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Title: High thermoelectric performance in complex phosphides enabled by stereochemically active lone pair electrons

Abstract

An alternative strategy to create optimum band shape for superior thermoelectric performance by utilizing stereochemically active lone pair electrons is proposed, which has been demonstrated in the Ag 6Ge 10(1-x)Ga 10xP 12.

Authors:
 [1]; ORCiD logo [2];  [3]; ORCiD logo [4];  [5]; ORCiD logo [3]; ORCiD logo [1]; ORCiD logo [3]
  1. Chongqing Univ (China); Chinese Academy of Sciences (CAS), Beijing (China)
  2. Northwestern Univ., Evanston, IL (United States)
  3. Chongqing Univ (China)
  4. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  5. Yale Univ., New Haven, CT (United States)
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1491639
Alternate Identifier(s):
OSTI ID: 1483899
Report Number(s):
LLNL-JRNL-741603
Journal ID: ISSN 2050-7488; JMCAET; 895402
Grant/Contract Number:  
AC52-07NA27344; FG02-07ER46433
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 6; Journal Issue: 48; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Shen, Xingchen, Xia, Yi, Wang, Guiwen, Zhou, Fei, Ozolins, Vidvuds, Lu, Xu, Wang, Guoyu, and Zhou, Xiaoyuan. High thermoelectric performance in complex phosphides enabled by stereochemically active lone pair electrons. United States: N. p., 2018. Web. doi:10.1039/C8TA08448C.
Shen, Xingchen, Xia, Yi, Wang, Guiwen, Zhou, Fei, Ozolins, Vidvuds, Lu, Xu, Wang, Guoyu, & Zhou, Xiaoyuan. High thermoelectric performance in complex phosphides enabled by stereochemically active lone pair electrons. United States. doi:10.1039/C8TA08448C.
Shen, Xingchen, Xia, Yi, Wang, Guiwen, Zhou, Fei, Ozolins, Vidvuds, Lu, Xu, Wang, Guoyu, and Zhou, Xiaoyuan. Thu . "High thermoelectric performance in complex phosphides enabled by stereochemically active lone pair electrons". United States. doi:10.1039/C8TA08448C.
@article{osti_1491639,
title = {High thermoelectric performance in complex phosphides enabled by stereochemically active lone pair electrons},
author = {Shen, Xingchen and Xia, Yi and Wang, Guiwen and Zhou, Fei and Ozolins, Vidvuds and Lu, Xu and Wang, Guoyu and Zhou, Xiaoyuan},
abstractNote = {An alternative strategy to create optimum band shape for superior thermoelectric performance by utilizing stereochemically active lone pair electrons is proposed, which has been demonstrated in the Ag6Ge10(1-x)Ga10xP12.},
doi = {10.1039/C8TA08448C},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 48,
volume = 6,
place = {United States},
year = {2018},
month = {11}
}

Journal Article:
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