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Title: Decorating β"-alumina solid-state electrolytes with micron Pb spherical particles for improving Na wettability at lower temperatures

Abstract

Na wetting in a sunny-side-up shape is observed on a β"-alumina surface decorated with micron-sized lead spherical particles.

Authors:
 [1];  [1];  [1];  [1];  [2]; ORCiD logo [3];  [4];  [1]; ORCiD logo [1]
  1. Electrochemical Materials and Systems Group; Pacific Northwest National Laboratory; Richland; USA
  2. Materials Science Group; Pacific Northwest National Laboratory; Richland; USA
  3. Interfacial Sci's & Simulation Group; Pacific Northwest National Laboratory; Richland; USA
  4. Materials Research Division; Research Institute of Industrial Science & Technology; Pohang; South Korea
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE Office of Electricity Delivery and Energy Reliability (OE)
OSTI Identifier:
1492550
Report Number(s):
PNNL-SA-135511
Journal ID: ISSN 2050-7488; JMCAET
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 6; Journal Issue: 40; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Chang, Hee-Jung, Lu, Xiaochuan, Bonnett, Jeffery F., Canfield, Nathan L., Han, Keesung, Engelhard, Mark H., Jung, Keeyoung, Sprenkle, Vincent L., and Li, Guosheng. Decorating β"-alumina solid-state electrolytes with micron Pb spherical particles for improving Na wettability at lower temperatures. United States: N. p., 2018. Web. doi:10.1039/C8TA06745G.
Chang, Hee-Jung, Lu, Xiaochuan, Bonnett, Jeffery F., Canfield, Nathan L., Han, Keesung, Engelhard, Mark H., Jung, Keeyoung, Sprenkle, Vincent L., & Li, Guosheng. Decorating β"-alumina solid-state electrolytes with micron Pb spherical particles for improving Na wettability at lower temperatures. United States. doi:10.1039/C8TA06745G.
Chang, Hee-Jung, Lu, Xiaochuan, Bonnett, Jeffery F., Canfield, Nathan L., Han, Keesung, Engelhard, Mark H., Jung, Keeyoung, Sprenkle, Vincent L., and Li, Guosheng. Mon . "Decorating β"-alumina solid-state electrolytes with micron Pb spherical particles for improving Na wettability at lower temperatures". United States. doi:10.1039/C8TA06745G.
@article{osti_1492550,
title = {Decorating β"-alumina solid-state electrolytes with micron Pb spherical particles for improving Na wettability at lower temperatures},
author = {Chang, Hee-Jung and Lu, Xiaochuan and Bonnett, Jeffery F. and Canfield, Nathan L. and Han, Keesung and Engelhard, Mark H. and Jung, Keeyoung and Sprenkle, Vincent L. and Li, Guosheng},
abstractNote = {Na wetting in a sunny-side-up shape is observed on a β"-alumina surface decorated with micron-sized lead spherical particles.},
doi = {10.1039/C8TA06745G},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 40,
volume = 6,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

Contact Angles on Heterogeneous Surfaces:  A New Look at Cassie's and Wenzel's Laws
journal, November 1998

  • Swain, Peter S.; Lipowsky, Reinhard
  • Langmuir, Vol. 14, Issue 23
  • DOI: 10.1021/la980602k

Wetting of sodium on β″-Al2O3/YSZ composites for low temperature planar sodium-metal halide batteries
journal, April 2013


Young-Dupre Revisited
journal, September 1995


Resistance Of Solid Surfaces To Wetting By Water
journal, August 1936

  • Wenzel, Robert N.
  • Industrial & Engineering Chemistry, Vol. 28, Issue 8, p. 988-994
  • DOI: 10.1021/ie50320a024

Development of intermediate temperature sodium nickel chloride rechargeable batteries using conventional polymer sealing technologies
journal, April 2017


Sodium-beta alumina batteries: Status and challenges
journal, September 2010


Imbibition by polygonal spreading on microdecorated surfaces
journal, August 2007

  • Courbin, Laurent; Denieul, Etienne; Dressaire, Emilie
  • Nature Materials, Vol. 6, Issue 9
  • DOI: 10.1038/nmat1978

Nucleation scenarios for wetting transition on textured surfaces: The effect of contact angle hysteresis
journal, November 2006


High temperature sodium batteries: status, challenges and future trends
journal, January 2013

