue 18 https://doi.org/10.1103/PhysRevB.70.184526	journal	November 2004
Heavy-fermion systems Fulde, P. Annalen der Physik, Vol. 9, Issue 11-12 https://doi.org/10.1002/1521-3889(200011)9:11/12<871::aid-andp871>3.0.co;2-s	journal	November 2000
Ab Initio Energy Landscape of GeF2: A System Featuring Lone Pair Structure Candidates Doll, Klaus; Jansen, Martin Angewandte Chemie, Vol. 123, Issue 20 https://doi.org/10.1002/ange.201008070	journal	April 2011
Mixed Valency in Yb7Co4InGe12: A Novel Intermetallic Compound Stabilized in Liquid Indium. Chondroudi, Maria; Balasubramanian, Mahalingam; Welp, Ulrich ChemInform, Vol. 38, Issue 48 https://doi.org/10.1002/chin.200748021	journal	November 2007
The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds Kanatzidis, Mercouri G.; Poettgen, Rainer; Jeitschko, Wolfgang ChemInform, Vol. 37, Issue 1 https://doi.org/10.1002/chin.200601226	journal	January 2006
Theory of Superconductivity Schrieffer, J. R.; Mansfield, John E. Physics Today, Vol. 18, Issue 5 https://doi.org/10.1063/1.3047438	journal	May 1965
Unconventional superconductivity Annett, James F. Contemporary Physics, Vol. 36, Issue 6 https://doi.org/10.1080/00107519508232300	journal	November 1995
Superfluid Density and Energy Gap-Function of Superconducting PrPt4Ge12 Maisuradze, A.; Nicklas, M.; Gumeniuk, R. arXiv https://doi.org/10.48550/arxiv.0902.1083	text	January 2009
The Challenge of Unconventional Superconductivity Norman, M. R. arXiv https://doi.org/10.48550/arxiv.1106.1213	text	January 2011
Materials Design for New Superconductors Norman, M. R. arXiv https://doi.org/10.48550/arxiv.1601.00709	text	January 2016
Tunneling measurements of the electron-phonon interaction in $\rm Ba_{1-x}K_xBiO_3$ Samuely, P.; Bobrov, N. L.; Jansen, A. G. M. arXiv https://doi.org/10.48550/arxiv.1704.00283	text	January 2017
Signatures of valence fluctuations in CeCu2Si2 under high pressure Holmes, A. T.; Jaccard, D.; Miyake, K. arXiv https://doi.org/10.48550/arxiv.cond-mat/0306054	text	January 2003

Cited By (1)

Exploration of Multi-Component Vanadium and Titanium Pnictides Using Flux Growth and Conventional High-Temperature Methods Ovchinnikov, Alexander; Bobev, Svilen Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00909	journal	January 2020

Similar Records

Anisotropic

H_{c 2}

, thermodynamic and transport measurements, and pressure dependence of

T_{c}

K_{2} {Cr}_{3} {As}_{3}

single crystals

Journal Article · Fri Jan 30 00:00:00 EST 2015 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:1497390

Kong, Tai; Bud'ko, Sergey L.; Canfield, Paul C.

Tipping the magnetic instability in paramagnetic

S r_{3} R u_{2} O_{7}

by Fe impurities [Tipping the magnetic instability in paramagnetic

S r_{3} R u_{2} O_{7}

by modest Fe substitution]

Journal Article · Fri May 19 00:00:00 EDT 2017 · Physical Review B · OSTI ID:1497390

Zhu, M.; Wang, Y.; Li, P. G.; +5 more

Evolution of magnetism in single-crystal

C a_{2} R u_{1 - x} I r_{x} O_{4} (0 \leq x \leq 0.65)

Journal Article · Fri Jul 24 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:1497390

Yuan, S. J.; Terzic, J.; Wang, J. C.; +5 more

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY

Title: Superconductivity in Y 7 R u 4 InG e 12

Citation Formats

References (59)

Cited By (1)

Linked Research (1)

Similar Records

Related Subjects

Title: Superconductivity in $Y_{7} R u_{4} InG e_{12}$