3D Printed Optical Quality Silica and Silica-Titania Glasses from Sol-Gel Feedstocks

Destino, Joel F.; Dudukovic, Nikola A.; Johnson, Michael A.; Nguyen, Du T.; Yee, Timothy D.; Egan, Garth C.; Sawvel, April M.; Steele, William A.; Baumann, Theodore F.; Duoss, Eric B.; Suratwala, Tayyab; Dylla-Spears, Rebecca

doi:10.1002/admt.201700323

Title: 3D Printed Optical Quality Silica and Silica-Titania Glasses from Sol-Gel Feedstocks

Journal Article · Mon Jan 08 00:00:00 EST 2018 · Advanced Materials Technologies

DOI:https://doi.org/10.1002/admt.201700323· OSTI ID:1491643

Destino, Joel F. ^[1]; Dudukovic, Nikola A. ^[2]; Johnson, Michael A. ^[2]; Nguyen, Du T. ^[2]; Yee, Timothy D. ^[2]; Egan, Garth C. ^[2]; Sawvel, April M. ^[2]; Steele, William A. ^[2]; Baumann, Theodore F. ^[2]; Duoss, Eric B. ^[2];

^[2];

^[2]

Creighton Univ., Omaha NE (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Abstract A method for fabricating optical quality silica and silica–titania glasses by three‐dimensional (3D) printing is reported. Key to this success is the combination of sol–gel derived silica and silica–titania colloidal feedstocks, direct ink writing (DIW) technology, and conventional glass thermal processing methods. Printable silica and silica–titania sol inks are prepared directly from molecular precursors by a simple one‐pot method, which is optimized to yield viscous, shear‐thinning colloidal suspensions with tuned rheology ideal for DIW. After printing, the parts are dried and sintered under optimized thermal conditions to ensure complete organic removal and uniform densification without crystallization. Characterizations of the 3D‐printed pure silica and silica–titania glasses show that they are equivalent to commercial optical fused silica and silica–titania glasses. More specifically, they exhibit comparable chemical composition, SiO ₂ network structure, refractive index, dispersion, optical transmission, and coefficient of thermal expansion. 3D‐printed silica and silica–titania glasses also exhibit comparable polished surface roughness and meet refractive index homogeneity standards within range of commercial optical grade glasses. This method establishes 3D printing as a viable tool to create optical glasses with compositional and geometric configurations that are inaccessible by conventional optical fabrication methods.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1491643

Alternate ID(s):: OSTI ID: 1416399

Report Number(s):: LLNL-JRNL-737841; 890806

Journal Information:: Advanced Materials Technologies, Vol. 3, Issue 6; ISSN 2365-709X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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