A Phosphonate-Functionalized Quinone Redox Flow Battery at Near-Neutral pH with Record Capacity Retention Rate

Ji, Yunlong; Goulet, Marc-Antoni; Pollack, Daniel A.; Kwabi, David G.; Jin, Shijian; De Porcellinis, Diana; Kerr, Emily F.; Gordan, Roy G.; Aziz, Michael J.

doi:10.1002/aenm.201900039

Title: A Phosphonate-Functionalized Quinone Redox Flow Battery at Near-Neutral pH with Record Capacity Retention Rate

Journal Article · Wed Feb 06 00:00:00 EST 2019 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201900039· OSTI ID:1661884

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Harvard Univ., Cambridge, MA (United States)

A highly stable phosphonate-functionalized anthraquinone is introduced as the redox-active material in a negative potential electrolyte (negolyte) for aqueous redox flow batteries operating at nearly neutral pH. Here, the design and synthesis of 2,6-DPPEAQ, (((9,10-dioxo-9,10-dihydroanthracene-2,6-diyl)bis(oxy))bis(propane-3,1-diyl))bis(phosphonic acid), which has a high solubility at pH 9 and above, is described. Chemical stability studies demonstrate high stability at both pH 9 and 12. By pairing 2,6-DPPEAQ with a potassium ferri/ferrocyanide positive electrolyte across an inexpensive, nonfluorinated permselective polymer membrane, this near-neutral quinone flow battery exhibits an open-circuit voltage of 1.0 V and a capacity fade rate of 0.00036% per cycle and 0.014% per day, which is the lowest ever reported for any flow battery in the absence of rebalancing processes. It is further demonstrated that the negolyte pH drifts upward upon atmospheric oxygen penetration but, when oxygen is excluded, oscillates reversibly between 9 and 12 during cycling. These results enhance the suitability of aqueous-soluble redox-active organics for use in large-scale energy storage, potentially enabling massive penetration of intermittent renewable electricity.

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Research Organization:: Harvard Univ., Cambridge, MA (United States). John A. Paulson School of Engineering and Applied Sciences (SEAS); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE; National Science Foundation (NSF); Innovation Fund Denmark; Massachusetts Clean Energy Technology Center

Grant/Contract Number:: AC05-76RL01830; 428977

OSTI ID:: 1661884

Alternate ID(s):: OSTI ID: 1493638

Journal Information:: Advanced Energy Materials, Vol. 9, Issue 12; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 166 works

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