Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol
Abstract
A low-temperature CH 3OH synthesis was achieved at 120–170 °C using tertiary amine and alcohol in the presence of a Cu/ZnO/Al 2O 3catalyst by CO 2hydrogenation.
- Authors:
-
[1];
[2];
[1]
- Energy Processes and Materials Division; Pacific Northwest National Laboratory; Richland; USA
- Environmental Molecular Sciences Laboratory; Pacific Northwest National Laboratory; Richland; USA
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1492552
- Report Number(s):
- PNNL-SA-133245
Journal ID: ISSN 2044-4753; CSTAGD
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Journal Article
- Journal Name:
- Catalysis Science and Technology
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 19; Journal ID: ISSN 2044-4753
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Kothandaraman, Jotheeswari, Dagle, Robert A., Dagle, Vanessa Labarbier, Davidson, Stephen D., Walter, Eric D., Burton, Sarah D., Hoyt, David W., and Heldebrant, David J. Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol. United States: N. p., 2018.
Web. doi:10.1039/C8CY00997J.
Kothandaraman, Jotheeswari, Dagle, Robert A., Dagle, Vanessa Labarbier, Davidson, Stephen D., Walter, Eric D., Burton, Sarah D., Hoyt, David W., & Heldebrant, David J. Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol. United States. doi:10.1039/C8CY00997J.
Kothandaraman, Jotheeswari, Dagle, Robert A., Dagle, Vanessa Labarbier, Davidson, Stephen D., Walter, Eric D., Burton, Sarah D., Hoyt, David W., and Heldebrant, David J. Mon .
"Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol". United States. doi:10.1039/C8CY00997J.
@article{osti_1492552,
title = {Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol},
author = {Kothandaraman, Jotheeswari and Dagle, Robert A. and Dagle, Vanessa Labarbier and Davidson, Stephen D. and Walter, Eric D. and Burton, Sarah D. and Hoyt, David W. and Heldebrant, David J.},
abstractNote = {A low-temperature CH3OH synthesis was achieved at 120–170 °C using tertiary amine and alcohol in the presence of a Cu/ZnO/Al2O3catalyst by CO2hydrogenation.},
doi = {10.1039/C8CY00997J},
journal = {Catalysis Science and Technology},
issn = {2044-4753},
number = 19,
volume = 8,
place = {United States},
year = {2018},
month = {1}
}
DOI: 10.1039/C8CY00997J
Other availability
Find in Google Scholar
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Methanol synthesis from CO2 and H2 in multi-tubular fixed-bed reactor and multi-tubular reactor filled with monoliths
journal, November 2014
- Arab, Sofiane; Commenge, Jean-Marc; Portha, Jean-François
- Chemical Engineering Research and Design, Vol. 92, Issue 11
Ruthenium complex catalysed hydrogenation of carbon dioxide to carbon monoxide, methanol and methane
journal, January 1993
- Tominaga, Ken-ichi; Sasaki, Yoshiyuki; Kawai, Motomitsu
- Journal of the Chemical Society, Chemical Communications, Issue 7
Conversion of CO 2 from Air into Methanol Using a Polyamine and a Homogeneous Ruthenium Catalyst
journal, January 2016
- Kothandaraman, Jotheeswari; Goeppert, Alain; Czaun, Miklos
- Journal of the American Chemical Society, Vol. 138, Issue 3
Opportunities and prospects in the chemical recycling of carbon dioxide to fuels
journal, November 2009
- Centi, Gabriele; Perathoner, Siglinda
- Catalysis Today, Vol. 148, Issue 3-4
Deactivation of Cu/ZnO/Al 2 O 3 Methanol Synthesis Catalyst by Sintering
journal, October 1999
- Sun, James T.; Metcalfe, Ian S.; Sahibzada, Mortaza
- Industrial & Engineering Chemistry Research, Vol. 38, Issue 10
Chemical Technologies for Exploiting and Recycling Carbon Dioxide into the Value Chain
journal, August 2011
- Peters, Martina; Köhler, Burkhard; Kuckshinrichs, Wilhelm
- ChemSusChem, Vol. 4, Issue 9
Catalytic reduction of CO 2 by H 2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities
journal, January 2016
- Porosoff, Marc D.; Yan, Binhang; Chen, Jingguang G.
