Molecularly Mixed Composite Membranes for Advanced Separation Processes

Zhu, Guanghui; Zhang, Fengyi; Rivera, Matthew P.; Hu, Xunxiang; Zhang, Guoyan; Jones, Christopher W.; Lively, Ryan P.

doi:10.1002/ange.201811341

Title: Molecularly Mixed Composite Membranes for Advanced Separation Processes

Journal Article · Fri Jan 25 00:00:00 EST 2019 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201811341· OSTI ID:1492098

Zhu, Guanghui ^[1]; Zhang, Fengyi ^[1]; Rivera, Matthew P. ^[1]; Hu, Xunxiang ^[2]; Zhang, Guoyan ^[1]; Jones, Christopher W. ^[1];

^[1]

School of Chemical &, Biomolecular Engineering Georgia Institute of Technology 311 Ferst Drive NW Atlanta GA 30332 USA
Materials Science and Technology Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA

Abstract Porous organic cages (POCs) are individual soluble, porous molecules. When fabricated into mixed‐matrix membranes (MMMs), the soluble POC molecules have the potential to exhibit intimate molecular‐level mixing with the polymer matrix. POCs have only recently been incorporated into mixed matrix membrane materials, but this process has not yet resulted in significant improvements of membrane performance. Now, vertex‐functionalized amorphous scrambled porous organic cages (ASPOCs) have been utilized as membrane performance enhancers and the amorphous ASPOC mixtures are observed to distribute throughout the matrix without any indication of particle formation or agglomeration, creating unique, molecularly mixed composite membranes. Overall, the molecularly mixed composite membrane provide significant increases in both membrane permeability and selectivity, offering new avenues for creation of membranes with unique properties in industrially relevant separations.

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Sponsoring Organization:: USDOE

OSTI ID:: 1492098

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 131 Journal Issue: 9; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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