  • Hueso, Karina B.; Armand, Michel; Rojo, Teófilo
  • Energy & Environmental Science, Vol. 6, Issue 3
  • DOI: 10.1039/c3ee24086j

Electrochemical Energy Storage for Green Grid
journal, May 2011

  • Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
  • Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
  • DOI: 10.1021/cr100290v

Liquid metals. Part I. The surface tension of liquid sodium : the vertical-plate technique
journal, January 1954

  • Addison, C. C.; Kerridge, D. H.; Lewis, J.
  • Journal of the Chemical Society (Resumed)
  • DOI: 10.1039/jr9540002861

Wetting transitions on textured hydrophilic surfaces
journal, April 2008


Improved cycling behavior of ZEBRA battery operated at intermediate temperature of 175 °C
journal, March 2014


The sodium/nickel chloride (ZEBRA) battery
journal, November 2001


Wetting characteristics of sodium on ??-alumina and on nasicon
journal, March 1982

  • Viswanathan, L.; Virkar, A. V.
  • Journal of Materials Science, Vol. 17, Issue 3
  • DOI: 10.1007/BF00540372

Low-cost shape-control synthesis of porous carbon film on β″-alumina ceramics for Na-based battery application
journal, December 2012


Challenges and perspectives on high and intermediate-temperature sodium batteries
journal, June 2017


An Advanced Na-FeCl 2 ZEBRA Battery for Stationary Energy Storage Application
journal, April 2015

  • Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y.
  • Advanced Energy Materials, Vol. 5, Issue 12
  • DOI: 10.1002/aenm.201500357

Cell degradation of a Na–NiCl2 (ZEBRA) battery
journal, January 2013

  • Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y.
  • Journal of Materials Chemistry A, Vol. 1, Issue 47
  • DOI: 10.1039/c3ta13644b

Unraveling the Decomposition Process of Lead(II) Acetate: Anhydrous Polymorphs, Hydrates, and Byproducts and Room Temperature Phosphorescence
journal, August 2016

  • Martínez-Casado, Francisco J.; Ramos-Riesco, Miguel; Rodríguez-Cheda, José A.
  • Inorganic Chemistry, Vol. 55, Issue 17
  • DOI: 10.1021/acs.inorgchem.6b01116

X-ray photoelectron spectra of lead oxides
journal, November 1973

  • Kim, K. S.; O'Leary, T. J.; Winograd, Nicholas.
  • Analytical Chemistry, Vol. 45, Issue 13
  • DOI: 10.1021/ac60335a009

Liquid Metal Batteries: Past, Present, and Future
journal, November 2012

  • Kim, Hojong; Boysen, Dane A.; Newhouse, Jocelyn M.
  • Chemical Reviews, Vol. 113, Issue 3
  • DOI: 10.1021/cr300205k

Water Wetting Transition Parameters of Perfluorinated Substrates with Periodically Distributed Flat-Top Microscale Obstacles
journal, February 2007

  • Barbieri, Laura; Wagner, Estelle; Hoffmann, Patrik
  • Langmuir, Vol. 23, Issue 4
  • DOI: 10.1021/la0617964

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


Sodium-Metal Halide and Sodium-Air Batteries
journal, June 2014


A review and probabilistic model of lifecycle costs of stationary batteries in multiple applications
journal, September 2013

  • Battke, Benedikt; Schmidt, Tobias S.; Grosspietsch, David
  • Renewable and Sustainable Energy Reviews, Vol. 25
  • DOI: 10.1016/j.rser.2013.04.023

X-ray absorption measurements on nickel cathode of sodium-beta alumina batteries: Fe–Ni–Cl chemical associations
journal, February 2014


Surface Tension of Sodium
journal, May 1929


Use of the Term ‘Young's Equation’ for Contact Angles
journal, October 1957


Wetting transitions on rough surfaces
journal, November 2004


Advanced intermediate temperature sodium–nickel chloride batteries with ultra-high energy density
journal, February 2016

  • Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10683

Model for Contact Angles and Hysteresis on Rough and Ultraphobic Surfaces
journal, October 2002


The effects of temperature on the electrochemical performance of sodium–nickel chloride batteries
journal, October 2012


Research Development on Sodium-Ion Batteries
journal, October 2014

  • Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500192f

Non-isothermal kinetic and thermodynamic study of the decomposition of lead acetate trihydrate
journal, May 1994