- Energy & Environmental Science, Vol. 9, Issue 1
Cascade Catalysis for the Homogeneous Hydrogenation of CO 2 to Methanol
journal, November 2011
- Huff, Chelsea A.; Sanford, Melanie S.
- Journal of the American Chemical Society, Vol. 133, Issue 45
Hydrogenation of carbon dioxide to methanol using a homogeneous ruthenium–Triphos catalyst: from mechanistic investigations to multiphase catalysis
journal, January 2015
- Wesselbaum, Sebastian; Moha, Verena; Meuresch, Markus
- Chemical Science, Vol. 6, Issue 1
Hydrogenation of Carbon Dioxide to Methanol by Using a Homogeneous Ruthenium-Phosphine Catalyst
journal, June 2012
- Wesselbaum, Sebastian; vom Stein, Thorsten; Klankermayer, Jürgen
- Angewandte Chemie International Edition, Vol. 51, Issue 30
Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO 2 to Methanol
journal, January 2015
- Rezayee, Nomaan M.; Huff, Chelsea A.; Sanford, Melanie S.
- Journal of the American Chemical Society, Vol. 137, Issue 3
Recent Advances in CO 2 Capture and Utilization
journal, November 2008
- Yu, Kai Man Kerry; Curcic, Igor; Gabriel, Joseph
- ChemSusChem, Vol. 1, Issue 11
Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts
journal, March 2017
- Kattel, Shyam; Ramírez, Pedro J.; Chen, Jingguang G.
- Science, Vol. 355, Issue 6331
Anhydrous tertiary alkanolamines as hybrid chemical and physical CO 2 capture reagents with pressure-swing regeneration
journal, January 2011
- Rainbolt, James E.; Koech, Phillip K.; Yonker, Clement R.
- Energy Environ. Sci., Vol. 4, Issue 2
Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron( ii ) catalyst
journal, January 2017
- Ribeiro, A. P. C.; Martins, L. M. D. R. S.; Pombeiro, A. J. L.
- Green Chemistry, Vol. 19, Issue 20
Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing
journal, June 2006
- Song, Chunshan
- Catalysis Today, Vol. 115, Issue 1-4
CO2 absorption by aqueous NH3 solutions: speciation of ammonium carbamate, bicarbonate and carbonate by a 13C NMR study
journal, January 2006
- Mani, Fabrizio; Peruzzini, Maurizio; Stoppioni, Piero
- Green Chemistry, Vol. 8, Issue 11
CO2 hydrogenation over metal/zirconia catalysts
journal, January 1999
- Wambach, Jörg; Baiker, Alfons; Wokaun, Alexander
- Physical Chemistry Chemical Physics, Vol. 1, Issue 22
Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment
journal, December 2017
- Artz, Jens; Müller, Thomas E.; Thenert, Katharina
- Chemical Reviews, Vol. 118, Issue 2
Water-Lean Solvents for Post-Combustion CO 2 Capture: Fundamentals, Uncertainties, Opportunities, and Outlook
journal, May 2017
- Heldebrant, David J.; Koech, Phillip K.; Glezakou, Vassiliki-Alexandra
- Chemical Reviews, Vol. 117, Issue 14
Transformation of Carbon Dioxide
journal, June 2007
- Sakakura, Toshiyasu; Choi, Jun-Chul; Yasuda, Hiroyuki
- Chemical Reviews, Vol. 107, Issue 6
Anthropogenic Chemical Carbon Cycle for a Sustainable Future
journal, August 2011
- Olah, George A.; Prakash, G. K. Surya; Goeppert, Alain
- Journal of the American Chemical Society, Vol. 133, Issue 33
In Situ Nuclear Magnetic Resonance Mechanistic Studies of Carbon Dioxide Reactions with Liquid Amines in Aqueous Systems: New Insights on Carbon Capture Reaction Pathways
journal, July 2015
- Kortunov, Pavel V.; Siskin, Michael; Baugh, Lisa Saunders
- Energy & Fuels, Vol. 29, Issue 9
Homogeneous Hydrogenation of CO 2 to Methyl Formate Utilizing Switchable Ionic Liquids
journal, August 2014
- Yadav, Mahendra; Linehan, John C.; Karkamkar, Abhijeet J.
