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Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/C8CC04565H· OSTI ID:1491885
 [1];  [1];  [1];  [1]
  1. Department of Chemistry, Texas A&M University; College Station; USA
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Synthesis, magnetic, and theoretical studies of a new family of mononuclear lanthanide complexes exhibiting the very rare cubic coordination geometry.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
NSFOTHER
OSTI ID:
1491885
Journal Information:
ChemComm, Vol. 54, Issue 72; ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH

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Influence of Pyrazolate vs N -Heterocyclic Carbene Ligands on the Slow Magnetic Relaxation of Homoleptic Trischelate Lanthanide(III) and Uranium(III) Complexes April 2014
Shape maps and polyhedral interconversion paths in transition metal chemistry September 2005
Single-Molecule Magnets November 2000
Relationship between the Skew Angle and Interplanar Distance in Four Bis(phthalocyaninato)lanthanide(III) Tetrabutylammonium Salts ([NBu n 4 ][Ln III Pc 2 ]; Ln = Nd, Gd, Ho, Lu) January 1996
A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit July 2017
Exploiting single-ion anisotropy in the design of f-element single-molecule magnets January 2011
Modulation of Homochiral Dy III Complexes: Single-Molecule Magnets with Ferroelectric Properties October 2012
Strategies towards single molecule magnets based on lanthanide ions October 2009
Lanthanides in molecular magnetism: old tools in a new field January 2011
Quantum Tunneling of Magnetization in Lanthanide Single-Molecule Magnets: Bis(phthalocyaninato)terbium and Bis(phthalocyaninato)dysprosium Anions May 2005
Tuning the Magnetoluminescence Behavior of Lanthanide Complexes Having Sphenocorona and Cubic Coordination Geometries: Tuning the Magnetoluminescence Behavior of Lanthanide Complexes Having Sphenocorona and Cubic Coordination Geometries April 2016
Symmetry strategies for high performance lanthanide-based single-molecule magnets January 2018
Molecular magnetic hysteresis at 60 kelvin in dysprosocenium August 2017
An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes October 2013
Exploring the Influence of Diamagnetic Ions on the Mechanism of Magnetization Relaxation in {Co III 2 Ln III 2 } (Ln = Dy, Tb, Ho) “Butterfly” Complexes February 2017
Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands January 2017
A Trigonal-Pyramidal Erbium(III) Single-Molecule Magnet March 2015
Polyoxopalladates Encapsulating Yttrium and Lanthanide Ions, [XIIIPdII12(AsPh)8O32]5− (X=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) June 2010
The Drosophila of single-molecule magnetism: [Mn12O12(O2CR)16(H2O)4] January 2009
Magnetism of Lanthanides in Molecular Materials with Transition-Metal Ions and Organic Radicals June 2002
Lanthanide Single-Molecule Magnets March 2013
Magnetic anisotropy in the excited states of low symmetry lanthanide complexes January 2011
Rational Design of Single-Ion Magnets and Spin Qubits Based on Mononuclear Lanthanoid Complexes October 2012
Spin Dynamics in the Negatively Charged Terbium (III) Bis-phthalocyaninato Complex April 2009
A Mononuclear Dysprosium Complex Featuring Single-Molecule-Magnet Behavior August 2010
Influencing the properties of dysprosium single-molecule magnets with phosphorus donor ligands July 2015

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