Speciation of technetium in carbonate media under helium ions and γ radiation

Journal Article · Mon Feb 25 00:00:00 EST 2019 · Radiochimica Acta

DOI:https://doi.org/10.1515/ract-2018-2939· OSTI ID:1493771

Ghalei, Mohammad; Vandenborre, Johan; Poineau, Frederic; Blain, Guillaume; Solari, Pier-Lorenzo; Rôques, Jerome; Haddad, Ferid; Fattahi, Massoud

Technetium carbonates complexes produced by chemical, electrochemical and radiolytic methods have been studied by UV-Visible, X-ray Absorption Fine Structure (XAFS) and Density Functional Theory methods. The (NH₄)₂TcCl₆ salt was dissolved in 2 M KHCO₃. The resulting purple solution was analyzed by XAFS and UV-Visible spectroscopy. The UV-Visible spectra exhibits a band centered at 515 nm. The XAFS results were consistent with the presence of polymeric species containing the [Tc₂(μ-O)₂]⁴⁺ core coordinated to carbonate ligand. Concerning the electrochemical methods, the pertechnetate anion was electrochemically reduced in concentrated carbonate solution [(CO₃^2-)=5 M and (HCO₃^-)=0.5 M]. For the radiolytic reduction, the speciation of Tc under Helium ions particle beam and γ radiation was examined by UV-Visible and XAFS spectroscopy in high concentrated carbonate media. In concentrated carbonate solutions, pertechnetate as Tc(VII), was not reduced under irradiation due to the formation of carbonate radical which is a strong oxidant. Then, the solution proposed was the addition of formate to the solution which can scavenge hydroxyl radical 10 times faster than carbonate and prevent re-oxidation of reduced technetium. The XANES and EXAFS spectroscopies, approved by theoretical methods, revealed that the final product of the radiolytic reduction of pertechnetate is in the +IV oxidation state. The final structure of the reduced product by He²⁺ radiolysis was the same as electrochemical reduction. From this complex determination and evolution vs. the dose, this study is reporting the solubility of the Tc(IV) complex.

• Research Organization: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
• Sponsoring Organization: FOREIGN
• OSTI ID: 1493771
• Journal Information: Radiochimica Acta, Vol. 107, Issue 2; ISSN 0033-8230
• Publisher: de Gruyter
• Country of Publication: United States
• Language: ENGLISH