- Inorganic Chemistry, Vol. 53, Issue 18
Using carbon dioxide as a building block in organic synthesis
journal, January 2015
- Liu, Qiang; Wu, Lipeng; Jackstell, Ralf
- Nature Communications, Vol. 6, Issue 1
Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons
journal, January 2009
- Olah, George A.; Goeppert, Alain; Prakash, G. K. Surya
- The Journal of Organic Chemistry, Vol. 74, Issue 2, p. 487-498
Low-temperature methanol synthesis from carbon dioxide and hydrogen via formic ester
journal, April 1999
- Fan, Li; Sakaiya, Yoshitada; Fujimoto, Kaoru
- Applied Catalysis A: General, Vol. 180, Issue 1-2
Quantification of Zinc Atoms in a Surface Alloy on Copper in an Industrial-Type Methanol Synthesis Catalyst
journal, April 2014
- Kuld, Sebastian; Conradsen, Christian; Moses, Poul Georg
- Angewandte Chemie International Edition, Vol. 53, Issue 23
The promoting effect of alcohols in a new process of low-temperature synthesis of methanol from CO/CO2/H2
journal, January 2002
- Zeng, Jian-Qing; Tsubaki, Noritatsu; Fujimoto, Kaoru
- Fuel, Vol. 81, Issue 1
Pd/ZnO catalysts for direct CO2 hydrogenation to methanol
journal, November 2016
- Bahruji, Hasliza; Bowker, Michael; Hutchings, Graham
- Journal of Catalysis, Vol. 343
Alcohol promoted methanol synthesis enhanced by adsorption of water and dual catalysts
journal, March 2018
- Nieminen, Harri; Givirovskiy, Georgy; Laari, Arto
- Journal of CO2 Utilization, Vol. 24
Low-Temperature CO 2 Hydrogenation to Liquid Products via a Heterogeneous Cascade Catalytic System
journal, February 2015
- Chen, Yuan; Choi, Saemin; Thompson, Levi T.
- ACS Catalysis, Vol. 5, Issue 3
High yield production of formate by hydrogenating CO 2 derived ammonium carbamate/carbonate at room temperature
journal, January 2015
- Su, Ji; Lu, Mi; Lin, Hongfei
- Green Chemistry, Vol. 17, Issue 5
Manganese-Catalyzed Sequential Hydrogenation of CO 2 to Methanol via Formamide
journal, August 2017
- Kar, Sayan; Goeppert, Alain; Kothandaraman, Jotheeswari
- ACS Catalysis, Vol. 7, Issue 9
Electron Spectroscopic Studies of CH 3 OH Chemisorption on Cu 2 O and ZnO Single-Crystal Surfaces: Methoxide Bonding and Reactivity Related to Methanol Synthesis
journal, February 1998
- Jones, Paul M.; May, Jennifer A.; Reitz, J. Brad
- Journal of the American Chemical Society, Vol. 120, Issue 7
Harnessing renewable energy with CO 2 for the chemical value chain: challenges and opportunities for catalysis
journal, February 2016
- Klankermayer, Jürgen; Leitner, Walter
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2061
Spontaneous Growth of ZnCO 3 Nanowires on ZnO Nanostructures in Normal Ambient Environment: Unstable ZnO Nanostructures
journal, January 2010
- Pan, Zhengwei; Tao, Jing; Zhu, Yimei
- Chemistry of Materials, Vol. 22, Issue 1
Synthesis of methanol and dimethyl ether from syngas over Pd/ZnO/Al2O3 catalysts
journal, January 2012
- Lebarbier, Vanessa M.; Dagle, Robert A.; Kovarik, Libor
- Catalysis Science & Technology, Vol. 2, Issue 10
A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2
journal, September 2011
- Das Neves Gomes, Christophe; Jacquet, Olivier; Villiers, Claude
- Angewandte Chemie International Edition, Vol. 51, Issue 1
Homogeneous Hydrogenation of Carbon Dioxide to Methanol Catalyzed by Ruthenium Cluster Anions in the Presence of Halide Anions
journal, October 1995
- Tominaga, Ken-ichi; Sasaki, Yoshiyuki; Watanabe, Taiki
- Bulletin of the Chemical Society of Japan, Vol. 68, Issue 10
Homogeneous Hydrogenation of Carbon Dioxide
journal, March 1995
- Jessop, Philip G.; Ikariya, Takao.; Noyori, Ryoji.
