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Title: Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation

Abstract

1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene is an effective silyl transfer reagent towards the oxygen of nitrate coordinated to Cr(iii) in a pincer complex.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Indiana University; Department of Chemistry; Bloomington; USA
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
NSFUNIVERSITY
OSTI Identifier:
1491899
Resource Type:
Journal Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 10; Journal Issue: 2; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Seo, Junghee, Cabelof, Alyssa C., Chen, Chun-Hsing, and Caulton, Kenneth G. Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation. United States: N. p., 2019. Web. doi:10.1039/C8SC02979B.
Seo, Junghee, Cabelof, Alyssa C., Chen, Chun-Hsing, & Caulton, Kenneth G. Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation. United States. doi:10.1039/C8SC02979B.
Seo, Junghee, Cabelof, Alyssa C., Chen, Chun-Hsing, and Caulton, Kenneth G. Tue . "Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation". United States. doi:10.1039/C8SC02979B.
@article{osti_1491899,
title = {Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation},
author = {Seo, Junghee and Cabelof, Alyssa C. and Chen, Chun-Hsing and Caulton, Kenneth G.},
abstractNote = {1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene is an effective silyl transfer reagent towards the oxygen of nitrate coordinated to Cr(iii) in a pincer complex.},
doi = {10.1039/C8SC02979B},
journal = {Chemical Science},
issn = {2041-6520},
number = 2,
volume = 10,
place = {United States},
year = {2019},
month = {1}
}