From Lead Halide Perovskites to Lead‐Free Metal Halide Perovskites and Perovskite Derivatives
Abstract
Abstract Despite the exciting progress on power conversion efficiencies, the commercialization of the emerging lead (Pb) halide perovskite solar cell technology still faces significant challenges, one of which is the inclusion of toxic Pb. Searching for Pb‐free perovskite solar cell absorbers is currently an attractive research direction. The approaches used for and the consequences of Pb replacement are reviewed herein. Reviews on the theoretical understanding of the electronic, optical, and defect properties of Pb and Pb‐free halide perovskites and perovskite derivatives are provided, as well as the experimental results available in the literature. The theoretical understanding explains well why Pb halide perovskites exhibit superior photovoltaic properties, but Pb‐free perovskites and perovskite derivatives do not.
- Authors:
-
- Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology Wuhan 430074 China
- Department of Physics and Astronomy and Wright Center for Photovoltaic Innovation and Commercialization The University of Toledo Toledo OH 43607 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1492092
- Grant/Contract Number:
- DE‐EE0006712
- Resource Type:
- Journal Article: Publisher's Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Name: Advanced Materials Journal Volume: 31 Journal Issue: 47; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Xiao, Zewen, Song, Zhaoning, and Yan, Yanfa. From Lead Halide Perovskites to Lead‐Free Metal Halide Perovskites and Perovskite Derivatives. Germany: N. p., 2019.
Web. doi:10.1002/adma.201803792.
Xiao, Zewen, Song, Zhaoning, & Yan, Yanfa. From Lead Halide Perovskites to Lead‐Free Metal Halide Perovskites and Perovskite Derivatives. Germany. https://doi.org/10.1002/adma.201803792
Xiao, Zewen, Song, Zhaoning, and Yan, Yanfa. 2019.
"From Lead Halide Perovskites to Lead‐Free Metal Halide Perovskites and Perovskite Derivatives". Germany. https://doi.org/10.1002/adma.201803792.
@article{osti_1492092,
title = {From Lead Halide Perovskites to Lead‐Free Metal Halide Perovskites and Perovskite Derivatives},
author = {Xiao, Zewen and Song, Zhaoning and Yan, Yanfa},
abstractNote = {Abstract Despite the exciting progress on power conversion efficiencies, the commercialization of the emerging lead (Pb) halide perovskite solar cell technology still faces significant challenges, one of which is the inclusion of toxic Pb. Searching for Pb‐free perovskite solar cell absorbers is currently an attractive research direction. The approaches used for and the consequences of Pb replacement are reviewed herein. Reviews on the theoretical understanding of the electronic, optical, and defect properties of Pb and Pb‐free halide perovskites and perovskite derivatives are provided, as well as the experimental results available in the literature. The theoretical understanding explains well why Pb halide perovskites exhibit superior photovoltaic properties, but Pb‐free perovskites and perovskite derivatives do not.},
doi = {10.1002/adma.201803792},
url = {https://www.osti.gov/biblio/1492092},
journal = {Advanced Materials},
issn = {0935-9648},
number = 47,
volume = 31,
place = {Germany},
year = {Thu Jan 24 00:00:00 EST 2019},
month = {Thu Jan 24 00:00:00 EST 2019}
}
Web of Science
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