- Chemical Reviews, Vol. 95, Issue 2
In situ IR studies on the mechanism of methanol synthesis from CO/H2 and CO2/H2 over Cu-ZnO-Al2O3 catalyst
journal, June 2010
- Wang, Xiaojuan; Zhang, Haipeng; Li, Wei
- Korean Journal of Chemical Engineering, Vol. 27, Issue 4
A New Method of Low-Temperature Methanol Synthesis
journal, January 2001
- Tsubaki, Noritatsu; Ito, Motoaki; Fujimoto, Kaoru
- Journal of Catalysis, Vol. 197, Issue 1
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012
- Behrens, M.; Studt, F.; Kasatkin, I.
- Science, Vol. 336, Issue 6083, p. 893-897
The steps of activating a prospective CO 2 hydrogenation catalyst with combined CO 2 capture and reduction
journal, January 2016
- Lao, D. B.; Galan, B. R.; Linehan, J. C.
- Green Chemistry, Vol. 18, Issue 18
A New Low-Temperature Synthesis Route of Methanol: Catalytic Effect of the Alcoholic Solvent
journal, January 2002
- Zeng, Jianqing; Fujimoto, Kaoru; Tsubaki, Noritatsu
- Energy & Fuels, Vol. 16, Issue 1
Methanol from CO 2 by Organo-Cocatalysis: CO 2 Capture and Hydrogenation in One Process Step
journal, November 2014
- Reller, Christian; Pöge, Matthias; Lißner, Andreas
- Environmental Science & Technology, Vol. 48, Issue 24
Methanol synthesis from CO2 and H2 over Pd/ZnO/Al2O3: Catalyst structure dependence of methanol selectivity
journal, March 2016
- Xu, Jinghua; Su, Xiong; Liu, Xiaoyan
- Applied Catalysis A: General, Vol. 514
CO 2 capture by amines in aqueous media and its subsequent conversion to formate with reusable ruthenium and iron catalysts
journal, January 2016
- Kothandaraman, Jotheeswari; Goeppert, Alain; Czaun, Miklos
- Green Chemistry, Vol. 18, Issue 21
A Study of Methyl Formate Production from Carbon Dioxide Hydrogenation in Methanol over a Copper Zinc Oxide Catalyst
journal, November 2010
- Kerry Yu, K. M.; Tsang, Shik Chi
- Catalysis Letters, Vol. 141, Issue 2
Ethyl formate hydrogenolysis over Mo2C-based catalysts: Towards low temperature CO and CO2 hydrogenation to methanol
journal, January 2016
- Chen, Yuan; Choi, Saemin; Thompson, Levi T.
- Catalysis Today, Vol. 259
On the Synergetic Catalytic Effect in Heterogeneous Nanocomposite Catalysts
journal, November 2012
- Shi, Jianlin
- Chemical Reviews, Vol. 113, Issue 3
Catalysis for CO2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries
journal, January 2013
- Centi, Gabriele; Quadrelli, Elsje Alessandra; Perathoner, Siglinda
- Energy & Environmental Science, Vol. 6, Issue 6
Kinetics and Mechanism of Carbamate Formation from CO 2 (aq), Carbonate Species, and Monoethanolamine in Aqueous Solution
journal, April 2009
- McCann, Nichola; Phan, Duong; Wang, Xiaoguang
- The Journal of Physical Chemistry A, Vol. 113, Issue 17