“Interpenetration Isomerism” of Triptycene-Based Hydrogen-Bonded Organic Frameworks

Li, Penghao; Li, Peng; Ryder, Matthew R.; Liu, Zhichang; Stern, Charlotte L.; Farha, Omar K.; Stoddart, Fraser

doi:10.1002/anie.201811263

Title: “Interpenetration Isomerism” of Triptycene-Based Hydrogen-Bonded Organic Frameworks

Journal Article · Tue Dec 11 00:00:00 EST 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201811263· OSTI ID:1488530

Li, Penghao ^[1]; Li, Peng ^[1]; Ryder, Matthew R. ^[2]; Liu, Zhichang ^[3]; Stern, Charlotte L. ^[1]; Farha, Omar K. ^[1]; Stoddart, Fraser ^[4]

Northwestern Univ., Evanston, IL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Westlake University, Hangzhou (China)
Northwestern Univ., Evanston, IL (United States); Tianjin University (China); University of New South Wales, Sydney (Australia)

We describe an example of “interpenetration isomerism” in three-dimensional hydrogen-bonded organic frameworks. By exploiting the crystallization conditions for a peripherally extended triptycene H6PET, we can modulate the interpenetration of the assembled frameworks, yielding a two-fold interpenetrated structure PETHOF-1 and a five-fold interpenetrated structure PETHOF-2 as interpenetration isomers. In PETHOF-1, two individual nets are related by inversion symmetry and form an interwoven topology with a large guest-accessible volume of about 80 %. In PETHOF-2, five individual nets are related by translational symmetry and are stacked in an alternating fashion. The activated materials show permanent porosity with Brunauer-Emmett-Teller surface areas exceeding 1100 m² g^-1. Synthetic control over the framework interpenetration could serve as a new strategy to construct complex supramolecular architectures from simple organic building blocks.

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Research Organization:: University of Notre Dame, IN (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: NA0003763; AC02-05CH11231; AC05-00OR22725

OSTI ID:: 1488530

Alternate ID(s):: OSTI ID: 1492749; OSTI ID: 1513397

Journal Information:: Angewandte Chemie (International Edition), Vol. 58, Issue 6; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 75 works

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