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Title: Chemically fueled covalent crosslinking of polymer materials

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/C8CC09823A· OSTI ID:1596011

Non-equilibrium covalently crosslinked hydrogels are synthesized using carbodiimide fueled coupling of carboxylic acids to anhydrides which eventually dissipate by hydrolysis.

Research Organization:
Miami Univ., Oxford, OH (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0018645
OSTI ID:
1596011
Alternate ID(s):
OSTI ID: 1492742
Journal Information:
ChemComm, Vol. 55, Issue 14; Related Information: Raw experimental data: http://hdl.handle.net/2374.MIA/6342; ISSN 1359-7345
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 41 works
Citation information provided by
Web of Science

References (28)

Self-Assembly at All Scales journal March 2002
Transient self-assembly of molecular nanostructures driven by chemical fuels journal August 2017
Dissipative out-of-equilibrium assembly of man-made supramolecular materials journal January 2017
Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel journal May 2010
Transient assembly of active materials fueled by a chemical reaction journal September 2015
Fuel-Controlled Reassembly of Metal–Organic Architectures journal December 2015
An autonomous chemically fuelled small-molecule motor journal June 2016
Supramolecular pathway selection of perylenediimides mediated by chemical fuels journal January 2016
Fuel-Mediated Transient Clustering of Colloidal Building Blocks journal July 2017
Non-equilibrium dissipative supramolecular materials with a tunable lifetime journal July 2017
Self-selection of dissipative assemblies driven by primitive chemical reaction networks journal May 2018
Dissipative assemblies that inhibit their deactivation journal January 2018
Dissipative Assembly of Aqueous Carboxylic Acid Anhydrides Fueled by Carbodiimides journal August 2017
50th Anniversary Perspective : RAFT Polymerization—A User Guide journal September 2017
The pyridine catalysed hydrolysis of carboxylic anhydrides journal January 1961
Rheological Study and Molecular Dynamics Simulation of Biopolymer Blend Thermogels of Tunable Strength journal September 2016
Strength and sorption capacity modulation of carboxymethylcellulose hydrogels in presence of ester-bonded gemini surfactants journal July 2017
Thermoreversible Hyaluronic Acid-PNIPAAm Hydrogel Systems for 3D Stem Cell Culture journal May 2018
Novel Mussel-Inspired Injectable Self-Healing Hydrogel with Anti-Biofouling Property journal January 2015
Rheological Characterization of in Situ Crosslinkable Hydrogels Formulated from Oxidized Dextran and N -Carboxyethyl Chitosan journal April 2007
Stochastic pumping of non-equilibrium steady-states: how molecules adapt to a fluctuating environment journal January 2018
A new approach for handling and transferring of thin semiconductor materials journal January 2003
Peptide Nanofibers with Dynamic Instability through Nonequilibrium Biocatalytic Assembly journal October 2013
Biocatalytic Feedback-Driven Temporal Programming of Self-Regulating Peptide Hydrogels journal August 2015
Sucrose-fueled, energy dissipative, transient formation of molecular hydrogels mediated by yeast activity journal January 2016
Kinetically Controlled Lifetimes in Redox-Responsive Transient Supramolecular Hydrogels journal February 2018
Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel journal May 2010
Biocatalytic Feedback‐Driven Temporal Programming of Self‐Regulating Peptide Hydrogels journal August 2015

Cited By (3)

Hydrogels with Preprogrammable Lifetime via UV‐Induced Polymerization and Degradation journal January 2020
Temporally‐Programmed Transient Supramolecular Gels journal June 2019
Chemically Fuelled Self‐Regulating Gel‐to‐Gel Transition journal October 2019

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