Nature of Hydrogen Adsorption on Platinum in the Aqueous Phase

Yang, Guoju; Akhade, Sneha A.; Chen, Xi; Liu, Yue; Lee, Mal -Soon; Glezakou, Vassiliki -Alexandra; Rousseau, Roger; Lercher, Johannes A.

doi:10.1002/anie.201813958

Title: Nature of Hydrogen Adsorption on Platinum in the Aqueous Phase

Journal Article · Mon Dec 17 00:00:00 EST 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201813958· OSTI ID:1487149

Yang, Guoju ^[1];

^[2]; Chen, Xi ^[1];

^[1];

^[2];

^[1]

Technische Univ. Munchen, Garching bei Munchen (Germany)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Cosmic microwave background (CMB) lensing is an integrated effect whose kernel is greater than half the peak value in the range 1 < z < 5 . Measuring this effect offers a powerful tool to probe the large-scale structure of the Universe at high redshifts. With the increasing precision of ongoing CMB surveys, other statistics than the lensing power spectrum, in particular the lensing bispectrum, will be measured at high statistical significance. This will provide ways to improve the constraints on cosmological models and lift degeneracies. Following up on an earlier paper, we test analytical predictions of the CMB lensing bispectrum against full-sky lensing simulations, and we discuss their validity and limitation in detail. The tree-level prediction of perturbation theory agrees with the simulation only up to ℓ ~ 200 , but the one-loop order allows capturing the simulation results up to ℓ ~ 600 . We also show that analytical predictions based on fitting formulas for the matter bispectrum agree reasonably well with simulation results, although the precision of the agreement depends on the configurations and scales considered. For instance, the agreement is at the 10% level for the equilateral configuration at multipoles up to ℓ ~ 2000 , but the difference in the squeezed limit increases to more than a factor of 2 at ℓ ~ 2000 . This discrepancy appears to come from limitations in the fitting formula of the matter bispectrum. We also find that the analytical prediction for the post-Born correction to the bispectrum is in good agreement with the simulation. We conclude by discussing the bispectrum prediction in some theories of modified gravity.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-76RL01830; AC02-05CH11231

OSTI ID:: 1487149

Alternate ID(s):: OSTI ID: 1492743; OSTI ID: 1530437

Report Number(s):: PNNL-SA-134839

Journal Information:: Angewandte Chemie (International Edition), Vol. 58, Issue 11; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 62 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
hydrogen
adsorption
water phase
platinum
hydrogen binding energy

Title: Nature of Hydrogen Adsorption on Platinum in the Aqueous Phase

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