Hydrogen bonding directed co-assembly of polyoxometalates and polymers to core–shell nanoparticles

Zhou, Jing; Hu, Jie; Li, Mu; Li, Hui; Wang, Weiyu; Liu, Yuzi; Winans, Randall E.; Li, Tao; Liu, Tianbo; Yin, Panchao

doi:10.1039/C8QM00291F

Title: Hydrogen bonding directed co-assembly of polyoxometalates and polymers to core–shell nanoparticles

Journal Article · Thu Sep 13 00:00:00 EDT 2018 · Materials Chemistry Frontiers

DOI:https://doi.org/10.1039/C8QM00291F· OSTI ID:1493752

Zhou, Jing ^[1]; Hu, Jie ^[2]; Li, Mu ^[2]; Li, Hui ^[3]; Wang, Weiyu ^[2]; Liu, Yuzi ^[4]; Winans, Randall E. ^[4]; Li, Tao ^[5]; Liu, Tianbo ^[3];

^[2]

South China University of Technology, Guangzhou (China); Univ. of Akron, Akron, OH (United States)
South China University of Technology, Guangzhou (China)
Univ. of Akron, Akron, OH (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Northern Illinois Univ., DeKalb, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Here, a general strategy has been developed here to co-assemble polyoxometalates (POMs) and polymers into core–shell hybrid nanoparticles via hydrogen bonding interaction. Due to the hydrogen bonds between the pyridine groups of poly(4-vinyl pyridine) (P4VP) and the hydrogen bonding donor groups on the POM surface, P4VP is stabilized by the POMs and dispersed as discrete hybrid core–shell nanoparticles in aqueous solution. For these thermodynamically stable nanoparticles, the P4VP cores are covered with hexagonal close-packed POMs. The size of the core–shell particles is controlled by the electrostatic repulsive interaction among the POMs. The introduction of extra salts screens the repulsive force among the POMs, thus increasing the size of the core–shell structures.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Argonne National Laboratory, Laboratory Directed Research and Development (LDRD); USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1493752

Alternate ID(s):: OSTI ID: 1472196

Journal Information:: Materials Chemistry Frontiers, Vol. 2, Issue 11; ISSN 2052-1537

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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